Analysis of crystallographic and structural data of polymeric iron-alkaline metal complexes
The present review covers almost 100 polymeric MFe (M=Li, Na, K, Rb, and Cs) compounds. The metal atoms of group 1 as partners with iron atom build up complex polymeric chains. The iron atoms are found in the oxidation states 0, +2, and +3, of which the oxidation state +3 prevails. The coordination...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2011-12-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2012-0900 |
| _version_ | 1818737918844338176 |
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| author | Melnik Milan Sundberg Markku Rafael Uggla Rolf |
| author_facet | Melnik Milan Sundberg Markku Rafael Uggla Rolf |
| author_sort | Melnik Milan |
| collection | DOAJ |
| description | The present review covers almost 100 polymeric MFe (M=Li, Na, K, Rb, and Cs) compounds. The metal atoms of group 1 as partners with iron atom build up complex polymeric chains. The iron atoms are found in the oxidation states 0, +2, and +3, of which the oxidation state +3 prevails. The coordination number of the iron atom ranges from 2 to 10 (sandwiched). The coordination sphere about the main group 1 metals varies, ranging from tetrahedral to mostly trigonal bipyramid. There are also higher coordination numbers involved, namely, from 6 to 10. The most common ligand atoms are oxygen and nitrogen. There are three compounds displaying distortion isomerism. Several relationships between structural parameters are found and discussed. |
| first_indexed | 2024-12-18T01:00:41Z |
| format | Article |
| id | doaj.art-889adec7d0b74a5295890afc4e8ea236 |
| institution | Directory Open Access Journal |
| issn | 0792-1241 2191-0219 |
| language | English |
| last_indexed | 2024-12-18T01:00:41Z |
| publishDate | 2011-12-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Main Group Metal Chemistry |
| spelling | doaj.art-889adec7d0b74a5295890afc4e8ea2362022-12-21T21:26:24ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192011-12-01345-69312610.1515/mgmc-2012-0900Analysis of crystallographic and structural data of polymeric iron-alkaline metal complexesMelnik Milan0Sundberg Markku Rafael1Uggla Rolf2Department of Inorganic Chemistry, Slovak Technical University, Radlinskeho 9, 81237 Bratislava, Slovak RepublicLaboratory of Inorganic Chemistry, Department of Chemistry, University of Helsinki, PO Box 55, 00014 Helsinki, FinlandLaboratory of Inorganic Chemistry, Department of Chemistry, University of Helsinki, PO Box 55, 00014 Helsinki, FinlandThe present review covers almost 100 polymeric MFe (M=Li, Na, K, Rb, and Cs) compounds. The metal atoms of group 1 as partners with iron atom build up complex polymeric chains. The iron atoms are found in the oxidation states 0, +2, and +3, of which the oxidation state +3 prevails. The coordination number of the iron atom ranges from 2 to 10 (sandwiched). The coordination sphere about the main group 1 metals varies, ranging from tetrahedral to mostly trigonal bipyramid. There are also higher coordination numbers involved, namely, from 6 to 10. The most common ligand atoms are oxygen and nitrogen. There are three compounds displaying distortion isomerism. Several relationships between structural parameters are found and discussed.https://doi.org/10.1515/mgmc-2012-0900classificationfemm=alkaline metalpolymericstructure |
| spellingShingle | Melnik Milan Sundberg Markku Rafael Uggla Rolf Analysis of crystallographic and structural data of polymeric iron-alkaline metal complexes Main Group Metal Chemistry classification fem m=alkaline metal polymeric structure |
| title | Analysis of crystallographic and structural data of polymeric iron-alkaline metal complexes |
| title_full | Analysis of crystallographic and structural data of polymeric iron-alkaline metal complexes |
| title_fullStr | Analysis of crystallographic and structural data of polymeric iron-alkaline metal complexes |
| title_full_unstemmed | Analysis of crystallographic and structural data of polymeric iron-alkaline metal complexes |
| title_short | Analysis of crystallographic and structural data of polymeric iron-alkaline metal complexes |
| title_sort | analysis of crystallographic and structural data of polymeric iron alkaline metal complexes |
| topic | classification fem m=alkaline metal polymeric structure |
| url | https://doi.org/10.1515/mgmc-2012-0900 |
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