Microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistors

Though solution-processed conjugated polymers with inverted temperature activated transport have been reported, the origin of this behaviour is unclear. Here, the authors realize temperature-independent electron transport above 280 K in a donor-acceptor copolymer through microstructural engineering....

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Main Authors: Alessandro Luzio, Fritz Nübling, Jaime Martin, Daniele Fazzi, Philipp Selter, Eliot Gann, Christopher R. McNeill, Martin Brinkmann, Michael Ryan Hansen, Natalie Stingelin, Michael Sommer, Mario Caironi
Format: Article
Language:English
Published: Nature Portfolio 2019-07-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-11125-9
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author Alessandro Luzio
Fritz Nübling
Jaime Martin
Daniele Fazzi
Philipp Selter
Eliot Gann
Christopher R. McNeill
Martin Brinkmann
Michael Ryan Hansen
Natalie Stingelin
Michael Sommer
Mario Caironi
author_facet Alessandro Luzio
Fritz Nübling
Jaime Martin
Daniele Fazzi
Philipp Selter
Eliot Gann
Christopher R. McNeill
Martin Brinkmann
Michael Ryan Hansen
Natalie Stingelin
Michael Sommer
Mario Caironi
author_sort Alessandro Luzio
collection DOAJ
description Though solution-processed conjugated polymers with inverted temperature activated transport have been reported, the origin of this behaviour is unclear. Here, the authors realize temperature-independent electron transport above 280 K in a donor-acceptor copolymer through microstructural engineering.
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spelling doaj.art-87476e2e67f64bb59a31068423e02d8b2022-12-21T22:54:52ZengNature PortfolioNature Communications2041-17232019-07-0110111310.1038/s41467-019-11125-9Microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistorsAlessandro Luzio0Fritz Nübling1Jaime Martin2Daniele Fazzi3Philipp Selter4Eliot Gann5Christopher R. McNeill6Martin Brinkmann7Michael Ryan Hansen8Natalie Stingelin9Michael Sommer10Mario Caironi11Center for Nano Science and Technology@PoliMi, Istituto Italiano di TecnologiaTechnische Universität Chemnitz, PolymerchemiePOLYMAT, University of the Basque Country UPV/EHUInstitut für Physikalische Chemie, Department Chemie, Universität zu KölnInstitut für Physikalische Chemie, Westfälische Wilhelms-UniversitätMaterials Science and Engineering, Monash UniveristyMaterials Science and Engineering, Monash UniveristyInstitut Charles Sadron, CNRS, Université de StrasbourgInstitut für Physikalische Chemie, Westfälische Wilhelms-UniversitätSchool of Materials Science and Engineering, Georgia Institute of TechnologyTechnische Universität Chemnitz, PolymerchemieCenter for Nano Science and Technology@PoliMi, Istituto Italiano di TecnologiaThough solution-processed conjugated polymers with inverted temperature activated transport have been reported, the origin of this behaviour is unclear. Here, the authors realize temperature-independent electron transport above 280 K in a donor-acceptor copolymer through microstructural engineering.https://doi.org/10.1038/s41467-019-11125-9
spellingShingle Alessandro Luzio
Fritz Nübling
Jaime Martin
Daniele Fazzi
Philipp Selter
Eliot Gann
Christopher R. McNeill
Martin Brinkmann
Michael Ryan Hansen
Natalie Stingelin
Michael Sommer
Mario Caironi
Microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistors
Nature Communications
title Microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistors
title_full Microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistors
title_fullStr Microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistors
title_full_unstemmed Microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistors
title_short Microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistors
title_sort microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistors
url https://doi.org/10.1038/s41467-019-11125-9
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