Chiral Chromonics Confined in Spherical Geometries

Chromonic liquid crystals have recently received a lot of attention due to their spontaneous self-assembly in supramolecular columnar structures that, depending on their concentration in water, align to form a nematic liquid crystalline phase. The chirality may be induced in chromonics by adding chi...

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Main Authors: Maria Penelope De Santo, Lorenza Spina, Federica Ciuchi
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/13/7/4507
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author Maria Penelope De Santo
Lorenza Spina
Federica Ciuchi
author_facet Maria Penelope De Santo
Lorenza Spina
Federica Ciuchi
author_sort Maria Penelope De Santo
collection DOAJ
description Chromonic liquid crystals have recently received a lot of attention due to their spontaneous self-assembly in supramolecular columnar structures that, depending on their concentration in water, align to form a nematic liquid crystalline phase. The chirality may be induced in chromonics by adding chiral moieties to the nematic phase or enhanced by confining them in curved geometrical constraints. This review summarizes the recent research developments on chiral chromonic liquid crystals confined in spherical geometry, relating the results to what was observed for thermotropic liquid crystals in the same conditions. The review focuses on the studies carried out on commercially available nematic chromonics, investigating the effects on their topologies in different anchoring conditions and different chiral dopants and suggesting an application in the sensor field.
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spelling doaj.art-894feb6cfd3a4179b1194938bcb3e5352023-11-17T16:21:20ZengMDPI AGApplied Sciences2076-34172023-04-01137450710.3390/app13074507Chiral Chromonics Confined in Spherical GeometriesMaria Penelope De Santo0Lorenza Spina1Federica Ciuchi2Physics Department, University of Calabria, Ponte Bucci, Cubo 31C, 87036 Arcavacata di Rende, ItalyPhysics Department, University of Calabria, Ponte Bucci, Cubo 31C, 87036 Arcavacata di Rende, ItalyCNR-Nanotec c/o Physics Department, University of Calabria, Ponte Bucci, Cubo 31C, 87036 Arcavacata di Rende, ItalyChromonic liquid crystals have recently received a lot of attention due to their spontaneous self-assembly in supramolecular columnar structures that, depending on their concentration in water, align to form a nematic liquid crystalline phase. The chirality may be induced in chromonics by adding chiral moieties to the nematic phase or enhanced by confining them in curved geometrical constraints. This review summarizes the recent research developments on chiral chromonic liquid crystals confined in spherical geometry, relating the results to what was observed for thermotropic liquid crystals in the same conditions. The review focuses on the studies carried out on commercially available nematic chromonics, investigating the effects on their topologies in different anchoring conditions and different chiral dopants and suggesting an application in the sensor field.https://www.mdpi.com/2076-3417/13/7/4507chromonicsliquid crystalschiralitymicrospheresconfinement
spellingShingle Maria Penelope De Santo
Lorenza Spina
Federica Ciuchi
Chiral Chromonics Confined in Spherical Geometries
Applied Sciences
chromonics
liquid crystals
chirality
microspheres
confinement
title Chiral Chromonics Confined in Spherical Geometries
title_full Chiral Chromonics Confined in Spherical Geometries
title_fullStr Chiral Chromonics Confined in Spherical Geometries
title_full_unstemmed Chiral Chromonics Confined in Spherical Geometries
title_short Chiral Chromonics Confined in Spherical Geometries
title_sort chiral chromonics confined in spherical geometries
topic chromonics
liquid crystals
chirality
microspheres
confinement
url https://www.mdpi.com/2076-3417/13/7/4507
work_keys_str_mv AT mariapenelopedesanto chiralchromonicsconfinedinsphericalgeometries
AT lorenzaspina chiralchromonicsconfinedinsphericalgeometries
AT federicaciuchi chiralchromonicsconfinedinsphericalgeometries