Burning characteristics of high density foamed GAP/CL-20 propellants

The monolithic foamed propellants with high densities were prepared by casting and two-step foaming processes. Glycidyl azide polymer (GAP) and isocyanate were used as the binder system and 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW, CL-20) was employed as the energetic compone...

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Main Authors: Man-man Li, Rui Hu, Ming-hui Xu, Qiong-lin Wang, Wei-tao Yang
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2022-10-01
Series:Defence Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2214914721001422
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author Man-man Li
Rui Hu
Ming-hui Xu
Qiong-lin Wang
Wei-tao Yang
author_facet Man-man Li
Rui Hu
Ming-hui Xu
Qiong-lin Wang
Wei-tao Yang
author_sort Man-man Li
collection DOAJ
description The monolithic foamed propellants with high densities were prepared by casting and two-step foaming processes. Glycidyl azide polymer (GAP) and isocyanate were used as the binder system and 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW, CL-20) was employed as the energetic component. The newly designed formulation containing 60 % CL-20 produced a force constant of 1077 J/g and low flame temperature of 2817 K. Two foamed propellants with densities of 1.32 g/cm3 and 1.53 g/cm3 were fabricated by a confined foaming process and examined by closed bomb tests. The results revealed that porosity significantly affects burning performance. A size effect on combustion behaviors was observed for the foamed propellant with 5.56 % porosity, and a double-hump progressive dynamic vivacity curve was obtained. At last, the 30 mm gun test was carried out to demonstrate the interior ballistic performance, and the muzzle velocity increased by 120 m/s at the same maximum chamber pressure when monolithic propellant was added in the charge.
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spelling doaj.art-88879284946a42bb830c35b0d3f88c802022-12-22T02:35:20ZengKeAi Communications Co., Ltd.Defence Technology2214-91472022-10-01181019141921Burning characteristics of high density foamed GAP/CL-20 propellantsMan-man Li0Rui Hu1Ming-hui Xu2Qiong-lin Wang3Wei-tao Yang4Xi'an Modern Chemistry Research Institute, Xi'an, 710065, PR ChinaXi'an Modern Chemistry Research Institute, Xi'an, 710065, PR ChinaXi'an Modern Chemistry Research Institute, Xi'an, 710065, PR ChinaXi'an Modern Chemistry Research Institute, Xi'an, 710065, PR ChinaXi'an Modern Chemistry Research Institute, Xi'an, 710065, PR China; School of Physics, Xi'an Jiaotong University, Xi'an, 710049, PR China; Corresponding author. Xi'an Modern Chemistry Research Institute, Xi'an, 710065, PR China.The monolithic foamed propellants with high densities were prepared by casting and two-step foaming processes. Glycidyl azide polymer (GAP) and isocyanate were used as the binder system and 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW, CL-20) was employed as the energetic component. The newly designed formulation containing 60 % CL-20 produced a force constant of 1077 J/g and low flame temperature of 2817 K. Two foamed propellants with densities of 1.32 g/cm3 and 1.53 g/cm3 were fabricated by a confined foaming process and examined by closed bomb tests. The results revealed that porosity significantly affects burning performance. A size effect on combustion behaviors was observed for the foamed propellant with 5.56 % porosity, and a double-hump progressive dynamic vivacity curve was obtained. At last, the 30 mm gun test was carried out to demonstrate the interior ballistic performance, and the muzzle velocity increased by 120 m/s at the same maximum chamber pressure when monolithic propellant was added in the charge.http://www.sciencedirect.com/science/article/pii/S2214914721001422Monolithic foamed propellantsTwo-step foaming processCasting processGAP/CL-20
spellingShingle Man-man Li
Rui Hu
Ming-hui Xu
Qiong-lin Wang
Wei-tao Yang
Burning characteristics of high density foamed GAP/CL-20 propellants
Defence Technology
Monolithic foamed propellants
Two-step foaming process
Casting process
GAP/CL-20
title Burning characteristics of high density foamed GAP/CL-20 propellants
title_full Burning characteristics of high density foamed GAP/CL-20 propellants
title_fullStr Burning characteristics of high density foamed GAP/CL-20 propellants
title_full_unstemmed Burning characteristics of high density foamed GAP/CL-20 propellants
title_short Burning characteristics of high density foamed GAP/CL-20 propellants
title_sort burning characteristics of high density foamed gap cl 20 propellants
topic Monolithic foamed propellants
Two-step foaming process
Casting process
GAP/CL-20
url http://www.sciencedirect.com/science/article/pii/S2214914721001422
work_keys_str_mv AT manmanli burningcharacteristicsofhighdensityfoamedgapcl20propellants
AT ruihu burningcharacteristicsofhighdensityfoamedgapcl20propellants
AT minghuixu burningcharacteristicsofhighdensityfoamedgapcl20propellants
AT qionglinwang burningcharacteristicsofhighdensityfoamedgapcl20propellants
AT weitaoyang burningcharacteristicsofhighdensityfoamedgapcl20propellants