Bis(N,N,N-trimethylethanaminium) bis(1,4-tetraselenido-κ2Se1,Se4)cadmate
The title compound, (EtMe3N)2[Cd(Se4)2], which has been prepared by reaction of CdI2, K2Se4 and EtMe3NI in dimethylformamide, is the first example of a [Cd(Se4)2]2− anion stabilized by alkylammonium counter-ions. The Cd atom in the complex [Cd(Se4)2]2− anion is tetrahedra...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811007227 |
| _version_ | 1830231293676224512 |
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| author | Jaemyeong Kim Kang-Woo Kim |
| author_facet | Jaemyeong Kim Kang-Woo Kim |
| author_sort | Jaemyeong Kim |
| collection | DOAJ |
| description | The title compound, (EtMe3N)2[Cd(Se4)2], which has been prepared by reaction of CdI2, K2Se4 and EtMe3NI in dimethylformamide, is the first example of a [Cd(Se4)2]2− anion stabilized by alkylammonium counter-ions. The Cd atom in the complex [Cd(Se4)2]2− anion is tetrahedrally coordinated by two chelating tetraselenide ligands, and both CdSe4 rings exhibit an envelope conformation. |
| first_indexed | 2024-12-18T11:08:52Z |
| format | Article |
| id | doaj.art-87c0587dec364c78b92d65d79d69cbb2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T11:08:52Z |
| publishDate | 2011-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-87c0587dec364c78b92d65d79d69cbb22022-12-21T21:10:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m394m39410.1107/S1600536811007227Bis(N,N,N-trimethylethanaminium) bis(1,4-tetraselenido-κ2Se1,Se4)cadmateJaemyeong KimKang-Woo KimThe title compound, (EtMe3N)2[Cd(Se4)2], which has been prepared by reaction of CdI2, K2Se4 and EtMe3NI in dimethylformamide, is the first example of a [Cd(Se4)2]2− anion stabilized by alkylammonium counter-ions. The Cd atom in the complex [Cd(Se4)2]2− anion is tetrahedrally coordinated by two chelating tetraselenide ligands, and both CdSe4 rings exhibit an envelope conformation.http://scripts.iucr.org/cgi-bin/paper?S1600536811007227 |
| spellingShingle | Jaemyeong Kim Kang-Woo Kim Bis(N,N,N-trimethylethanaminium) bis(1,4-tetraselenido-κ2Se1,Se4)cadmate Acta Crystallographica Section E |
| title | Bis(N,N,N-trimethylethanaminium) bis(1,4-tetraselenido-κ2Se1,Se4)cadmate |
| title_full | Bis(N,N,N-trimethylethanaminium) bis(1,4-tetraselenido-κ2Se1,Se4)cadmate |
| title_fullStr | Bis(N,N,N-trimethylethanaminium) bis(1,4-tetraselenido-κ2Se1,Se4)cadmate |
| title_full_unstemmed | Bis(N,N,N-trimethylethanaminium) bis(1,4-tetraselenido-κ2Se1,Se4)cadmate |
| title_short | Bis(N,N,N-trimethylethanaminium) bis(1,4-tetraselenido-κ2Se1,Se4)cadmate |
| title_sort | bis n n n trimethylethanaminium bis 1 4 tetraselenido amp 954 2se1 se4 cadmate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811007227 |
| work_keys_str_mv | AT jaemyeongkim bisnnntrimethylethanaminiumbis14tetraselenidoamp9542se1se4cadmate AT kangwookim bisnnntrimethylethanaminiumbis14tetraselenidoamp9542se1se4cadmate |