Synthesis and Characterisation of ASA-PEEK Composites for Fused Filament Fabrication

In this paper, a series of polymer composites made from acrylonitrile-styrene-acrylate (ASA) and poly (ether ether ketone) (PEEK) were manufactured. ASA acts as a polymer matrix while PEEK is loaded in the form of micro-particles that act as a reinforcing filler. The composites were compounded by si...

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Main Authors: Belén Palacios-Ibáñez, José J. Relinque, Daniel Moreno-Sánchez, Alberto S. de León, Francisco J. Delgado, Ramón Escobar-Galindo, Sergio I. Molina
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/3/496
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author Belén Palacios-Ibáñez
José J. Relinque
Daniel Moreno-Sánchez
Alberto S. de León
Francisco J. Delgado
Ramón Escobar-Galindo
Sergio I. Molina
author_facet Belén Palacios-Ibáñez
José J. Relinque
Daniel Moreno-Sánchez
Alberto S. de León
Francisco J. Delgado
Ramón Escobar-Galindo
Sergio I. Molina
author_sort Belén Palacios-Ibáñez
collection DOAJ
description In this paper, a series of polymer composites made from acrylonitrile-styrene-acrylate (ASA) and poly (ether ether ketone) (PEEK) were manufactured. ASA acts as a polymer matrix while PEEK is loaded in the form of micro-particles that act as a reinforcing filler. The composites were compounded by single screw extrusion and then, different specimens were manufactured either via injection moulding (IM) or fused filament fabrication (FFF). Two different types of PEEK (commercial and reused) in different concentrations (3 and 6 wt.%) were tested and their influence in the mechanical, structural, and thermal properties were studied. It was observed that reused PEEK enhanced the stiffness and tensile strength and thermal stability of the composites both, for injected and printed specimens. This evidences the suitability of these composites as potential candidates as novel materials with enhanced properties following an approach of circular economy.
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spelling doaj.art-8868ec49febb48cb851b3f4bfb2358692023-11-23T17:34:47ZengMDPI AGPolymers2073-43602022-01-0114349610.3390/polym14030496Synthesis and Characterisation of ASA-PEEK Composites for Fused Filament FabricationBelén Palacios-Ibáñez0José J. Relinque1Daniel Moreno-Sánchez2Alberto S. de León3Francisco J. Delgado4Ramón Escobar-Galindo5Sergio I. Molina6Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, IMEYMAT, Facultad de Ciencias, Campus Río San Pedro s/n, Universidad de Cádiz, 11510 Puerto Real (Cádiz), SpainDepartamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, IMEYMAT, Facultad de Ciencias, Campus Río San Pedro s/n, Universidad de Cádiz, 11510 Puerto Real (Cádiz), SpainDepartamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, IMEYMAT, Facultad de Ciencias, Campus Río San Pedro s/n, Universidad de Cádiz, 11510 Puerto Real (Cádiz), SpainDepartamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, IMEYMAT, Facultad de Ciencias, Campus Río San Pedro s/n, Universidad de Cádiz, 11510 Puerto Real (Cádiz), SpainDepartamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, IMEYMAT, Facultad de Ciencias, Campus Río San Pedro s/n, Universidad de Cádiz, 11510 Puerto Real (Cádiz), SpainDepartamento de Física Aplicada, Escuela Politécnica Superior, Universidad de Sevilla, C/Virgen de África 7, 41011 Sevilla, SpainDepartamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, IMEYMAT, Facultad de Ciencias, Campus Río San Pedro s/n, Universidad de Cádiz, 11510 Puerto Real (Cádiz), SpainIn this paper, a series of polymer composites made from acrylonitrile-styrene-acrylate (ASA) and poly (ether ether ketone) (PEEK) were manufactured. ASA acts as a polymer matrix while PEEK is loaded in the form of micro-particles that act as a reinforcing filler. The composites were compounded by single screw extrusion and then, different specimens were manufactured either via injection moulding (IM) or fused filament fabrication (FFF). Two different types of PEEK (commercial and reused) in different concentrations (3 and 6 wt.%) were tested and their influence in the mechanical, structural, and thermal properties were studied. It was observed that reused PEEK enhanced the stiffness and tensile strength and thermal stability of the composites both, for injected and printed specimens. This evidences the suitability of these composites as potential candidates as novel materials with enhanced properties following an approach of circular economy.https://www.mdpi.com/2073-4360/14/3/496thermoplastic polymerscomposite materialsfused filament fabricationmechanical propertiesthermal properties
spellingShingle Belén Palacios-Ibáñez
José J. Relinque
Daniel Moreno-Sánchez
Alberto S. de León
Francisco J. Delgado
Ramón Escobar-Galindo
Sergio I. Molina
Synthesis and Characterisation of ASA-PEEK Composites for Fused Filament Fabrication
Polymers
thermoplastic polymers
composite materials
fused filament fabrication
mechanical properties
thermal properties
title Synthesis and Characterisation of ASA-PEEK Composites for Fused Filament Fabrication
title_full Synthesis and Characterisation of ASA-PEEK Composites for Fused Filament Fabrication
title_fullStr Synthesis and Characterisation of ASA-PEEK Composites for Fused Filament Fabrication
title_full_unstemmed Synthesis and Characterisation of ASA-PEEK Composites for Fused Filament Fabrication
title_short Synthesis and Characterisation of ASA-PEEK Composites for Fused Filament Fabrication
title_sort synthesis and characterisation of asa peek composites for fused filament fabrication
topic thermoplastic polymers
composite materials
fused filament fabrication
mechanical properties
thermal properties
url https://www.mdpi.com/2073-4360/14/3/496
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AT albertosdeleon synthesisandcharacterisationofasapeekcompositesforfusedfilamentfabrication
AT franciscojdelgado synthesisandcharacterisationofasapeekcompositesforfusedfilamentfabrication
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