Preliminary study of all-solid-state batteries: Evaluation of blast formation during the thermal runaway

Summary: All-solid-state batteries have been developed to increase energy density by replacing the lithiated graphite negative electrode by a lithium metal foil and to increase safety by removing the organic compounds. However, the safety issues of these batteries have received little attention up t...

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Main Authors: Juliette Charbonnel, Sébastien Dubourg, Etienne Testard, Ludovic Broche, Christophe Magnier, Thibaut Rochard, Daniel Marteau, Pierre-Xavier Thivel, Rémi Vincent
Format: Article
Language:English
Published: Elsevier 2023-11-01
Series:iScience
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2589004223021557
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author Juliette Charbonnel
Sébastien Dubourg
Etienne Testard
Ludovic Broche
Christophe Magnier
Thibaut Rochard
Daniel Marteau
Pierre-Xavier Thivel
Rémi Vincent
author_facet Juliette Charbonnel
Sébastien Dubourg
Etienne Testard
Ludovic Broche
Christophe Magnier
Thibaut Rochard
Daniel Marteau
Pierre-Xavier Thivel
Rémi Vincent
author_sort Juliette Charbonnel
collection DOAJ
description Summary: All-solid-state batteries have been developed to increase energy density by replacing the lithiated graphite negative electrode by a lithium metal foil and to increase safety by removing the organic compounds. However, the safety issues of these batteries have received little attention up to now.The behavior of a reassembled all-solid-state battery under thermal stress was recorded by X-ray radiography and a high-speed camera. The thermal runaway (TR) lasted about 5 ms, thus extremely fast reaction kinetics. In comparison, the TR of a lithium-ion battery is about 500 ms. Furthermore, a 188-mbar aerial overpressure was measured using a piezoelectric sensor. Although this cell is not an explosive, 2.7 g TNT equivalent was calculated for it.This atypical behavior could have an impact on the casing or the battery pack. Therefore, it must be studied in greater detail.
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spelling doaj.art-88247698f1ef4d5b8557190ef4dc18b92023-10-15T04:38:04ZengElsevieriScience2589-00422023-11-012611108078Preliminary study of all-solid-state batteries: Evaluation of blast formation during the thermal runawayJuliette Charbonnel0Sébastien Dubourg1Etienne Testard2Ludovic Broche3Christophe Magnier4Thibaut Rochard5Daniel Marteau6Pierre-Xavier Thivel7Rémi Vincent8University Grenoble Alpes, CEA, LITEN, DEHT, 38000 Grenoble, France; University Grenoble Alpes, University Savoie Mont Blanc, CNRS, Grenoble INP, LEPMI, 38000 Grenoble, FranceCEA/Le Ripault, BP 16, 37260 Monts, FranceCEA/Le Ripault, BP 16, 37260 Monts, FranceEuropean Synchrotron Radiation Facility (ESRF), 38000 Grenoble, FranceCEA/Le Ripault, BP 16, 37260 Monts, FranceCEA/Le Ripault, BP 16, 37260 Monts, FranceCEA/Le Ripault, BP 16, 37260 Monts, FranceUniversity Grenoble Alpes, University Savoie Mont Blanc, CNRS, Grenoble INP, LEPMI, 38000 Grenoble, FranceUniversity Grenoble Alpes, CEA, LITEN, DEHT, 38000 Grenoble, France; Corresponding authorSummary: All-solid-state batteries have been developed to increase energy density by replacing the lithiated graphite negative electrode by a lithium metal foil and to increase safety by removing the organic compounds. However, the safety issues of these batteries have received little attention up to now.The behavior of a reassembled all-solid-state battery under thermal stress was recorded by X-ray radiography and a high-speed camera. The thermal runaway (TR) lasted about 5 ms, thus extremely fast reaction kinetics. In comparison, the TR of a lithium-ion battery is about 500 ms. Furthermore, a 188-mbar aerial overpressure was measured using a piezoelectric sensor. Although this cell is not an explosive, 2.7 g TNT equivalent was calculated for it.This atypical behavior could have an impact on the casing or the battery pack. Therefore, it must be studied in greater detail.http://www.sciencedirect.com/science/article/pii/S2589004223021557CancerComputational bioinformaticsHealth informaticsPathology
spellingShingle Juliette Charbonnel
Sébastien Dubourg
Etienne Testard
Ludovic Broche
Christophe Magnier
Thibaut Rochard
Daniel Marteau
Pierre-Xavier Thivel
Rémi Vincent
Preliminary study of all-solid-state batteries: Evaluation of blast formation during the thermal runaway
iScience
Cancer
Computational bioinformatics
Health informatics
Pathology
title Preliminary study of all-solid-state batteries: Evaluation of blast formation during the thermal runaway
title_full Preliminary study of all-solid-state batteries: Evaluation of blast formation during the thermal runaway
title_fullStr Preliminary study of all-solid-state batteries: Evaluation of blast formation during the thermal runaway
title_full_unstemmed Preliminary study of all-solid-state batteries: Evaluation of blast formation during the thermal runaway
title_short Preliminary study of all-solid-state batteries: Evaluation of blast formation during the thermal runaway
title_sort preliminary study of all solid state batteries evaluation of blast formation during the thermal runaway
topic Cancer
Computational bioinformatics
Health informatics
Pathology
url http://www.sciencedirect.com/science/article/pii/S2589004223021557
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