cis-(Acetato-κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate
The complete cation in the title hydrated molecular salt, [Ni(CH3CO2)(C16H36N4)]ClO4·H2O, is generated by the application of crystallographic twofold symmetry; the perchlorate anion and water molecule are each disordered around a twofold axis. The NiII atom exists within a cis-N4O2 dono...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-04-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812013232 |
| _version_ | 1818958444339658752 |
|---|---|
| author | Tapashi G. Roy Debashis Palit Babul Chandra Nath Seik Weng Ng Edward R. T. Tiekink |
| author_facet | Tapashi G. Roy Debashis Palit Babul Chandra Nath Seik Weng Ng Edward R. T. Tiekink |
| author_sort | Tapashi G. Roy |
| collection | DOAJ |
| description | The complete cation in the title hydrated molecular salt, [Ni(CH3CO2)(C16H36N4)]ClO4·H2O, is generated by the application of crystallographic twofold symmetry; the perchlorate anion and water molecule are each disordered around a twofold axis. The NiII atom exists within a cis-N4O2 donor set based on a strongly distorted octahedron and defined by the four N atoms of the macrocyclic ligand and two O atoms of a symmetrically coordinating acetate ligand. In the crystal, hydrogen bonding (water–acetate/perchlorate O—H...O and amine–perchlorate N—H...O) leads to layers in the ab plane. The layers stack along the c axis, being connected by C—H...O(water) interactions. The crystal studied was found to be a non-merohedral twin; the minor component refined to 15.9 (6)%. |
| first_indexed | 2024-12-20T11:25:50Z |
| format | Article |
| id | doaj.art-8826f838a4ef4e71b6a67a10b2c6468b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:25:50Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8826f838a4ef4e71b6a67a10b2c6468b2022-12-21T19:42:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m525m52610.1107/S1600536812013232cis-(Acetato-κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrateTapashi G. RoyDebashis PalitBabul Chandra NathSeik Weng NgEdward R. T. TiekinkThe complete cation in the title hydrated molecular salt, [Ni(CH3CO2)(C16H36N4)]ClO4·H2O, is generated by the application of crystallographic twofold symmetry; the perchlorate anion and water molecule are each disordered around a twofold axis. The NiII atom exists within a cis-N4O2 donor set based on a strongly distorted octahedron and defined by the four N atoms of the macrocyclic ligand and two O atoms of a symmetrically coordinating acetate ligand. In the crystal, hydrogen bonding (water–acetate/perchlorate O—H...O and amine–perchlorate N—H...O) leads to layers in the ab plane. The layers stack along the c axis, being connected by C—H...O(water) interactions. The crystal studied was found to be a non-merohedral twin; the minor component refined to 15.9 (6)%.http://scripts.iucr.org/cgi-bin/paper?S1600536812013232 |
| spellingShingle | Tapashi G. Roy Debashis Palit Babul Chandra Nath Seik Weng Ng Edward R. T. Tiekink cis-(Acetato-κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate Acta Crystallographica Section E |
| title | cis-(Acetato-κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_full | cis-(Acetato-κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_fullStr | cis-(Acetato-κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_full_unstemmed | cis-(Acetato-κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_short | cis-(Acetato-κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_sort | cis acetato amp 954 2o o amp 8242 5 5 7 12 12 14 hexamethyl 1 4 8 11 tetraazacyclotetradecane amp 954 4n n amp 8242 n amp 8242 amp 8242 n amp 8242 amp 8242 amp 8242 nickel ii perchlorate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812013232 |
| work_keys_str_mv | AT tapashigroy cisacetatoamp9542ooamp8242557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchloratemonohydrate AT debashispalit cisacetatoamp9542ooamp8242557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchloratemonohydrate AT babulchandranath cisacetatoamp9542ooamp8242557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchloratemonohydrate AT seikwengng cisacetatoamp9542ooamp8242557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchloratemonohydrate AT edwardrttiekink cisacetatoamp9542ooamp8242557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchloratemonohydrate |