Water vapor P-ρ-T properties calculation in the temperature range from 773 K to 1673 K
The paper presents the calculation of isotherms of the equation of state of water vapor in the temperature range from T = 773 K to T = 1673 K. The calculation was made using a specially developed software module “Fract EOS”. An approach that improves the accuracy of calculations of the previously d...
| Main Authors: | , |
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| Format: | Article |
| Language: | Russian |
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Tver State University
2022-12-01
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| Series: | Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов |
| Subjects: | |
| Online Access: | https://physchemaspects.ru/2022/doi-10-26456-pcascnn-2022-14-298/?lang=en |
| _version_ | 1811198596830199808 |
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| author | R.A. Magomedov E.N. Akhmedov |
| author_facet | R.A. Magomedov E.N. Akhmedov |
| author_sort | R.A. Magomedov |
| collection | DOAJ |
| description | The paper presents the calculation of isotherms of the equation of state of water vapor in the temperature range from T = 773 K to T = 1673 K. The calculation was made using a specially developed software module “Fract EOS”. An approach that improves the accuracy of calculations of the previously described method is proposed. If there are tabular data of the P-V-T (P-ρ-T) ratio for several temperatures and the pressure dependences of the fractional derivative exponent α(ρ) (which is fitting parameter for the proposed model) obtained from them, then it is possible to obtain the dependence α(ρ) for any temperature within the range. After that, the equation of state can be calculated at a given temperature with high accuracy, without fitting α by experimental values. The results obtained are in good agreement with experimental data. It is shown that proposed method is suitable for calculating isotherms in the temperature ranges not presented in tabulated reference data. |
| first_indexed | 2024-04-12T01:34:08Z |
| format | Article |
| id | doaj.art-88a09a4c6acc4baeaec4486661fbfd5a |
| institution | Directory Open Access Journal |
| issn | 2226-4442 2658-4360 |
| language | Russian |
| last_indexed | 2024-04-12T01:34:08Z |
| publishDate | 2022-12-01 |
| publisher | Tver State University |
| record_format | Article |
| series | Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов |
| spelling | doaj.art-88a09a4c6acc4baeaec4486661fbfd5a2022-12-22T03:53:23ZrusTver State UniversityФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов2226-44422658-43602022-12-011429830610.26456/pcascnn/2022.14.298Water vapor P-ρ-T properties calculation in the temperature range from 773 K to 1673 KR.A. Magomedov0E.N. Akhmedov1Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow, RussiaJoint Institute for High Temperatures, Russian Academy of Sciences, Moscow, Russia The paper presents the calculation of isotherms of the equation of state of water vapor in the temperature range from T = 773 K to T = 1673 K. The calculation was made using a specially developed software module “Fract EOS”. An approach that improves the accuracy of calculations of the previously described method is proposed. If there are tabular data of the P-V-T (P-ρ-T) ratio for several temperatures and the pressure dependences of the fractional derivative exponent α(ρ) (which is fitting parameter for the proposed model) obtained from them, then it is possible to obtain the dependence α(ρ) for any temperature within the range. After that, the equation of state can be calculated at a given temperature with high accuracy, without fitting α by experimental values. The results obtained are in good agreement with experimental data. It is shown that proposed method is suitable for calculating isotherms in the temperature ranges not presented in tabulated reference data. https://physchemaspects.ru/2022/doi-10-26456-pcascnn-2022-14-298/?lang=enequation of stateintegral-differentiation of fractional ordermaxwell relationshelmholtz potentialpartition functionwater vaporisothermthermophysical properties |
| spellingShingle | R.A. Magomedov E.N. Akhmedov Water vapor P-ρ-T properties calculation in the temperature range from 773 K to 1673 K Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов equation of state integral-differentiation of fractional order maxwell relations helmholtz potential partition function water vapor isotherm thermophysical properties |
| title | Water vapor P-ρ-T properties calculation in the temperature range from 773 K to 1673 K |
| title_full | Water vapor P-ρ-T properties calculation in the temperature range from 773 K to 1673 K |
| title_fullStr | Water vapor P-ρ-T properties calculation in the temperature range from 773 K to 1673 K |
| title_full_unstemmed | Water vapor P-ρ-T properties calculation in the temperature range from 773 K to 1673 K |
| title_short | Water vapor P-ρ-T properties calculation in the temperature range from 773 K to 1673 K |
| title_sort | water vapor p ρ t properties calculation in the temperature range from 773 k to 1673 k |
| topic | equation of state integral-differentiation of fractional order maxwell relations helmholtz potential partition function water vapor isotherm thermophysical properties |
| url | https://physchemaspects.ru/2022/doi-10-26456-pcascnn-2022-14-298/?lang=en |
| work_keys_str_mv | AT ramagomedov watervaporprtpropertiescalculationinthetemperaturerangefrom773kto1673k AT enakhmedov watervaporprtpropertiescalculationinthetemperaturerangefrom773kto1673k |