Progress in Promising Semiconductor Materials for Efficient Photoelectrocatalytic Hydrogen Production

Photoelectrocatalytic (PEC) water decomposition provides a promising method for converting solar energy into green hydrogen energy. Indeed, significant advances and improvements have been made in various fundamental aspects for cutting-edge applications, such as water splitting and hydrogen producti...

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Main Authors: Weisong Fu, Yan Zhang, Xi Zhang, Hui Yang, Ruihao Xie, Shaoan Zhang, Yang Lv, Liangbin Xiong
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/29/2/289
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author Weisong Fu
Yan Zhang
Xi Zhang
Hui Yang
Ruihao Xie
Shaoan Zhang
Yang Lv
Liangbin Xiong
author_facet Weisong Fu
Yan Zhang
Xi Zhang
Hui Yang
Ruihao Xie
Shaoan Zhang
Yang Lv
Liangbin Xiong
author_sort Weisong Fu
collection DOAJ
description Photoelectrocatalytic (PEC) water decomposition provides a promising method for converting solar energy into green hydrogen energy. Indeed, significant advances and improvements have been made in various fundamental aspects for cutting-edge applications, such as water splitting and hydrogen production. However, the fairly low PEC efficiency of water decomposition by a semiconductor photoelectrode and photocorrosion seriously restrict the practical application of photoelectrochemistry. In this review, the mechanisms of PEC water decomposition are first introduced to provide a solid understanding of the PEC process and ensure that this review is accessible to a wide range of readers. Afterwards, notable achievements to date are outlined, and unique approaches involving promising semiconductor materials for efficient PEC hydrogen production, including metal oxide, sulfide, and graphite-phase carbon nitride, are described. Finally, four strategies which can effectively improve the hydrogen production rate—morphological control, doping, heterojunction, and surface modification—are discussed.
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spelling doaj.art-8921384fe755438c8e71cd1279a7d4182024-01-29T14:07:17ZengMDPI AGMolecules1420-30492024-01-0129228910.3390/molecules29020289Progress in Promising Semiconductor Materials for Efficient Photoelectrocatalytic Hydrogen ProductionWeisong Fu0Yan Zhang1Xi Zhang2Hui Yang3Ruihao Xie4Shaoan Zhang5Yang Lv6Liangbin Xiong7School of Optoelectronic Engineering, Guangdong Polytechnic Normal University, Guangzhou 510665, ChinaSchool of Optoelectronic Engineering, Guangdong Polytechnic Normal University, Guangzhou 510665, ChinaSchool of Optoelectronic Engineering, Guangdong Polytechnic Normal University, Guangzhou 510665, ChinaSchool of Medical Information Engineering, Gannan Medical University, Ganzhou 341004, ChinaSchool of Optoelectronic Engineering, Guangdong Polytechnic Normal University, Guangzhou 510665, ChinaSchool of Optoelectronic Engineering, Guangdong Polytechnic Normal University, Guangzhou 510665, ChinaSchool of Optoelectronic Engineering, Guangdong Polytechnic Normal University, Guangzhou 510665, ChinaSchool of Optoelectronic Engineering, Guangdong Polytechnic Normal University, Guangzhou 510665, ChinaPhotoelectrocatalytic (PEC) water decomposition provides a promising method for converting solar energy into green hydrogen energy. Indeed, significant advances and improvements have been made in various fundamental aspects for cutting-edge applications, such as water splitting and hydrogen production. However, the fairly low PEC efficiency of water decomposition by a semiconductor photoelectrode and photocorrosion seriously restrict the practical application of photoelectrochemistry. In this review, the mechanisms of PEC water decomposition are first introduced to provide a solid understanding of the PEC process and ensure that this review is accessible to a wide range of readers. Afterwards, notable achievements to date are outlined, and unique approaches involving promising semiconductor materials for efficient PEC hydrogen production, including metal oxide, sulfide, and graphite-phase carbon nitride, are described. Finally, four strategies which can effectively improve the hydrogen production rate—morphological control, doping, heterojunction, and surface modification—are discussed.https://www.mdpi.com/1420-3049/29/2/289photoelectrocatalysishydrogen energysemiconductorphotoelectrode
spellingShingle Weisong Fu
Yan Zhang
Xi Zhang
Hui Yang
Ruihao Xie
Shaoan Zhang
Yang Lv
Liangbin Xiong
Progress in Promising Semiconductor Materials for Efficient Photoelectrocatalytic Hydrogen Production
Molecules
photoelectrocatalysis
hydrogen energy
semiconductor
photoelectrode
title Progress in Promising Semiconductor Materials for Efficient Photoelectrocatalytic Hydrogen Production
title_full Progress in Promising Semiconductor Materials for Efficient Photoelectrocatalytic Hydrogen Production
title_fullStr Progress in Promising Semiconductor Materials for Efficient Photoelectrocatalytic Hydrogen Production
title_full_unstemmed Progress in Promising Semiconductor Materials for Efficient Photoelectrocatalytic Hydrogen Production
title_short Progress in Promising Semiconductor Materials for Efficient Photoelectrocatalytic Hydrogen Production
title_sort progress in promising semiconductor materials for efficient photoelectrocatalytic hydrogen production
topic photoelectrocatalysis
hydrogen energy
semiconductor
photoelectrode
url https://www.mdpi.com/1420-3049/29/2/289
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