Screw sense excess and reversals of helical polymers in solution

Reversals are structural motifs found in helical polymers that are difficult to determine experimentally. Here, the authors turn to photochemical electrocyclization as a tool to establish their presence and estimate excess screw sense in solution.

Bibliographic Details
Main Authors: Francisco Rey-Tarrío, Rafael Rodríguez, Emilio Quiñoá, Félix Freire
Format: Article
Language:English
Published: Nature Portfolio 2023-03-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-023-37405-z
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author Francisco Rey-Tarrío
Rafael Rodríguez
Emilio Quiñoá
Félix Freire
author_facet Francisco Rey-Tarrío
Rafael Rodríguez
Emilio Quiñoá
Félix Freire
author_sort Francisco Rey-Tarrío
collection DOAJ
description Reversals are structural motifs found in helical polymers that are difficult to determine experimentally. Here, the authors turn to photochemical electrocyclization as a tool to establish their presence and estimate excess screw sense in solution.
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spelling doaj.art-88c882967d4f494ab2c952981eee05bb2023-04-03T05:32:50ZengNature PortfolioNature Communications2041-17232023-03-011411910.1038/s41467-023-37405-zScrew sense excess and reversals of helical polymers in solutionFrancisco Rey-Tarrío0Rafael Rodríguez1Emilio Quiñoá2Félix Freire3Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CiQUS), University of Santiago de CompostelaCentro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CiQUS), University of Santiago de CompostelaCentro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CiQUS), University of Santiago de CompostelaCentro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CiQUS), University of Santiago de CompostelaReversals are structural motifs found in helical polymers that are difficult to determine experimentally. Here, the authors turn to photochemical electrocyclization as a tool to establish their presence and estimate excess screw sense in solution.https://doi.org/10.1038/s41467-023-37405-z
spellingShingle Francisco Rey-Tarrío
Rafael Rodríguez
Emilio Quiñoá
Félix Freire
Screw sense excess and reversals of helical polymers in solution
Nature Communications
title Screw sense excess and reversals of helical polymers in solution
title_full Screw sense excess and reversals of helical polymers in solution
title_fullStr Screw sense excess and reversals of helical polymers in solution
title_full_unstemmed Screw sense excess and reversals of helical polymers in solution
title_short Screw sense excess and reversals of helical polymers in solution
title_sort screw sense excess and reversals of helical polymers in solution
url https://doi.org/10.1038/s41467-023-37405-z
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