Effects of Biochar Amendment on Chloropicrin Adsorption and Degradation in Soil

The characteristics of biochar vary with pyrolysis temperature. Chloropicrin (CP) is an effective fumigant for controlling soil-borne pests. This study investigated the characteristics of biochars prepared at 300, 500, and 700 °C by michelia alba (Magnolia denudata) wood and evaluated their capacity...

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Main Authors: Pengfei Liu, Qiuxia Wang, Dongdong Yan, Wensheng Fang, Liangang Mao, Dong Wang, Yuan Li, Canbin Ouyang, Meixia Guo, Aocheng Cao
Format: Article
Language:English
Published: MDPI AG 2016-10-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/9/11/869
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author Pengfei Liu
Qiuxia Wang
Dongdong Yan
Wensheng Fang
Liangang Mao
Dong Wang
Yuan Li
Canbin Ouyang
Meixia Guo
Aocheng Cao
author_facet Pengfei Liu
Qiuxia Wang
Dongdong Yan
Wensheng Fang
Liangang Mao
Dong Wang
Yuan Li
Canbin Ouyang
Meixia Guo
Aocheng Cao
author_sort Pengfei Liu
collection DOAJ
description The characteristics of biochar vary with pyrolysis temperature. Chloropicrin (CP) is an effective fumigant for controlling soil-borne pests. This study investigated the characteristics of biochars prepared at 300, 500, and 700 °C by michelia alba (Magnolia denudata) wood and evaluated their capacity to adsorb CP. The study also determined the potential influence of biochar, which was added to sterilized and unsterilized soils at rates of 0%, 1%, 5%, and 100%, on CP degradation. The specific surface area, pore volume, and micropores increased considerably with an increase in the pyrolytic temperature. The adsorption rate of biochar for CP increased with increasing pyrolytic temperature. The maximum adsorption amounts of CP were similar for the three biochars. Next, the study examined the degradation ability of the biochar for CP. The degradation rate constant (k) of CP increased when biochar was added to the soil, and k increased with increased amendment rate and pyrolysis temperature. The results indicate that biochar can accelerate CP degradation in soil. The findings will be instructive in using biochar as a new fertilizer in fumigating soil with CP.
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spelling doaj.art-87fc8f753f284fbb8b2fa86a247f82502022-12-22T04:21:07ZengMDPI AGEnergies1996-10732016-10-0191186910.3390/en9110869en9110869Effects of Biochar Amendment on Chloropicrin Adsorption and Degradation in SoilPengfei Liu0Qiuxia Wang1Dongdong Yan2Wensheng Fang3Liangang Mao4Dong Wang5Yuan Li6Canbin Ouyang7Meixia Guo8Aocheng Cao9Southwest Research and Design Institute of Chemical Industry Co., Ltd., Chengdu 610225, ChinaPlant Protection Institute of Chinese Academy of Agricultural Sciences, State Key Laboratory for Biology of Plant Disease and Insect Pest, Beijing 100193, ChinaPlant Protection Institute of Chinese Academy of Agricultural Sciences, State Key Laboratory for Biology of Plant Disease and Insect Pest, Beijing 100193, ChinaPlant Protection Institute of Chinese Academy of Agricultural Sciences, State Key Laboratory for Biology of Plant Disease and Insect Pest, Beijing 100193, ChinaPlant Protection Institute of Chinese Academy of Agricultural Sciences, State Key Laboratory for Biology of Plant Disease and Insect Pest, Beijing 100193, ChinaU.S. Department of Agriculture—Agricultural Research Service (USDA-ARS), Water Management Research Unit, Parlier 93648, CA, USAPlant Protection Institute of Chinese Academy of Agricultural Sciences, State Key Laboratory for Biology of Plant Disease and Insect Pest, Beijing 100193, ChinaPlant Protection Institute of Chinese Academy of Agricultural Sciences, State Key Laboratory for Biology of Plant Disease and Insect Pest, Beijing 100193, ChinaPlant Protection Institute of Chinese Academy of Agricultural Sciences, State Key Laboratory for Biology of Plant Disease and Insect Pest, Beijing 100193, ChinaPlant Protection Institute of Chinese Academy of Agricultural Sciences, State Key Laboratory for Biology of Plant Disease and Insect Pest, Beijing 100193, ChinaThe characteristics of biochar vary with pyrolysis temperature. Chloropicrin (CP) is an effective fumigant for controlling soil-borne pests. This study investigated the characteristics of biochars prepared at 300, 500, and 700 °C by michelia alba (Magnolia denudata) wood and evaluated their capacity to adsorb CP. The study also determined the potential influence of biochar, which was added to sterilized and unsterilized soils at rates of 0%, 1%, 5%, and 100%, on CP degradation. The specific surface area, pore volume, and micropores increased considerably with an increase in the pyrolytic temperature. The adsorption rate of biochar for CP increased with increasing pyrolytic temperature. The maximum adsorption amounts of CP were similar for the three biochars. Next, the study examined the degradation ability of the biochar for CP. The degradation rate constant (k) of CP increased when biochar was added to the soil, and k increased with increased amendment rate and pyrolysis temperature. The results indicate that biochar can accelerate CP degradation in soil. The findings will be instructive in using biochar as a new fertilizer in fumigating soil with CP.http://www.mdpi.com/1996-1073/9/11/869chloropicrinbiocharpyrolysis temperatureadsorptiondegradation
spellingShingle Pengfei Liu
Qiuxia Wang
Dongdong Yan
Wensheng Fang
Liangang Mao
Dong Wang
Yuan Li
Canbin Ouyang
Meixia Guo
Aocheng Cao
Effects of Biochar Amendment on Chloropicrin Adsorption and Degradation in Soil
Energies
chloropicrin
biochar
pyrolysis temperature
adsorption
degradation
title Effects of Biochar Amendment on Chloropicrin Adsorption and Degradation in Soil
title_full Effects of Biochar Amendment on Chloropicrin Adsorption and Degradation in Soil
title_fullStr Effects of Biochar Amendment on Chloropicrin Adsorption and Degradation in Soil
title_full_unstemmed Effects of Biochar Amendment on Chloropicrin Adsorption and Degradation in Soil
title_short Effects of Biochar Amendment on Chloropicrin Adsorption and Degradation in Soil
title_sort effects of biochar amendment on chloropicrin adsorption and degradation in soil
topic chloropicrin
biochar
pyrolysis temperature
adsorption
degradation
url http://www.mdpi.com/1996-1073/9/11/869
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