Pretreatment of Copper Sulphide Ores Prior to Heap Leaching: A Review

Although the main cause of hydrometallurgical plant closures is the depletion of oxidized copper minerals reserves, the lack of new hydrometallurgy projects also contributes to these closures. One solution is to be able to process copper sulphide ores hydrometallurgically. However, it is widely know...

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Main Authors: Andrés Neira, Diana Pizarro, Víctor Quezada, Lilian Velásquez-Yévenes
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/11/7/1067
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author Andrés Neira
Diana Pizarro
Víctor Quezada
Lilian Velásquez-Yévenes
author_facet Andrés Neira
Diana Pizarro
Víctor Quezada
Lilian Velásquez-Yévenes
author_sort Andrés Neira
collection DOAJ
description Although the main cause of hydrometallurgical plant closures is the depletion of oxidized copper minerals reserves, the lack of new hydrometallurgy projects also contributes to these closures. One solution is to be able to process copper sulphide ores hydrometallurgically. However, it is widely known that sulphide copper ores—and chalcopyrite in particular—have very slow dissolution kinetics in traditional leaching systems. An alternative to improve the extraction of copper from sulphide ores is the use of a pretreatment process. Several investigations were developed evaluating the effects of pretreatment, mainly in the extraction of copper from chalcopyrite in chloride media. This study presents a review of various pretreatment methods prior to heap leaching to aid in the dissolution of copper from sulphide ores. Different variables of pretreatment that affect the extraction of copper were identified, including the type of salts used in agglomeration, curing time, and curing temperatures. Successful cases such as the implementation of the CuproChlor<sup>®</sup> process (use of calcium chloride), and various pilot studies using sodium chloride and temperature, show that pretreatment is an alternative that aids in the dissolution of copper from sulphide ores.
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spelling doaj.art-8799a5be1f3b4ee09a7944a3a74e34002023-11-22T04:23:15ZengMDPI AGMetals2075-47012021-07-01117106710.3390/met11071067Pretreatment of Copper Sulphide Ores Prior to Heap Leaching: A ReviewAndrés Neira0Diana Pizarro1Víctor Quezada2Lilian Velásquez-Yévenes3Laboratorio de Investigación de Minerales Sulfurados, Departamento de Ingeniería Metalúrgica y Minas, Universidad Católica del Norte, Avenida Angamos 0610, 1270709 Antofagasta, ChileLaboratorio de Investigación de Minerales Sulfurados, Departamento de Ingeniería Metalúrgica y Minas, Universidad Católica del Norte, Avenida Angamos 0610, 1270709 Antofagasta, ChileLaboratorio de Investigación de Minerales Sulfurados, Departamento de Ingeniería Metalúrgica y Minas, Universidad Católica del Norte, Avenida Angamos 0610, 1270709 Antofagasta, ChileEscuela de Ingeniería Civil de Minas, Facultad de Ingeniería, Universidad de Talca, 3340000 Curicó, ChileAlthough the main cause of hydrometallurgical plant closures is the depletion of oxidized copper minerals reserves, the lack of new hydrometallurgy projects also contributes to these closures. One solution is to be able to process copper sulphide ores hydrometallurgically. However, it is widely known that sulphide copper ores—and chalcopyrite in particular—have very slow dissolution kinetics in traditional leaching systems. An alternative to improve the extraction of copper from sulphide ores is the use of a pretreatment process. Several investigations were developed evaluating the effects of pretreatment, mainly in the extraction of copper from chalcopyrite in chloride media. This study presents a review of various pretreatment methods prior to heap leaching to aid in the dissolution of copper from sulphide ores. Different variables of pretreatment that affect the extraction of copper were identified, including the type of salts used in agglomeration, curing time, and curing temperatures. Successful cases such as the implementation of the CuproChlor<sup>®</sup> process (use of calcium chloride), and various pilot studies using sodium chloride and temperature, show that pretreatment is an alternative that aids in the dissolution of copper from sulphide ores.https://www.mdpi.com/2075-4701/11/7/1067copper sulphide oreagglomerationleachingcuringpretreatmentchloride
spellingShingle Andrés Neira
Diana Pizarro
Víctor Quezada
Lilian Velásquez-Yévenes
Pretreatment of Copper Sulphide Ores Prior to Heap Leaching: A Review
Metals
copper sulphide ore
agglomeration
leaching
curing
pretreatment
chloride
title Pretreatment of Copper Sulphide Ores Prior to Heap Leaching: A Review
title_full Pretreatment of Copper Sulphide Ores Prior to Heap Leaching: A Review
title_fullStr Pretreatment of Copper Sulphide Ores Prior to Heap Leaching: A Review
title_full_unstemmed Pretreatment of Copper Sulphide Ores Prior to Heap Leaching: A Review
title_short Pretreatment of Copper Sulphide Ores Prior to Heap Leaching: A Review
title_sort pretreatment of copper sulphide ores prior to heap leaching a review
topic copper sulphide ore
agglomeration
leaching
curing
pretreatment
chloride
url https://www.mdpi.com/2075-4701/11/7/1067
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