Environmental degradation of Modern non-balanced glasses

Crizzling is an alteration pathology related to non-balanced glasses (high content of flux oxides and low content of stabilizer ones), which can produce an intense damage such as transparency losses, appearance of drops on the surface or cracking. In this study two case studies (outdoor and indoor e...

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Main Authors: Teresa Palomar, Alexandra Rodrigues
Format: Article
Language:English
Published: Grupo Español del IIC 2020-06-01
Series:Ge-conservación
Subjects:
Online Access:https://ge-iic.com/ojs/index.php/revista/article/view/690/957
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author Teresa Palomar
Alexandra Rodrigues
author_facet Teresa Palomar
Alexandra Rodrigues
author_sort Teresa Palomar
collection DOAJ
description Crizzling is an alteration pathology related to non-balanced glasses (high content of flux oxides and low content of stabilizer ones), which can produce an intense damage such as transparency losses, appearance of drops on the surface or cracking. In this study two case studies (outdoor and indoor environment) were presented. The main alteration agent for these glasses was the water (rain, condensation and environmental humidity). In the outdoor environment, the rain washed away the [OH−] ions formed during the alteration; however, the exposure to cyclic conditions accelerated its alteration rate. In the indoor environment, early stages revealed to consist of an alkali leaching that concentrates on the surface, on specific areas, that were related to water adsorption and consistent with the weeping phenomenon. Cracking and flaking of the surface represents a later stage, occurring specifically in unbalanced compositions.
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spelling doaj.art-8742465648c849bb9a4bc51c6abe68ff2022-12-22T03:07:56ZengGrupo Español del IICGe-conservación1989-85682020-06-0117226232https://doi.org/10.37558/gec.v17i1.690Environmental degradation of Modern non-balanced glassesTeresa Palomar0https://orcid.org/0000-0002-3762-8788Alexandra Rodrigues1https://orcid.org/0000-0002-4688-7159Instituto de Cerámica y Vidrio (CSIC)Unidade de investigação VICARTE “Vidro e Cerâmica para as Artes”, Universidade Nova de Lisboa, Campus de Caparica, FCT-UNLCrizzling is an alteration pathology related to non-balanced glasses (high content of flux oxides and low content of stabilizer ones), which can produce an intense damage such as transparency losses, appearance of drops on the surface or cracking. In this study two case studies (outdoor and indoor environment) were presented. The main alteration agent for these glasses was the water (rain, condensation and environmental humidity). In the outdoor environment, the rain washed away the [OH−] ions formed during the alteration; however, the exposure to cyclic conditions accelerated its alteration rate. In the indoor environment, early stages revealed to consist of an alkali leaching that concentrates on the surface, on specific areas, that were related to water adsorption and consistent with the weeping phenomenon. Cracking and flaking of the surface represents a later stage, occurring specifically in unbalanced compositions.https://ge-iic.com/ojs/index.php/revista/article/view/690/957glasscrizzlingnatural environmentdegradation mechanism
spellingShingle Teresa Palomar
Alexandra Rodrigues
Environmental degradation of Modern non-balanced glasses
Ge-conservación
glass
crizzling
natural environment
degradation mechanism
title Environmental degradation of Modern non-balanced glasses
title_full Environmental degradation of Modern non-balanced glasses
title_fullStr Environmental degradation of Modern non-balanced glasses
title_full_unstemmed Environmental degradation of Modern non-balanced glasses
title_short Environmental degradation of Modern non-balanced glasses
title_sort environmental degradation of modern non balanced glasses
topic glass
crizzling
natural environment
degradation mechanism
url https://ge-iic.com/ojs/index.php/revista/article/view/690/957
work_keys_str_mv AT teresapalomar environmentaldegradationofmodernnonbalancedglasses
AT alexandrarodrigues environmentaldegradationofmodernnonbalancedglasses