Reduction in Technogenic Burden on the Environment by Flotation Recovery of Rare Earth Elements from Diluted Industrial Solutions

Unconventional raw materials are widely used in construction sectors; for example, phosphate sludge with the addition of rare earth elements (REE) when producing brick. The second example is nanostructured composite systems of REE when forming covers of construction materials. This article studies f...

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Main Authors: Natalia Dzhevaga, Olga Lobacheva
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/11/16/7452
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author Natalia Dzhevaga
Olga Lobacheva
author_facet Natalia Dzhevaga
Olga Lobacheva
author_sort Natalia Dzhevaga
collection DOAJ
description Unconventional raw materials are widely used in construction sectors; for example, phosphate sludge with the addition of rare earth elements (REE) when producing brick. The second example is nanostructured composite systems of REE when forming covers of construction materials. This article studies flotation recovery of REE, the impact of chlorides on distribution coefficient, and pH recovery. The study proves the possibility of effective REE recovery from diluted industrial solutions and, consequently, the significant decrease in their content in wastewaters, which allows the improvement of the ecological situation in the industrial plant areas. In this article, optimum flotation conditions of REE by flotation are given by the example of yttrium (III) and lanthanum (III) salts. The processes of rare earth elements recovery by sodium dodecyl sulphate as salts of various compositions were studied. Distribution coefficients for target components as a function of aqueous phase pH and the presence of foreign anions were determined. The analysis of dependences obtained by the comparison of rare earth elements’ chloro and hydroxo complexes stability constants was made. The products of REE obtained by the authors will be used when manufacturing various kinds of building materials: carbon cement, baked brick, light construction materials, and high-tensile steel.
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spelling doaj.art-88999fcf6e43431cad4c09aeb0733b6a2023-11-22T06:41:54ZengMDPI AGApplied Sciences2076-34172021-08-011116745210.3390/app11167452Reduction in Technogenic Burden on the Environment by Flotation Recovery of Rare Earth Elements from Diluted Industrial SolutionsNatalia Dzhevaga0Olga Lobacheva1Department of Geoecology, Saint-Petersburg Mining University, Vasilievskiy Island, 21st Line, 2, 199106 Saint-Petersburg, RussiaDepartment of General Chemistry, Saint-Petersburg Mining University, Vasilievskiy Island, 21st Line, 2, 199106 Saint-Petersburg, RussiaUnconventional raw materials are widely used in construction sectors; for example, phosphate sludge with the addition of rare earth elements (REE) when producing brick. The second example is nanostructured composite systems of REE when forming covers of construction materials. This article studies flotation recovery of REE, the impact of chlorides on distribution coefficient, and pH recovery. The study proves the possibility of effective REE recovery from diluted industrial solutions and, consequently, the significant decrease in their content in wastewaters, which allows the improvement of the ecological situation in the industrial plant areas. In this article, optimum flotation conditions of REE by flotation are given by the example of yttrium (III) and lanthanum (III) salts. The processes of rare earth elements recovery by sodium dodecyl sulphate as salts of various compositions were studied. Distribution coefficients for target components as a function of aqueous phase pH and the presence of foreign anions were determined. The analysis of dependences obtained by the comparison of rare earth elements’ chloro and hydroxo complexes stability constants was made. The products of REE obtained by the authors will be used when manufacturing various kinds of building materials: carbon cement, baked brick, light construction materials, and high-tensile steel.https://www.mdpi.com/2076-3417/11/16/7452ion flotationlanthanum (III)yttrium (III)recoverytechnogenic burdenconstruction materials
spellingShingle Natalia Dzhevaga
Olga Lobacheva
Reduction in Technogenic Burden on the Environment by Flotation Recovery of Rare Earth Elements from Diluted Industrial Solutions
Applied Sciences
ion flotation
lanthanum (III)
yttrium (III)
recovery
technogenic burden
construction materials
title Reduction in Technogenic Burden on the Environment by Flotation Recovery of Rare Earth Elements from Diluted Industrial Solutions
title_full Reduction in Technogenic Burden on the Environment by Flotation Recovery of Rare Earth Elements from Diluted Industrial Solutions
title_fullStr Reduction in Technogenic Burden on the Environment by Flotation Recovery of Rare Earth Elements from Diluted Industrial Solutions
title_full_unstemmed Reduction in Technogenic Burden on the Environment by Flotation Recovery of Rare Earth Elements from Diluted Industrial Solutions
title_short Reduction in Technogenic Burden on the Environment by Flotation Recovery of Rare Earth Elements from Diluted Industrial Solutions
title_sort reduction in technogenic burden on the environment by flotation recovery of rare earth elements from diluted industrial solutions
topic ion flotation
lanthanum (III)
yttrium (III)
recovery
technogenic burden
construction materials
url https://www.mdpi.com/2076-3417/11/16/7452
work_keys_str_mv AT nataliadzhevaga reductionintechnogenicburdenontheenvironmentbyflotationrecoveryofrareearthelementsfromdilutedindustrialsolutions
AT olgalobacheva reductionintechnogenicburdenontheenvironmentbyflotationrecoveryofrareearthelementsfromdilutedindustrialsolutions