Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
Organocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which led to the discovery of oxygen-doped a...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2021-01-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-020-20645-8 |
| _version_ | 1818692170226335744 |
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| author | Qiang Ma Jinshuai Song Xun Zhang Yu Jiang Li Ji Saihu Liao |
| author_facet | Qiang Ma Jinshuai Song Xun Zhang Yu Jiang Li Ji Saihu Liao |
| author_sort | Qiang Ma |
| collection | DOAJ |
| description | Organocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which led to the discovery of oxygen-doped anthanthrene as an organic photoredox catalysts for O-ATRP. |
| first_indexed | 2024-12-17T12:53:32Z |
| format | Article |
| id | doaj.art-88be05f482a64236a23650a990086e8b |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-17T12:53:32Z |
| publishDate | 2021-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-88be05f482a64236a23650a990086e8b2022-12-21T21:47:32ZengNature PortfolioNature Communications2041-17232021-01-011211810.1038/s41467-020-20645-8Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlightQiang Ma0Jinshuai Song1Xun Zhang2Yu Jiang3Li Ji4Saihu Liao5Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou UniversityCollege of Chemistry and Molecular Engineering, Zhengzhou UniversityKey Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou UniversityKey Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou UniversityGrubbs Institute, Southern University of Science and TechnologyKey Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou UniversityOrganocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which led to the discovery of oxygen-doped anthanthrene as an organic photoredox catalysts for O-ATRP.https://doi.org/10.1038/s41467-020-20645-8 |
| spellingShingle | Qiang Ma Jinshuai Song Xun Zhang Yu Jiang Li Ji Saihu Liao Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight Nature Communications |
| title | Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight |
| title_full | Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight |
| title_fullStr | Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight |
| title_full_unstemmed | Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight |
| title_short | Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight |
| title_sort | metal free atom transfer radical polymerization with ppm catalyst loading under sunlight |
| url | https://doi.org/10.1038/s41467-020-20645-8 |
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