Natural polymer fillers instead of dye and pigments: Pumice and scoria in PDMS fluid and elastomer composites

The electrical and thermal conductivities and light transmittance properties of silicone oil and polydimethylsiloxane (PDMS) elastomer composites were investigated. Pumice, scoria, nano-Ag, and multi-walled carbon nanotube (MWCNT) particles were used as fillers. An effective, clean, and easy method...

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Main Authors: Özvezir Esra, Beyli Pınar Turan
Format: Article
Language:English
Published: De Gruyter 2023-12-01
Series:Green Processing and Synthesis
Subjects:
Online Access:https://doi.org/10.1515/gps-2023-0128
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author Özvezir Esra
Beyli Pınar Turan
author_facet Özvezir Esra
Beyli Pınar Turan
author_sort Özvezir Esra
collection DOAJ
description The electrical and thermal conductivities and light transmittance properties of silicone oil and polydimethylsiloxane (PDMS) elastomer composites were investigated. Pumice, scoria, nano-Ag, and multi-walled carbon nanotube (MWCNT) particles were used as fillers. An effective, clean, and easy method was used to prepare nanosized particles from pumice and scoria rocks. Only MWCNT–PDMS composites showed electrical conductivity. The highest electrical conductivity of 24.7 S·m−1 was obtained with the 25% pumice–10% MWCNT–silicone oil composite. All filler particles increased the thermal conductivity of the PDMS elastomer. MWCNTs were more effective than pumice and scoria, and the thermal conductivity reached 0.62 W·(m·K)−1 with an addition of 3 wt% MWCNTs. All filler particles decreased the transparency of the PDMS elastomer. The sample with 5 wt% pumice particles reached zero transmittance. Pumice and scoria naturally colored the PDMS elastomer. The powders of these natural volcanic rocks could be used as a suitable coloring filling material instead of dyes and pigments for polymers without waste. However, it was concluded that pumice and scoria particles are not suitable for making composites with silicone oil due to the possibility of catalyzing the degradation of linear PDSM.
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spelling doaj.art-879f6b0c2b3549fb9ee0a18f28825e652023-12-11T07:36:19ZengDe GruyterGreen Processing and Synthesis2191-95502023-12-011211032010.1515/gps-2023-0128Natural polymer fillers instead of dye and pigments: Pumice and scoria in PDMS fluid and elastomer compositesÖzvezir Esra0Beyli Pınar Turan1Chemistry Department, Faculty of Science and Literature, Balikesir Üniversity, Balikesir, TurkeyChemistry Department, Faculty of Science and Literature, Balikesir Üniversity, Balikesir, TurkeyThe electrical and thermal conductivities and light transmittance properties of silicone oil and polydimethylsiloxane (PDMS) elastomer composites were investigated. Pumice, scoria, nano-Ag, and multi-walled carbon nanotube (MWCNT) particles were used as fillers. An effective, clean, and easy method was used to prepare nanosized particles from pumice and scoria rocks. Only MWCNT–PDMS composites showed electrical conductivity. The highest electrical conductivity of 24.7 S·m−1 was obtained with the 25% pumice–10% MWCNT–silicone oil composite. All filler particles increased the thermal conductivity of the PDMS elastomer. MWCNTs were more effective than pumice and scoria, and the thermal conductivity reached 0.62 W·(m·K)−1 with an addition of 3 wt% MWCNTs. All filler particles decreased the transparency of the PDMS elastomer. The sample with 5 wt% pumice particles reached zero transmittance. Pumice and scoria naturally colored the PDMS elastomer. The powders of these natural volcanic rocks could be used as a suitable coloring filling material instead of dyes and pigments for polymers without waste. However, it was concluded that pumice and scoria particles are not suitable for making composites with silicone oil due to the possibility of catalyzing the degradation of linear PDSM.https://doi.org/10.1515/gps-2023-0128pdmsmwcntvolcanic rocksthermal and electrical conductivitylight transmittance
spellingShingle Özvezir Esra
Beyli Pınar Turan
Natural polymer fillers instead of dye and pigments: Pumice and scoria in PDMS fluid and elastomer composites
Green Processing and Synthesis
pdms
mwcnt
volcanic rocks
thermal and electrical conductivity
light transmittance
title Natural polymer fillers instead of dye and pigments: Pumice and scoria in PDMS fluid and elastomer composites
title_full Natural polymer fillers instead of dye and pigments: Pumice and scoria in PDMS fluid and elastomer composites
title_fullStr Natural polymer fillers instead of dye and pigments: Pumice and scoria in PDMS fluid and elastomer composites
title_full_unstemmed Natural polymer fillers instead of dye and pigments: Pumice and scoria in PDMS fluid and elastomer composites
title_short Natural polymer fillers instead of dye and pigments: Pumice and scoria in PDMS fluid and elastomer composites
title_sort natural polymer fillers instead of dye and pigments pumice and scoria in pdms fluid and elastomer composites
topic pdms
mwcnt
volcanic rocks
thermal and electrical conductivity
light transmittance
url https://doi.org/10.1515/gps-2023-0128
work_keys_str_mv AT ozveziresra naturalpolymerfillersinsteadofdyeandpigmentspumiceandscoriainpdmsfluidandelastomercomposites
AT beylipınarturan naturalpolymerfillersinsteadofdyeandpigmentspumiceandscoriainpdmsfluidandelastomercomposites