Study of Coatings Formed on Zirconium Alloy by Plasma Electrolytic Oxidation in Electrolyte with Submicron Yttria Powder Additives

Coatings with thickness 40 to 150 μm were formed by plasma electrolytic oxidation (PEO) on the zirconium alloy Zr-1Nb (Zr-1% Nb) in the slurry electrolyte containing 9 g/L Na<sub>2</sub>SiO<sub>3</sub> 5H<sub>2</sub>O, 5 g/L Na(PH<sub>2</sub>O<sub&g...

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Bibliographic Details
Main Authors: Svetlana Savushkina, Mikhail Gerasimov, Andrey Apelfeld, Igor Suminov
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/11/9/1392
Description
Summary:Coatings with thickness 40 to 150 μm were formed by plasma electrolytic oxidation (PEO) on the zirconium alloy Zr-1Nb (Zr-1% Nb) in the slurry electrolyte containing 9 g/L Na<sub>2</sub>SiO<sub>3</sub> 5H<sub>2</sub>O, 5 g/L Na(PH<sub>2</sub>O<sub>2</sub>) and 6 g/L submicron Y<sub>2</sub>O<sub>3</sub> yttria powder during 60 min under the AC electrical mode at current densities 20; 30 and 40 A/dm<sup>2</sup>. The surface morphology, structure, composition, and corrosion-protective ability of the formed coatings have been analyzed. At PEO current density 30 A/dm<sup>2</sup>, a predominantly tetragonal phase of zirconia was formed in coatings. Increasing the PEO current density up to 40 A/dm<sup>2</sup> promoted the formation of the coating surface layer containing submicron yttria particles. Electrochemical polarization studies in 0.5% LiOH solution showed that PEO coatings demonstrated high corrosion-protective ability. The dependence of the polarization currents on the PEO current density was found to be inconsequential.
ISSN:2075-4701