Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography

Synthesis of a homologous series of photo-polymerizable α,w-polytetrahydrofuranether-diacrylate (PTHF-DA) resins is described with characterization by NMR, GPC, DSC, soaking and rheometrical measurements. The curing speeds of the resins are determined under UV light exposure. Young’s modulus and ten...

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Main Authors: Michael Wegener, Burkhard Elling, Esther Novosel, Sascha Engelhardt, Wolfdietrich Meyer, Hartmut Krüger
Format: Article
Language:English
Published: MDPI AG 2012-03-01
Series:Journal of Functional Biomaterials
Subjects:
Online Access:http://www.mdpi.com/2079-4983/3/2/257/
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author Michael Wegener
Burkhard Elling
Esther Novosel
Sascha Engelhardt
Wolfdietrich Meyer
Hartmut Krüger
author_facet Michael Wegener
Burkhard Elling
Esther Novosel
Sascha Engelhardt
Wolfdietrich Meyer
Hartmut Krüger
author_sort Michael Wegener
collection DOAJ
description Synthesis of a homologous series of photo-polymerizable α,w-polytetrahydrofuranether-diacrylate (PTHF-DA) resins is described with characterization by NMR, GPC, DSC, soaking and rheometrical measurements. The curing speeds of the resins are determined under UV light exposure. Young’s modulus and tensile strength of fully cured resins show flexible to soft material attributes dependent on the molar mass of the used linear PTHF-diacrylates. Structuring the materials by stereo lithography (SL) and multiphoton polymerization (MPP) leads to tubes and bifurcated tube systems with a diameter smaller than 2 mm aimed at small to smallest supplying systems with capillary dimensions. WST-1 biocompatibility tests ofm polymer extracts show nontoxic characteristics of the adapted polymers after a washing process. Some polymers show shape memory effect (SME).
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spelling doaj.art-888dd8e2afba4bd3bfc96c252f04b4d72022-12-22T02:06:45ZengMDPI AGJournal of Functional Biomaterials2079-49832012-03-013225726810.3390/jfb3020257Soft Polymers for Building up Small and Smallest Blood Supplying Systems by StereolithographyMichael WegenerBurkhard EllingEsther NovoselSascha EngelhardtWolfdietrich MeyerHartmut KrügerSynthesis of a homologous series of photo-polymerizable α,w-polytetrahydrofuranether-diacrylate (PTHF-DA) resins is described with characterization by NMR, GPC, DSC, soaking and rheometrical measurements. The curing speeds of the resins are determined under UV light exposure. Young’s modulus and tensile strength of fully cured resins show flexible to soft material attributes dependent on the molar mass of the used linear PTHF-diacrylates. Structuring the materials by stereo lithography (SL) and multiphoton polymerization (MPP) leads to tubes and bifurcated tube systems with a diameter smaller than 2 mm aimed at small to smallest supplying systems with capillary dimensions. WST-1 biocompatibility tests ofm polymer extracts show nontoxic characteristics of the adapted polymers after a washing process. Some polymers show shape memory effect (SME).http://www.mdpi.com/2079-4983/3/2/257/functional biopolymersbiocompatibilitybiomedical devicestissue devicesrapid prototyping
spellingShingle Michael Wegener
Burkhard Elling
Esther Novosel
Sascha Engelhardt
Wolfdietrich Meyer
Hartmut Krüger
Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography
Journal of Functional Biomaterials
functional biopolymers
biocompatibility
biomedical devices
tissue devices
rapid prototyping
title Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography
title_full Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography
title_fullStr Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography
title_full_unstemmed Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography
title_short Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography
title_sort soft polymers for building up small and smallest blood supplying systems by stereolithography
topic functional biopolymers
biocompatibility
biomedical devices
tissue devices
rapid prototyping
url http://www.mdpi.com/2079-4983/3/2/257/
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