Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography
Synthesis of a homologous series of photo-polymerizable α,w-polytetrahydrofuranether-diacrylate (PTHF-DA) resins is described with characterization by NMR, GPC, DSC, soaking and rheometrical measurements. The curing speeds of the resins are determined under UV light exposure. Young’s modulus and ten...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2012-03-01
|
Series: | Journal of Functional Biomaterials |
Subjects: | |
Online Access: | http://www.mdpi.com/2079-4983/3/2/257/ |
_version_ | 1818015708846489600 |
---|---|
author | Michael Wegener Burkhard Elling Esther Novosel Sascha Engelhardt Wolfdietrich Meyer Hartmut Krüger |
author_facet | Michael Wegener Burkhard Elling Esther Novosel Sascha Engelhardt Wolfdietrich Meyer Hartmut Krüger |
author_sort | Michael Wegener |
collection | DOAJ |
description | Synthesis of a homologous series of photo-polymerizable α,w-polytetrahydrofuranether-diacrylate (PTHF-DA) resins is described with characterization by NMR, GPC, DSC, soaking and rheometrical measurements. The curing speeds of the resins are determined under UV light exposure. Young’s modulus and tensile strength of fully cured resins show flexible to soft material attributes dependent on the molar mass of the used linear PTHF-diacrylates. Structuring the materials by stereo lithography (SL) and multiphoton polymerization (MPP) leads to tubes and bifurcated tube systems with a diameter smaller than 2 mm aimed at small to smallest supplying systems with capillary dimensions. WST-1 biocompatibility tests ofm polymer extracts show nontoxic characteristics of the adapted polymers after a washing process. Some polymers show shape memory effect (SME). |
first_indexed | 2024-04-14T07:01:32Z |
format | Article |
id | doaj.art-888dd8e2afba4bd3bfc96c252f04b4d7 |
institution | Directory Open Access Journal |
issn | 2079-4983 |
language | English |
last_indexed | 2024-04-14T07:01:32Z |
publishDate | 2012-03-01 |
publisher | MDPI AG |
record_format | Article |
series | Journal of Functional Biomaterials |
spelling | doaj.art-888dd8e2afba4bd3bfc96c252f04b4d72022-12-22T02:06:45ZengMDPI AGJournal of Functional Biomaterials2079-49832012-03-013225726810.3390/jfb3020257Soft Polymers for Building up Small and Smallest Blood Supplying Systems by StereolithographyMichael WegenerBurkhard EllingEsther NovoselSascha EngelhardtWolfdietrich MeyerHartmut KrügerSynthesis of a homologous series of photo-polymerizable α,w-polytetrahydrofuranether-diacrylate (PTHF-DA) resins is described with characterization by NMR, GPC, DSC, soaking and rheometrical measurements. The curing speeds of the resins are determined under UV light exposure. Young’s modulus and tensile strength of fully cured resins show flexible to soft material attributes dependent on the molar mass of the used linear PTHF-diacrylates. Structuring the materials by stereo lithography (SL) and multiphoton polymerization (MPP) leads to tubes and bifurcated tube systems with a diameter smaller than 2 mm aimed at small to smallest supplying systems with capillary dimensions. WST-1 biocompatibility tests ofm polymer extracts show nontoxic characteristics of the adapted polymers after a washing process. Some polymers show shape memory effect (SME).http://www.mdpi.com/2079-4983/3/2/257/functional biopolymersbiocompatibilitybiomedical devicestissue devicesrapid prototyping |
spellingShingle | Michael Wegener Burkhard Elling Esther Novosel Sascha Engelhardt Wolfdietrich Meyer Hartmut Krüger Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography Journal of Functional Biomaterials functional biopolymers biocompatibility biomedical devices tissue devices rapid prototyping |
title | Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography |
title_full | Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography |
title_fullStr | Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography |
title_full_unstemmed | Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography |
title_short | Soft Polymers for Building up Small and Smallest Blood Supplying Systems by Stereolithography |
title_sort | soft polymers for building up small and smallest blood supplying systems by stereolithography |
topic | functional biopolymers biocompatibility biomedical devices tissue devices rapid prototyping |
url | http://www.mdpi.com/2079-4983/3/2/257/ |
work_keys_str_mv | AT michaelwegener softpolymersforbuildingupsmallandsmallestbloodsupplyingsystemsbystereolithography AT burkhardelling softpolymersforbuildingupsmallandsmallestbloodsupplyingsystemsbystereolithography AT esthernovosel softpolymersforbuildingupsmallandsmallestbloodsupplyingsystemsbystereolithography AT saschaengelhardt softpolymersforbuildingupsmallandsmallestbloodsupplyingsystemsbystereolithography AT wolfdietrichmeyer softpolymersforbuildingupsmallandsmallestbloodsupplyingsystemsbystereolithography AT hartmutkruger softpolymersforbuildingupsmallandsmallestbloodsupplyingsystemsbystereolithography |