Preparation, Structural Characterization and Evaluation of Some Dynamic and Rheological Properties of a New Type of Clay Containing Mastic Material, Clay-Mastic
This study focused on the preparation, structural characterization and evaluation of some dynamic and rheological properties of a new type of mastic material, clay-mastic, which consists of bituminous binders mixed with mineral fillers. For this purpose, mastic samples were prepared by mixing conven...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-05-01
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| Series: | Minerals |
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| Online Access: | https://www.mdpi.com/2075-163X/13/5/705 |
| _version_ | 1797598925791690752 |
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| author | Ahmet Gürses Tahsin Barkın Barın |
| author_facet | Ahmet Gürses Tahsin Barkın Barın |
| author_sort | Ahmet Gürses |
| collection | DOAJ |
| description | This study focused on the preparation, structural characterization and evaluation of some dynamic and rheological properties of a new type of mastic material, clay-mastic, which consists of bituminous binders mixed with mineral fillers. For this purpose, mastic samples were prepared by mixing conventional bitumen (50/70) with organo-montmorillonite (OMMT) in various proportions. X-ray powder diffraction (XRD) spectra and scanning electron microscope (SEM) and high-resolution transmission electron microscope (HRTEM) images of raw clay (MMT), organo-clay (OMMT) and raw bitumen with the prepared mastics were taken, and the changes in the crystallographic properties of the clay and its dispersion characteristics in the bitumen matrix as well as the changes in the morphological properties of the mastic samples were investigated comparatively. In addition, penetration, softening point, flash point, dynamic viscosity, dynamic shear rheometer (DSR) and Fraass breaking point tests were carried out together with those of base bitumen in order to evaluate the properties of the prepared mastic samples in terms of dynamics and rheology. A comparison of the images of raw clay and organo-clay indicated delamination based on surface modification in clay layers in those belonging to organo-clay, and diffractograms of prepared mastic samples showed that the characteristic smectite peak of Montmorillonite shifted to the left gradually with an increasing clay ratio. This shows that due to the successful lyophilic modification on the clay surface, the effective intercalated and even exfoliated dispersion of the clay layers in the bitumen matrix can occur. The penetration viscosity number (PVN) values, defined as a function of penetration and dynamic viscosity, and the penetration index (PI) values, defined as a function of penetration and softening point, were found to be within a well-accepted thermal stability range for all of the prepared mastic samples. For this reason, it was concluded that the sensitivity of the samples to temperature decreased with the addition of organo-clay, thus providing applicability in a wider temperature range. The Fraass breaking point and dynamic viscosity values of the prepared mastic samples decreased and increased, respectively, with an increasing clay ratio, meaning that the addition of organo-clay lead to an increase in the crack resistance of the samples at low temperatures and a decrease in their permeability. |
| first_indexed | 2024-03-11T03:27:30Z |
| format | Article |
| id | doaj.art-878c8d5821df4857898eae346c431cbf |
| institution | Directory Open Access Journal |
| issn | 2075-163X |
| language | English |
| last_indexed | 2024-03-11T03:27:30Z |
| publishDate | 2023-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Minerals |
| spelling | doaj.art-878c8d5821df4857898eae346c431cbf2023-11-18T02:37:25ZengMDPI AGMinerals2075-163X2023-05-0113570510.3390/min13050705Preparation, Structural Characterization and Evaluation of Some Dynamic and Rheological Properties of a New Type of Clay Containing Mastic Material, Clay-MasticAhmet Gürses0Tahsin Barkın Barın1Department of Chemistry Education, K.K. Education Faculty, Atatürk University, Erzurum 25240, TurkeyNanoscience and Nano Engineering Department, Atatürk University, Erzurum 25240, TurkeyThis study focused on the preparation, structural characterization and evaluation of some dynamic and rheological properties of a new type of mastic material, clay-mastic, which consists of bituminous binders mixed with mineral fillers. For this purpose, mastic samples were prepared by mixing conventional bitumen (50/70) with organo-montmorillonite (OMMT) in various proportions. X-ray powder diffraction (XRD) spectra and scanning electron microscope (SEM) and high-resolution transmission electron microscope (HRTEM) images of raw clay (MMT), organo-clay (OMMT) and raw bitumen with the prepared mastics were taken, and the changes in the crystallographic properties of the clay and its dispersion characteristics in the bitumen matrix as well as the changes in the morphological properties of the mastic samples were investigated comparatively. In addition, penetration, softening point, flash point, dynamic viscosity, dynamic shear rheometer (DSR) and Fraass breaking point tests were carried out together with those of base bitumen in order to evaluate the properties of the prepared mastic samples in terms of dynamics and rheology. A comparison of the images of raw clay and organo-clay indicated delamination based on surface modification in clay layers in those belonging to organo-clay, and diffractograms of prepared mastic samples showed that the characteristic smectite peak of Montmorillonite shifted to the left gradually with an increasing clay ratio. This shows that due to the successful lyophilic modification on the clay surface, the effective intercalated and even exfoliated dispersion of the clay layers in the bitumen matrix can occur. The penetration viscosity number (PVN) values, defined as a function of penetration and dynamic viscosity, and the penetration index (PI) values, defined as a function of penetration and softening point, were found to be within a well-accepted thermal stability range for all of the prepared mastic samples. For this reason, it was concluded that the sensitivity of the samples to temperature decreased with the addition of organo-clay, thus providing applicability in a wider temperature range. The Fraass breaking point and dynamic viscosity values of the prepared mastic samples decreased and increased, respectively, with an increasing clay ratio, meaning that the addition of organo-clay lead to an increase in the crack resistance of the samples at low temperatures and a decrease in their permeability.https://www.mdpi.com/2075-163X/13/5/705mastic materialorgano-claybitumenmodificationdynamic and rheological properties |
| spellingShingle | Ahmet Gürses Tahsin Barkın Barın Preparation, Structural Characterization and Evaluation of Some Dynamic and Rheological Properties of a New Type of Clay Containing Mastic Material, Clay-Mastic Minerals mastic material organo-clay bitumen modification dynamic and rheological properties |
| title | Preparation, Structural Characterization and Evaluation of Some Dynamic and Rheological Properties of a New Type of Clay Containing Mastic Material, Clay-Mastic |
| title_full | Preparation, Structural Characterization and Evaluation of Some Dynamic and Rheological Properties of a New Type of Clay Containing Mastic Material, Clay-Mastic |
| title_fullStr | Preparation, Structural Characterization and Evaluation of Some Dynamic and Rheological Properties of a New Type of Clay Containing Mastic Material, Clay-Mastic |
| title_full_unstemmed | Preparation, Structural Characterization and Evaluation of Some Dynamic and Rheological Properties of a New Type of Clay Containing Mastic Material, Clay-Mastic |
| title_short | Preparation, Structural Characterization and Evaluation of Some Dynamic and Rheological Properties of a New Type of Clay Containing Mastic Material, Clay-Mastic |
| title_sort | preparation structural characterization and evaluation of some dynamic and rheological properties of a new type of clay containing mastic material clay mastic |
| topic | mastic material organo-clay bitumen modification dynamic and rheological properties |
| url | https://www.mdpi.com/2075-163X/13/5/705 |
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