Physical, Barrier, Mechanical, and Biodegradability Properties of Modified Starch Films with Nut By-Products Extracts

Starch-based films with phenolic extracts could replace the use of petroleum-based plastics. In this study, octenyl succinate starch (OSS) films with pecan nutshell extract (PSE) or hazelnut skin extract (HSE) were prepared. The water resistance, as well as the optical, physical, mechanical, and bio...

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Main Authors: Marcos Leon-Bejarano, Yusuf Durmus, Maribel Ovando-Martínez, Senay Simsek
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Foods
Subjects:
Online Access:https://www.mdpi.com/2304-8158/9/2/226
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author Marcos Leon-Bejarano
Yusuf Durmus
Maribel Ovando-Martínez
Senay Simsek
author_facet Marcos Leon-Bejarano
Yusuf Durmus
Maribel Ovando-Martínez
Senay Simsek
author_sort Marcos Leon-Bejarano
collection DOAJ
description Starch-based films with phenolic extracts could replace the use of petroleum-based plastics. In this study, octenyl succinate starch (OSS) films with pecan nutshell extract (PSE) or hazelnut skin extract (HSE) were prepared. The water resistance, as well as the optical, physical, mechanical, and biodegradable properties of these films, were investigated. The PSE and HSE improved the water resistance (decreasing the solubility to 17% and increasing the contact angle to 96.80°) and UV-light barrier properties of the films. For PSE and HSE, as their concentrations increased, the film rigidity decreased since these extracts acted as plasticizers. Micrographs obtained by scanning electron microscopy (SEM) depicted a homogeneous surface as a result of extracts dispersion through the polymeric matrix and the interactions between the phenolic compounds (PC) of the extracts and the OSS. The phenolic extracts from nut by-products and octenyl succinic anhydride (OSA) starch could be used to develop films to replace the conventional plastics.
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spelling doaj.art-880362a233fc4eb89bda5ba26fd56d272022-12-21T18:59:35ZengMDPI AGFoods2304-81582020-02-019222610.3390/foods9020226foods9020226Physical, Barrier, Mechanical, and Biodegradability Properties of Modified Starch Films with Nut By-Products ExtractsMarcos Leon-Bejarano0Yusuf Durmus1Maribel Ovando-Martínez2Senay Simsek3Departamento de Investigaciones Científicas y Tecnológicas de la Universidad de Sonora, Blvd. Luis Donaldo Colosio s/n, entre Reforma y Sahuaripa, Edificio 7G, Col. Centro. C.P., Hermosillo 83000, Sonora, MexicoDepartment of Food Engineering, Faculty of Agriculture, Ordu University, 52200 Ordu, TurkeyDepartamento de Investigaciones Científicas y Tecnológicas de la Universidad de Sonora, Blvd. Luis Donaldo Colosio s/n, entre Reforma y Sahuaripa, Edificio 7G, Col. Centro. C.P., Hermosillo 83000, Sonora, MexicoDepartment of Plant Sciences, North Dakota State University, PO Box 6050, Dept# 7670, Fargo, ND 58108-6050, USAStarch-based films with phenolic extracts could replace the use of petroleum-based plastics. In this study, octenyl succinate starch (OSS) films with pecan nutshell extract (PSE) or hazelnut skin extract (HSE) were prepared. The water resistance, as well as the optical, physical, mechanical, and biodegradable properties of these films, were investigated. The PSE and HSE improved the water resistance (decreasing the solubility to 17% and increasing the contact angle to 96.80°) and UV-light barrier properties of the films. For PSE and HSE, as their concentrations increased, the film rigidity decreased since these extracts acted as plasticizers. Micrographs obtained by scanning electron microscopy (SEM) depicted a homogeneous surface as a result of extracts dispersion through the polymeric matrix and the interactions between the phenolic compounds (PC) of the extracts and the OSS. The phenolic extracts from nut by-products and octenyl succinic anhydride (OSA) starch could be used to develop films to replace the conventional plastics.https://www.mdpi.com/2304-8158/9/2/226pecan nuthazelnutnut by-productsphenolic compoundsoctenyl succinate starchstarch films
spellingShingle Marcos Leon-Bejarano
Yusuf Durmus
Maribel Ovando-Martínez
Senay Simsek
Physical, Barrier, Mechanical, and Biodegradability Properties of Modified Starch Films with Nut By-Products Extracts
Foods
pecan nut
hazelnut
nut by-products
phenolic compounds
octenyl succinate starch
starch films
title Physical, Barrier, Mechanical, and Biodegradability Properties of Modified Starch Films with Nut By-Products Extracts
title_full Physical, Barrier, Mechanical, and Biodegradability Properties of Modified Starch Films with Nut By-Products Extracts
title_fullStr Physical, Barrier, Mechanical, and Biodegradability Properties of Modified Starch Films with Nut By-Products Extracts
title_full_unstemmed Physical, Barrier, Mechanical, and Biodegradability Properties of Modified Starch Films with Nut By-Products Extracts
title_short Physical, Barrier, Mechanical, and Biodegradability Properties of Modified Starch Films with Nut By-Products Extracts
title_sort physical barrier mechanical and biodegradability properties of modified starch films with nut by products extracts
topic pecan nut
hazelnut
nut by-products
phenolic compounds
octenyl succinate starch
starch films
url https://www.mdpi.com/2304-8158/9/2/226
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AT maribelovandomartinez physicalbarriermechanicalandbiodegradabilitypropertiesofmodifiedstarchfilmswithnutbyproductsextracts
AT senaysimsek physicalbarriermechanicalandbiodegradabilitypropertiesofmodifiedstarchfilmswithnutbyproductsextracts