Selective C-N σ Bond Cleavage in Azetidinyl Amides under Transition Metal-Free Conditions

Selective C-N σ Bond Cleavage in Azetidinyl Amides under Transition Metal-Free Conditions

Functionalization of amide bond via the cleavage of a non-carbonyl, C-N &#963; bond remains under-investigated. In this work, a transition-metal-free single-electron transfer reaction has been developed for the C-N &#963; bond cleavage of <i>N</i>-acylazetidines using the electri...

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Bibliographic Details
Main Authors: Hengzhao Li, Zemin Lai, Adila Adijiang, Hongye Zhao, Jie An
Format: Article
Language:English
Published: MDPI AG 2019-01-01
Series:Molecules
Subjects:
amides
C-N σ bond cleavage
sodium
crown ether
Online Access:https://www.mdpi.com/1420-3049/24/3/459

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