Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane + n-alkane systems
The Peng-Robinson-Stryjek-Vera (PRSV) equation of state (EOS) coupled with a modified two parameter van der Waals one-fluid mixing rule (MvdW1) and the Huron-Vidal-Orbey-Sandler mixing rule incorporating the NRTL equation as a GE model was used for the correlation of excess enthalpy (HE), excess hea...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
1999-12-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol64/No12-Pdf/V64-No12-09.zip |
| _version_ | 1818777487631450112 |
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| author | SLOBODAN P. SERBANOVIC MIRJANA LJ. KIJEVCANIN ALEKSANDAR Z. TASIC BOJAN D. DJORDJEVIC |
| author_facet | SLOBODAN P. SERBANOVIC MIRJANA LJ. KIJEVCANIN ALEKSANDAR Z. TASIC BOJAN D. DJORDJEVIC |
| author_sort | SLOBODAN P. SERBANOVIC |
| collection | DOAJ |
| description | The Peng-Robinson-Stryjek-Vera (PRSV) equation of state (EOS) coupled with a modified two parameter van der Waals one-fluid mixing rule (MvdW1) and the Huron-Vidal-Orbey-Sandler mixing rule incorporating the NRTL equation as a GE model was used for the correlation of excess enthalpy (HE), excess heat capacity (CpE) and the simultaneous correlation of both properties. All calculations with temperature dependent parameters of EOS models were applied to 1,3-dioxolane+n-alkane systems. The correlation of the HE and CpE data alone with four coefficients and the HE+CpE data with six coefficients of the temperature dependent parameters of the HVOS-NRTL models could be considered as very satisfactory. |
| first_indexed | 2024-12-18T11:29:37Z |
| format | Article |
| id | doaj.art-87d1d820aca1483d94d28f47f549b7c7 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-18T11:29:37Z |
| publishDate | 1999-12-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-87d1d820aca1483d94d28f47f549b7c72022-12-21T21:09:38ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391999-12-016412801811Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane + n-alkane systemsSLOBODAN P. SERBANOVICMIRJANA LJ. KIJEVCANINALEKSANDAR Z. TASICBOJAN D. DJORDJEVICThe Peng-Robinson-Stryjek-Vera (PRSV) equation of state (EOS) coupled with a modified two parameter van der Waals one-fluid mixing rule (MvdW1) and the Huron-Vidal-Orbey-Sandler mixing rule incorporating the NRTL equation as a GE model was used for the correlation of excess enthalpy (HE), excess heat capacity (CpE) and the simultaneous correlation of both properties. All calculations with temperature dependent parameters of EOS models were applied to 1,3-dioxolane+n-alkane systems. The correlation of the HE and CpE data alone with four coefficients and the HE+CpE data with six coefficients of the temperature dependent parameters of the HVOS-NRTL models could be considered as very satisfactory.http://www.shd.org.yu/HtDocs/SHD/Vol64/No12-Pdf/V64-No12-09.zipequation of statemixing ruleexcess properties13-dioxolanen-alkane |
| spellingShingle | SLOBODAN P. SERBANOVIC MIRJANA LJ. KIJEVCANIN ALEKSANDAR Z. TASIC BOJAN D. DJORDJEVIC Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane + n-alkane systems Journal of the Serbian Chemical Society equation of state mixing rule excess properties 1 3-dioxolane n-alkane |
| title | Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane + n-alkane systems |
| title_full | Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane + n-alkane systems |
| title_fullStr | Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane + n-alkane systems |
| title_full_unstemmed | Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane + n-alkane systems |
| title_short | Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane + n-alkane systems |
| title_sort | application of the mvdw1 and hvos nrtl mixing rules to the simultaneous correlation of excess enthalpies and w shaped excess heat capacities data of 1 3 dioxolane n alkane systems |
| topic | equation of state mixing rule excess properties 1 3-dioxolane n-alkane |
| url | http://www.shd.org.yu/HtDocs/SHD/Vol64/No12-Pdf/V64-No12-09.zip |
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