Enhancement of Efficiency of Water Removal from Bangestan Crude Oil by Silica Nanoparticles Using Imidazolium-based Ionic Liquids

The effect of coating silica nanoparticles by several 1-alkyl-3-methylimidazolium hexafluorophosphate ionic liquids of [Rmim][PF6] general formula (R= C10, C12, and C14) on the water removal efficiency of silica nanoparticles from crude oil emulsions have been studied in this study. The ionic liquid...

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Main Authors: Ali Mehdizadeh, Fakhrotolou Masoumi, Amir Nasser Ahmadi, Marzieh Shekarriz, Shahriar Ghamami
Format: Article
Language:English
Published: Reaserch Institute of Petroleum Industry 2022-05-01
Series:Journal of Petroleum Science and Technology
Subjects:
Online Access:https://jpst.ripi.ir/article_1286_5be5e0aad5f058a019c399575878fa99.pdf
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author Ali Mehdizadeh
Fakhrotolou Masoumi
Amir Nasser Ahmadi
Marzieh Shekarriz
Shahriar Ghamami
author_facet Ali Mehdizadeh
Fakhrotolou Masoumi
Amir Nasser Ahmadi
Marzieh Shekarriz
Shahriar Ghamami
author_sort Ali Mehdizadeh
collection DOAJ
description The effect of coating silica nanoparticles by several 1-alkyl-3-methylimidazolium hexafluorophosphate ionic liquids of [Rmim][PF6] general formula (R= C10, C12, and C14) on the water removal efficiency of silica nanoparticles from crude oil emulsions have been studied in this study. The ionic liquids have been prepared and characterized by comparing their 1HNMR and FT-IR spectra with those reported in the literature. In addition, the effects of factors including cation alkyl chain length and concentration of the ionic liquids prepared on the water separation efficiency of the demulsifier have also been investigated to determine the optimal values for the chain length and concentration of the ionic liquid. [C14mim][PF6] ionic liquid at a concentration of 1200 ppm was shown to be the most efficient ionic liquid among the ionic liquids studied. The water separation efficiency achieved using coated nanosilica under optimal conditions was 93.3%.
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spelling doaj.art-89349996ba354d8fb07e376d523c5be92023-02-28T11:57:33ZengReaserch Institute of Petroleum IndustryJournal of Petroleum Science and Technology2251-659X2645-33122022-05-01122515810.22078/jpst.2023.4855.18131286Enhancement of Efficiency of Water Removal from Bangestan Crude Oil by Silica Nanoparticles Using Imidazolium-based Ionic LiquidsAli Mehdizadeh0Fakhrotolou Masoumi1Amir Nasser Ahmadi2Marzieh Shekarriz3Shahriar Ghamami4Chemical, Polymeric, and Petrochemical Research Division, Faculty of Upstream Research and Development, Research Institute of Petroleum Industry IRPI, Tehran, IranChemical, Polymeric, and Petrochemical Research Division, Faculty of Upstream Research and Development, Research Institute of Petroleum Industry IRPI, Tehran, IranChemical, Polymeric, and Petrochemical Research Division, Faculty of Upstream Research and Development, Research Institute of Petroleum Industry IRPI, Tehran, IranChemical, Polymeric, and Petrochemical Research Division, Faculty of Upstream Research and Development, Research Institute of Petroleum Industry IRPI, Tehran, IranDepartment of Chemistry, Imam Khomeini International University, Qazvin, IranThe effect of coating silica nanoparticles by several 1-alkyl-3-methylimidazolium hexafluorophosphate ionic liquids of [Rmim][PF6] general formula (R= C10, C12, and C14) on the water removal efficiency of silica nanoparticles from crude oil emulsions have been studied in this study. The ionic liquids have been prepared and characterized by comparing their 1HNMR and FT-IR spectra with those reported in the literature. In addition, the effects of factors including cation alkyl chain length and concentration of the ionic liquids prepared on the water separation efficiency of the demulsifier have also been investigated to determine the optimal values for the chain length and concentration of the ionic liquid. [C14mim][PF6] ionic liquid at a concentration of 1200 ppm was shown to be the most efficient ionic liquid among the ionic liquids studied. The water separation efficiency achieved using coated nanosilica under optimal conditions was 93.3%.https://jpst.ripi.ir/article_1286_5be5e0aad5f058a019c399575878fa99.pdfionic liquidsdemulsificationcrude oilsilica nanoparticles
spellingShingle Ali Mehdizadeh
Fakhrotolou Masoumi
Amir Nasser Ahmadi
Marzieh Shekarriz
Shahriar Ghamami
Enhancement of Efficiency of Water Removal from Bangestan Crude Oil by Silica Nanoparticles Using Imidazolium-based Ionic Liquids
Journal of Petroleum Science and Technology
ionic liquids
demulsification
crude oil
silica nanoparticles
title Enhancement of Efficiency of Water Removal from Bangestan Crude Oil by Silica Nanoparticles Using Imidazolium-based Ionic Liquids
title_full Enhancement of Efficiency of Water Removal from Bangestan Crude Oil by Silica Nanoparticles Using Imidazolium-based Ionic Liquids
title_fullStr Enhancement of Efficiency of Water Removal from Bangestan Crude Oil by Silica Nanoparticles Using Imidazolium-based Ionic Liquids
title_full_unstemmed Enhancement of Efficiency of Water Removal from Bangestan Crude Oil by Silica Nanoparticles Using Imidazolium-based Ionic Liquids
title_short Enhancement of Efficiency of Water Removal from Bangestan Crude Oil by Silica Nanoparticles Using Imidazolium-based Ionic Liquids
title_sort enhancement of efficiency of water removal from bangestan crude oil by silica nanoparticles using imidazolium based ionic liquids
topic ionic liquids
demulsification
crude oil
silica nanoparticles
url https://jpst.ripi.ir/article_1286_5be5e0aad5f058a019c399575878fa99.pdf
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