New zeotropic CO2-based refrigerant mixtures for cascade high-temperature heat pump to reach heat sink temperature up to 180 °C

There is a great demand for clean, high-temperature heating in industries. The present work demonstrates the modeling and analysis of a high-temperature heat pump (HTHP) using a two-stage cascade refrigeration system with newly developed refrigerant mixtures. Environment-friendly CO2/butane and CO2/...

Full description

Bibliographic Details
Main Authors: P. Ganesan, Trygve M. Eikevik
Format: Article
Language:English
Published: Elsevier 2023-10-01
Series:Energy Conversion and Management: X
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590174523000636
_version_ 1797801716683374592
author P. Ganesan
Trygve M. Eikevik
author_facet P. Ganesan
Trygve M. Eikevik
author_sort P. Ganesan
collection DOAJ
description There is a great demand for clean, high-temperature heating in industries. The present work demonstrates the modeling and analysis of a high-temperature heat pump (HTHP) using a two-stage cascade refrigeration system with newly developed refrigerant mixtures. Environment-friendly CO2/butane and CO2/pentane mixtures were introduced in the Low-stage (LS) and High-stage (HS) cycles, respectively. The model was built in MATLAB and explored the possibilities of high-temperature heating. A heating source temperature of 10 to 50 °C was considered as the system's input. The HTHP was designed to deliver hot water at a temperature above 115 °C. The performance of the system was investigated in terms of the heat sink and hot water temperatures, temperature lift, heating capacity, LS, HS, and total system’s coefficient of performance (COP), volumetric and isentropic efficiencies, and discussed. The analysis indicated that the system could deliver high-temperature water with a temperature lift of 70 °C. Mixtures of 5% CO2/ 95% butane and 5% CO2/ 95% pentane exhibit excellent thermo-physical properties making them suitable for high-temperature heating applications with high COP. For instance, such mixtures obtain the system's COP and heating capacity of 3.6 and 201.5 kW, respectively for the heat sink temperature of 116.7 °C. It shows an improvement of 20% compared to pure fluids. Also, the heat sink temperature could reach up to 181 °C when the CO2 composition in the refrigerant mixtures is 20%. The volumetric (0.72–0.87) and isentropic (0.61–0.71) efficiencies of the compressor were studied and displayed.
first_indexed 2024-03-13T04:54:43Z
format Article
id doaj.art-89075b95d8b449ddbcbcf1e7470dc9e6
institution Directory Open Access Journal
issn 2590-1745
language English
last_indexed 2024-03-13T04:54:43Z
publishDate 2023-10-01
publisher Elsevier
record_format Article
series Energy Conversion and Management: X
spelling doaj.art-89075b95d8b449ddbcbcf1e7470dc9e62023-06-18T05:03:16ZengElsevierEnergy Conversion and Management: X2590-17452023-10-0120100407New zeotropic CO2-based refrigerant mixtures for cascade high-temperature heat pump to reach heat sink temperature up to 180 °CP. Ganesan0Trygve M. Eikevik1Corresponding author.; Process and Power Research Group, Department of Energy and Process Engineering, Norwegian University of Science and Technology (NTNU), Trondheim, NorwayProcess and Power Research Group, Department of Energy and Process Engineering, Norwegian University of Science and Technology (NTNU), Trondheim, NorwayThere is a great demand for clean, high-temperature heating in industries. The present work demonstrates the modeling and analysis of a high-temperature heat pump (HTHP) using a two-stage cascade refrigeration system with newly developed refrigerant mixtures. Environment-friendly CO2/butane and CO2/pentane mixtures were introduced in the Low-stage (LS) and High-stage (HS) cycles, respectively. The model was built in MATLAB and explored the possibilities of high-temperature heating. A heating source temperature of 10 to 50 °C was considered as the system's input. The HTHP was designed to deliver hot water at a temperature above 115 °C. The performance of the system was investigated in terms of the heat sink and hot water temperatures, temperature lift, heating capacity, LS, HS, and total system’s coefficient of performance (COP), volumetric and isentropic efficiencies, and discussed. The analysis indicated that the system could deliver high-temperature water with a temperature lift of 70 °C. Mixtures of 5% CO2/ 95% butane and 5% CO2/ 95% pentane exhibit excellent thermo-physical properties making them suitable for high-temperature heating applications with high COP. For instance, such mixtures obtain the system's COP and heating capacity of 3.6 and 201.5 kW, respectively for the heat sink temperature of 116.7 °C. It shows an improvement of 20% compared to pure fluids. Also, the heat sink temperature could reach up to 181 °C when the CO2 composition in the refrigerant mixtures is 20%. The volumetric (0.72–0.87) and isentropic (0.61–0.71) efficiencies of the compressor were studied and displayed.http://www.sciencedirect.com/science/article/pii/S2590174523000636Cascade systemHigh-temperature heat pumpNatural refrigerantsZeotropic mixturesMATLAB
spellingShingle P. Ganesan
Trygve M. Eikevik
New zeotropic CO2-based refrigerant mixtures for cascade high-temperature heat pump to reach heat sink temperature up to 180 °C
Energy Conversion and Management: X
Cascade system
High-temperature heat pump
Natural refrigerants
Zeotropic mixtures
MATLAB
title New zeotropic CO2-based refrigerant mixtures for cascade high-temperature heat pump to reach heat sink temperature up to 180 °C
title_full New zeotropic CO2-based refrigerant mixtures for cascade high-temperature heat pump to reach heat sink temperature up to 180 °C
title_fullStr New zeotropic CO2-based refrigerant mixtures for cascade high-temperature heat pump to reach heat sink temperature up to 180 °C
title_full_unstemmed New zeotropic CO2-based refrigerant mixtures for cascade high-temperature heat pump to reach heat sink temperature up to 180 °C
title_short New zeotropic CO2-based refrigerant mixtures for cascade high-temperature heat pump to reach heat sink temperature up to 180 °C
title_sort new zeotropic co2 based refrigerant mixtures for cascade high temperature heat pump to reach heat sink temperature up to 180 °c
topic Cascade system
High-temperature heat pump
Natural refrigerants
Zeotropic mixtures
MATLAB
url http://www.sciencedirect.com/science/article/pii/S2590174523000636
work_keys_str_mv AT pganesan newzeotropicco2basedrefrigerantmixturesforcascadehightemperatureheatpumptoreachheatsinktemperatureupto180c
AT trygvemeikevik newzeotropicco2basedrefrigerantmixturesforcascadehightemperatureheatpumptoreachheatsinktemperatureupto180c