A Facile Pathway to Modify Cellulose Composite Film by Reducing Wettability and Improving Barrier towards Moisture

The hydrophilic property of cellulose is a key limiting factor for its wide application. Here, a novel solution impregnation pathway was developed to increase the hydrophobic properties of cellulose. When compared with the regenerated cellulose (RC), the composite films showed a decrease in water up...

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Main Authors: Xiaorong Hu, Lin Chen, Dandan Tao, Zhaocheng Ma, Shilin Liu
Format: Article
Language:English
Published: MDPI AG 2017-01-01
Series:Materials
Subjects:
Online Access:http://www.mdpi.com/1996-1944/10/1/39
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author Xiaorong Hu
Lin Chen
Dandan Tao
Zhaocheng Ma
Shilin Liu
author_facet Xiaorong Hu
Lin Chen
Dandan Tao
Zhaocheng Ma
Shilin Liu
author_sort Xiaorong Hu
collection DOAJ
description The hydrophilic property of cellulose is a key limiting factor for its wide application. Here, a novel solution impregnation pathway was developed to increase the hydrophobic properties of cellulose. When compared with the regenerated cellulose (RC), the composite films showed a decrease in water uptake ability towards water vapor, and an increase of the water contact angle from 29° to 65° with increasing resin content in the composites, with only a slight change in the transmittance. Furthermore, the Young’s modulus value increased from 3.2 GPa (RC film) to 5.1 GPa (RCBEA50 film). The results indicated that the composites had combined the advantages of cellulose and biphenyl A epoxy acrylate prepolymer (BEA) resin. The presented method has great potential for the preparation of biocomposites with improved properties. The overall results suggest that composite films can be used as high-performance packaging materials.
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spelling doaj.art-895d4e9ab82d4ce1b00fb99488012cc12022-12-22T03:58:03ZengMDPI AGMaterials1996-19442017-01-011013910.3390/ma10010039ma10010039A Facile Pathway to Modify Cellulose Composite Film by Reducing Wettability and Improving Barrier towards MoistureXiaorong Hu0Lin Chen1Dandan Tao2Zhaocheng Ma3Shilin Liu4Department of Cardiology, Renmin Hospital, Wuhan University, Wuhan 430070, ChinaKey Laboratory of Horticultural Plant Biology of Ministry of Education, College of Horticulture and Forestry Sciences, Huazhong Agricultural University, Wuhan 430070, ChinaSchool of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, ChinaKey Laboratory of Horticultural Plant Biology of Ministry of Education, College of Horticulture and Forestry Sciences, Huazhong Agricultural University, Wuhan 430070, ChinaKey Laboratory of Horticultural Plant Biology of Ministry of Education, College of Horticulture and Forestry Sciences, Huazhong Agricultural University, Wuhan 430070, ChinaThe hydrophilic property of cellulose is a key limiting factor for its wide application. Here, a novel solution impregnation pathway was developed to increase the hydrophobic properties of cellulose. When compared with the regenerated cellulose (RC), the composite films showed a decrease in water uptake ability towards water vapor, and an increase of the water contact angle from 29° to 65° with increasing resin content in the composites, with only a slight change in the transmittance. Furthermore, the Young’s modulus value increased from 3.2 GPa (RC film) to 5.1 GPa (RCBEA50 film). The results indicated that the composites had combined the advantages of cellulose and biphenyl A epoxy acrylate prepolymer (BEA) resin. The presented method has great potential for the preparation of biocomposites with improved properties. The overall results suggest that composite films can be used as high-performance packaging materials.http://www.mdpi.com/1996-1944/10/1/39polymer-matrix composites (PMCs)cellulosewettabilitycuring
spellingShingle Xiaorong Hu
Lin Chen
Dandan Tao
Zhaocheng Ma
Shilin Liu
A Facile Pathway to Modify Cellulose Composite Film by Reducing Wettability and Improving Barrier towards Moisture
Materials
polymer-matrix composites (PMCs)
cellulose
wettability
curing
title A Facile Pathway to Modify Cellulose Composite Film by Reducing Wettability and Improving Barrier towards Moisture
title_full A Facile Pathway to Modify Cellulose Composite Film by Reducing Wettability and Improving Barrier towards Moisture
title_fullStr A Facile Pathway to Modify Cellulose Composite Film by Reducing Wettability and Improving Barrier towards Moisture
title_full_unstemmed A Facile Pathway to Modify Cellulose Composite Film by Reducing Wettability and Improving Barrier towards Moisture
title_short A Facile Pathway to Modify Cellulose Composite Film by Reducing Wettability and Improving Barrier towards Moisture
title_sort facile pathway to modify cellulose composite film by reducing wettability and improving barrier towards moisture
topic polymer-matrix composites (PMCs)
cellulose
wettability
curing
url http://www.mdpi.com/1996-1944/10/1/39
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