Treatment of Water Contaminated with Reactive Black-5 Dye by Carbon Nanotubes

Most of the dyes used today by the textile industry are of synthetic origin. These substances, many of which are highly toxic, are in many cases not adequately filtered during the processing stages, ending up in groundwater and water courses. The aim of this work was to optimize the adsorption proce...

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Main Authors: Pierantonio De Luca, Jànos B. Nagy
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/23/5508
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author Pierantonio De Luca
Jànos B. Nagy
author_facet Pierantonio De Luca
Jànos B. Nagy
author_sort Pierantonio De Luca
collection DOAJ
description Most of the dyes used today by the textile industry are of synthetic origin. These substances, many of which are highly toxic, are in many cases not adequately filtered during the processing stages, ending up in groundwater and water courses. The aim of this work was to optimize the adsorption process of carbon nanotubes to remove an azo-dye, called Reactive Black-5, from aqueous systems. Particular systems containing carbon nanotubes and dye solutions were analyzed. Furthermore, the reversibility of the process and the presence of possible degradation phenomena by the dye molecules were investigated. For this purpose, the influence of different parameters on the adsorption process, such as the nature of the carbon nanotubes (purified and nonpurified), initial concentration of the dye, stirring speed, and contact times, were studied. The solid and liquid phases after the tests were characterized by chemical-physical techniques such as thermogravimetric analysis (TG, DTA), UV spectrophotometry, BET (Brunauer, Emmett, Teller), and TOC (total organic carbon) analysis. The data obtained showed a high adsorbing capacity of carbon nanotubes in the removal of the Reactive Black-5 dye from aqueous systems. Furthermore, the efficiency of the adsorption process was observed to be influenced by the stirring speed of the samples and the contact time, while purified and nonpurified nanotubes provided substantially the same results.
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spelling doaj.art-87e78ff4027e4a3daa225380de2cdb9a2023-11-20T23:18:26ZengMDPI AGMaterials1996-19442020-12-011323550810.3390/ma13235508Treatment of Water Contaminated with Reactive Black-5 Dye by Carbon NanotubesPierantonio De Luca0Jànos B. Nagy1Dipartimento di Ingegneria Meccanica, Energetica e Gestionale, University of Calabria, I-87030 Arcavacata di Rende (CS), ItalyDipartimento di Ingegneria Meccanica, Energetica e Gestionale, University of Calabria, I-87030 Arcavacata di Rende (CS), ItalyMost of the dyes used today by the textile industry are of synthetic origin. These substances, many of which are highly toxic, are in many cases not adequately filtered during the processing stages, ending up in groundwater and water courses. The aim of this work was to optimize the adsorption process of carbon nanotubes to remove an azo-dye, called Reactive Black-5, from aqueous systems. Particular systems containing carbon nanotubes and dye solutions were analyzed. Furthermore, the reversibility of the process and the presence of possible degradation phenomena by the dye molecules were investigated. For this purpose, the influence of different parameters on the adsorption process, such as the nature of the carbon nanotubes (purified and nonpurified), initial concentration of the dye, stirring speed, and contact times, were studied. The solid and liquid phases after the tests were characterized by chemical-physical techniques such as thermogravimetric analysis (TG, DTA), UV spectrophotometry, BET (Brunauer, Emmett, Teller), and TOC (total organic carbon) analysis. The data obtained showed a high adsorbing capacity of carbon nanotubes in the removal of the Reactive Black-5 dye from aqueous systems. Furthermore, the efficiency of the adsorption process was observed to be influenced by the stirring speed of the samples and the contact time, while purified and nonpurified nanotubes provided substantially the same results.https://www.mdpi.com/1996-1944/13/23/5508adsorptioncarbon nanotubesdyereactive black-5
spellingShingle Pierantonio De Luca
Jànos B. Nagy
Treatment of Water Contaminated with Reactive Black-5 Dye by Carbon Nanotubes
Materials
adsorption
carbon nanotubes
dye
reactive black-5
title Treatment of Water Contaminated with Reactive Black-5 Dye by Carbon Nanotubes
title_full Treatment of Water Contaminated with Reactive Black-5 Dye by Carbon Nanotubes
title_fullStr Treatment of Water Contaminated with Reactive Black-5 Dye by Carbon Nanotubes
title_full_unstemmed Treatment of Water Contaminated with Reactive Black-5 Dye by Carbon Nanotubes
title_short Treatment of Water Contaminated with Reactive Black-5 Dye by Carbon Nanotubes
title_sort treatment of water contaminated with reactive black 5 dye by carbon nanotubes
topic adsorption
carbon nanotubes
dye
reactive black-5
url https://www.mdpi.com/1996-1944/13/23/5508
work_keys_str_mv AT pierantoniodeluca treatmentofwatercontaminatedwithreactiveblack5dyebycarbonnanotubes
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