About the Implementation of Frequency Conversion Processes in Solar Cell Device Simulations

Solar cells are electrical devices that can directly convert sunlight into electricity. While solar cells are a mature technology, their efficiencies are still far below the theoretical limit. The major losses in a typical semiconductor solar cell are due to the thermalization of electrons in the UV...

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Main Authors: Alexander Quandt, Tahir Aslan, Itumeleng Mokgosi, Robert Warmbier, Maurizio Ferrari, Giancarlo Righini
Format: Article
Language:English
Published: MDPI AG 2018-08-01
Series:Micromachines
Subjects:
Online Access:http://www.mdpi.com/2072-666X/9/9/435
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author Alexander Quandt
Tahir Aslan
Itumeleng Mokgosi
Robert Warmbier
Maurizio Ferrari
Giancarlo Righini
author_facet Alexander Quandt
Tahir Aslan
Itumeleng Mokgosi
Robert Warmbier
Maurizio Ferrari
Giancarlo Righini
author_sort Alexander Quandt
collection DOAJ
description Solar cells are electrical devices that can directly convert sunlight into electricity. While solar cells are a mature technology, their efficiencies are still far below the theoretical limit. The major losses in a typical semiconductor solar cell are due to the thermalization of electrons in the UV and visible range of the solar spectrum, the inability of a solar cell to absorb photons with energies below the electronic band gap, and losses due to the recombination of electrons and holes, which mainly occur at the contacts. These prevent the realization of the theoretical efficiency limit of 85% for a generic photovoltaic device. A promising strategy to harness light with minimum thermal losses outside the typical frequency range of a single junction solar cell could be frequency conversion using rare earth ions, as suggested by Trupke. In this work, we discuss the modelling of generic frequency conversion processes in the context of solar cell device simulations, which can be used to supplement experimental studies. In the spirit of a proof-of-concept study, we limit the discussion to up-conversion and restrict ourselves to a simple rare earth model system, together with a basic diode model for a crystalline silicon solar cell. The results of this show that these simulations are very useful for the development of new types of highly efficient solar cells.
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spelling doaj.art-89272f6f4ba14bdbb65bf961f4b3a0082022-12-22T02:35:45ZengMDPI AGMicromachines2072-666X2018-08-019943510.3390/mi9090435mi9090435About the Implementation of Frequency Conversion Processes in Solar Cell Device SimulationsAlexander Quandt0Tahir Aslan1Itumeleng Mokgosi2Robert Warmbier3Maurizio Ferrari4Giancarlo Righini5Historical Museum of Physics and Study & Research Centre “Enrico Fermi”, 00184 Roma, ItalySchool of Physics and Materials for Energy Research Group, University of the Witwatersrand, 2050 Johannesburg, South AfricaSchool of Physics and Materials for Energy Research Group, University of the Witwatersrand, 2050 Johannesburg, South AfricaDepartment of Physics, University of Johannesburg, 2006 Auckland Park, South AfricaHistorical Museum of Physics and Study & Research Centre “Enrico Fermi”, 00184 Roma, ItalyHistorical Museum of Physics and Study & Research Centre “Enrico Fermi”, 00184 Roma, ItalySolar cells are electrical devices that can directly convert sunlight into electricity. While solar cells are a mature technology, their efficiencies are still far below the theoretical limit. The major losses in a typical semiconductor solar cell are due to the thermalization of electrons in the UV and visible range of the solar spectrum, the inability of a solar cell to absorb photons with energies below the electronic band gap, and losses due to the recombination of electrons and holes, which mainly occur at the contacts. These prevent the realization of the theoretical efficiency limit of 85% for a generic photovoltaic device. A promising strategy to harness light with minimum thermal losses outside the typical frequency range of a single junction solar cell could be frequency conversion using rare earth ions, as suggested by Trupke. In this work, we discuss the modelling of generic frequency conversion processes in the context of solar cell device simulations, which can be used to supplement experimental studies. In the spirit of a proof-of-concept study, we limit the discussion to up-conversion and restrict ourselves to a simple rare earth model system, together with a basic diode model for a crystalline silicon solar cell. The results of this show that these simulations are very useful for the development of new types of highly efficient solar cells.http://www.mdpi.com/2072-666X/9/9/435photovoltaicsfrequency conversiondevice simulations
spellingShingle Alexander Quandt
Tahir Aslan
Itumeleng Mokgosi
Robert Warmbier
Maurizio Ferrari
Giancarlo Righini
About the Implementation of Frequency Conversion Processes in Solar Cell Device Simulations
Micromachines
photovoltaics
frequency conversion
device simulations
title About the Implementation of Frequency Conversion Processes in Solar Cell Device Simulations
title_full About the Implementation of Frequency Conversion Processes in Solar Cell Device Simulations
title_fullStr About the Implementation of Frequency Conversion Processes in Solar Cell Device Simulations
title_full_unstemmed About the Implementation of Frequency Conversion Processes in Solar Cell Device Simulations
title_short About the Implementation of Frequency Conversion Processes in Solar Cell Device Simulations
title_sort about the implementation of frequency conversion processes in solar cell device simulations
topic photovoltaics
frequency conversion
device simulations
url http://www.mdpi.com/2072-666X/9/9/435
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