Electrical Conductivity Measurement of Electrolyte Solution

Methods for measuring and analyzing the electrical conductivity of electrolyte solutions are reviewed. The accuracy of conductivity measurements, which have been around for more than 100 years, depends on the physical properties related to ionic conductivity, especially the concentration of the refe...

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Main Author: Minoru MIZUHATA
Format: Article
Language:English
Published: The Electrochemical Society of Japan 2022-10-01
Series:Electrochemistry
Subjects:
Online Access:https://www.jstage.jst.go.jp/article/electrochemistry/90/10/90_22-66111/_html/-char/en
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author Minoru MIZUHATA
author_facet Minoru MIZUHATA
author_sort Minoru MIZUHATA
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description Methods for measuring and analyzing the electrical conductivity of electrolyte solutions are reviewed. The accuracy of conductivity measurements, which have been around for more than 100 years, depends on the physical properties related to ionic conductivity, especially the concentration of the reference material, the electrical signal at the time of measurement, and the temperature, each of which has been redefined each time according to changes in definitions and standards. This article summarizes elemental factors in electrical conductivity measurement, including the concentration and traceability of potassium chloride as a reference material, the history of the bridge method and types of measuring cells, and important notes and recent topics regarding the concept of temperature dependence.
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spelling doaj.art-87ef489764394762b7d51fdb7d79fbd72023-01-03T10:41:59ZengThe Electrochemical Society of JapanElectrochemistry2186-24512022-10-01901010201110201110.5796/electrochemistry.22-66111electrochemistryElectrical Conductivity Measurement of Electrolyte SolutionMinoru MIZUHATA0https://orcid.org/0000-0002-4496-2215Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe UniversityMethods for measuring and analyzing the electrical conductivity of electrolyte solutions are reviewed. The accuracy of conductivity measurements, which have been around for more than 100 years, depends on the physical properties related to ionic conductivity, especially the concentration of the reference material, the electrical signal at the time of measurement, and the temperature, each of which has been redefined each time according to changes in definitions and standards. This article summarizes elemental factors in electrical conductivity measurement, including the concentration and traceability of potassium chloride as a reference material, the history of the bridge method and types of measuring cells, and important notes and recent topics regarding the concept of temperature dependence.https://www.jstage.jst.go.jp/article/electrochemistry/90/10/90_22-66111/_html/-char/enprinciple of electrical conductivity measurementconcentration and traceability of potassium chloridekohlrausch bridge and automatic balancing bridgetemperature dependence in arrhenius and vtf equations
spellingShingle Minoru MIZUHATA
Electrical Conductivity Measurement of Electrolyte Solution
Electrochemistry
principle of electrical conductivity measurement
concentration and traceability of potassium chloride
kohlrausch bridge and automatic balancing bridge
temperature dependence in arrhenius and vtf equations
title Electrical Conductivity Measurement of Electrolyte Solution
title_full Electrical Conductivity Measurement of Electrolyte Solution
title_fullStr Electrical Conductivity Measurement of Electrolyte Solution
title_full_unstemmed Electrical Conductivity Measurement of Electrolyte Solution
title_short Electrical Conductivity Measurement of Electrolyte Solution
title_sort electrical conductivity measurement of electrolyte solution
topic principle of electrical conductivity measurement
concentration and traceability of potassium chloride
kohlrausch bridge and automatic balancing bridge
temperature dependence in arrhenius and vtf equations
url https://www.jstage.jst.go.jp/article/electrochemistry/90/10/90_22-66111/_html/-char/en
work_keys_str_mv AT minorumizuhata electricalconductivitymeasurementofelectrolytesolution