Poly(acrylamide)-MWNTs hybrid hydrogel with extremely high mechanical strength

Poly(acrylamide)-multiwalled carbon nanotubes (PAAm-MWNTs) hybrid hydrogels were prepared through the radiation-induced polymerization and crosslinking of the aqueous solution of acrylamide and well-dispersed MWNTs for the first time. The PAAm gels obtained by the radiation-induced polymerization an...

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Main Authors: Feng Huanhuan, Zheng Tingting, Wang Xuezhen, Wang Huiliang
Format: Article
Language:English
Published: De Gruyter 2016-01-01
Series:Open Chemistry
Subjects:
Online Access:http://www.degruyter.com/view/j/chem.2016.14.issue-1/chem-2016-0017/chem-2016-0017.xml?format=INT
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author Feng Huanhuan
Zheng Tingting
Wang Xuezhen
Wang Huiliang
author_facet Feng Huanhuan
Zheng Tingting
Wang Xuezhen
Wang Huiliang
author_sort Feng Huanhuan
collection DOAJ
description Poly(acrylamide)-multiwalled carbon nanotubes (PAAm-MWNTs) hybrid hydrogels were prepared through the radiation-induced polymerization and crosslinking of the aqueous solution of acrylamide and well-dispersed MWNTs for the first time. The PAAm gels obtained by the radiation-induced polymerization and cosslinking showed very high mechanical strengths, and the PAAm-MWNTs hybrid hydrogels had improved mechanical properties compared with the PAAm gels, and hence the PAAm-MWNTs hybrid hydrogels showed extremely high compressive and tensile strengths. The hybrid hydrogels with water contents more than 80 wt.% usually did not fracture even at compressive strengths close to or even more than 60 MPa and strains more than 97%. And the hybrid hydrogels had very high elongations (more than 2000% in some cases), especially when the water content was high. The tensile strengths were in sub-MPa. The hybrid PAAm-MWNTs hydrogel is one of the strongest hydrogel even made.
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spelling doaj.art-87ddd76c29fc4358a8b167452d05c7542022-12-21T20:29:58ZengDe GruyterOpen Chemistry2391-54202016-01-0114115015710.1515/chem-2016-0017chem-2016-0017Poly(acrylamide)-MWNTs hybrid hydrogel with extremely high mechanical strengthFeng Huanhuan0Zheng Tingting1Wang Xuezhen2Wang Huiliang3Physical Chemistry and Soft Matter, Wageningen University, Helix building Stippeneng 4, 6708 WE Wageningen, The NetherlandsPhysical Chemistry and Soft Matter, Wageningen University, Helix building Stippeneng 4, 6708 WE Wageningen, The NetherlandsArtie McFerrin Department of Chemical Engineering, Texas A&M University, College Station, TX, 7843-3122, United States of AmericaDepartment Material Science and Engineering, Harbin Institute of Technology, Shenzhen 518055, China; College of Chemistry, Beijing Normal University, Beijing 100875, ChinaPoly(acrylamide)-multiwalled carbon nanotubes (PAAm-MWNTs) hybrid hydrogels were prepared through the radiation-induced polymerization and crosslinking of the aqueous solution of acrylamide and well-dispersed MWNTs for the first time. The PAAm gels obtained by the radiation-induced polymerization and cosslinking showed very high mechanical strengths, and the PAAm-MWNTs hybrid hydrogels had improved mechanical properties compared with the PAAm gels, and hence the PAAm-MWNTs hybrid hydrogels showed extremely high compressive and tensile strengths. The hybrid hydrogels with water contents more than 80 wt.% usually did not fracture even at compressive strengths close to or even more than 60 MPa and strains more than 97%. And the hybrid hydrogels had very high elongations (more than 2000% in some cases), especially when the water content was high. The tensile strengths were in sub-MPa. The hybrid PAAm-MWNTs hydrogel is one of the strongest hydrogel even made.http://www.degruyter.com/view/j/chem.2016.14.issue-1/chem-2016-0017/chem-2016-0017.xml?format=INThydrogelscntsradiationhigh-strength
spellingShingle Feng Huanhuan
Zheng Tingting
Wang Xuezhen
Wang Huiliang
Poly(acrylamide)-MWNTs hybrid hydrogel with extremely high mechanical strength
Open Chemistry
hydrogels
cnts
radiation
high-strength
title Poly(acrylamide)-MWNTs hybrid hydrogel with extremely high mechanical strength
title_full Poly(acrylamide)-MWNTs hybrid hydrogel with extremely high mechanical strength
title_fullStr Poly(acrylamide)-MWNTs hybrid hydrogel with extremely high mechanical strength
title_full_unstemmed Poly(acrylamide)-MWNTs hybrid hydrogel with extremely high mechanical strength
title_short Poly(acrylamide)-MWNTs hybrid hydrogel with extremely high mechanical strength
title_sort poly acrylamide mwnts hybrid hydrogel with extremely high mechanical strength
topic hydrogels
cnts
radiation
high-strength
url http://www.degruyter.com/view/j/chem.2016.14.issue-1/chem-2016-0017/chem-2016-0017.xml?format=INT
work_keys_str_mv AT fenghuanhuan polyacrylamidemwntshybridhydrogelwithextremelyhighmechanicalstrength
AT zhengtingting polyacrylamidemwntshybridhydrogelwithextremelyhighmechanicalstrength
AT wangxuezhen polyacrylamidemwntshybridhydrogelwithextremelyhighmechanicalstrength
AT wanghuiliang polyacrylamidemwntshybridhydrogelwithextremelyhighmechanicalstrength