(Sp)-1-Diphenylphosphanyl-2-{(S)-[2-(diphenylphosphanyl)phenyl]hydroxymethyl}ferrocene
The absolute configuration of the title compound, [Fe(C5H5)(C36H29OP2)], is Sp at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal–pyramidal conformation. There is a short intramolecular C—H...P contact with an H...P distance of 2.56 &...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808038294 |
| _version_ | 1818084898682961920 |
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| author | A. Stephen K. Hashmi Andreas Rivas Nass Angelino Doppiu Jan W. Bats |
| author_facet | A. Stephen K. Hashmi Andreas Rivas Nass Angelino Doppiu Jan W. Bats |
| author_sort | A. Stephen K. Hashmi |
| collection | DOAJ |
| description | The absolute configuration of the title compound, [Fe(C5H5)(C36H29OP2)], is Sp at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal–pyramidal conformation. There is a short intramolecular C—H...P contact with an H...P distance of 2.56 Å. The hydroxy group is involved in an intramolecular O—H...πphenyl interaction. The crystal packing shows five very weak intermolecular C—H...π contacts, with H...Cg distances between 3.26 and 3.39 Å (Cg is the centroid of a phenyl or cyclopentadienyl ring). |
| first_indexed | 2024-12-10T20:01:12Z |
| format | Article |
| id | doaj.art-8960c6877e834338b4103befcf316a45 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:01:12Z |
| publishDate | 2008-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8960c6877e834338b4103befcf316a452022-12-22T01:35:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412m1585m158510.1107/S1600536808038294(Sp)-1-Diphenylphosphanyl-2-{(S)-[2-(diphenylphosphanyl)phenyl]hydroxymethyl}ferroceneA. Stephen K. HashmiAndreas Rivas NassAngelino DoppiuJan W. BatsThe absolute configuration of the title compound, [Fe(C5H5)(C36H29OP2)], is Sp at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal–pyramidal conformation. There is a short intramolecular C—H...P contact with an H...P distance of 2.56 Å. The hydroxy group is involved in an intramolecular O—H...πphenyl interaction. The crystal packing shows five very weak intermolecular C—H...π contacts, with H...Cg distances between 3.26 and 3.39 Å (Cg is the centroid of a phenyl or cyclopentadienyl ring).http://scripts.iucr.org/cgi-bin/paper?S1600536808038294 |
| spellingShingle | A. Stephen K. Hashmi Andreas Rivas Nass Angelino Doppiu Jan W. Bats (Sp)-1-Diphenylphosphanyl-2-{(S)-[2-(diphenylphosphanyl)phenyl]hydroxymethyl}ferrocene Acta Crystallographica Section E |
| title | (Sp)-1-Diphenylphosphanyl-2-{(S)-[2-(diphenylphosphanyl)phenyl]hydroxymethyl}ferrocene |
| title_full | (Sp)-1-Diphenylphosphanyl-2-{(S)-[2-(diphenylphosphanyl)phenyl]hydroxymethyl}ferrocene |
| title_fullStr | (Sp)-1-Diphenylphosphanyl-2-{(S)-[2-(diphenylphosphanyl)phenyl]hydroxymethyl}ferrocene |
| title_full_unstemmed | (Sp)-1-Diphenylphosphanyl-2-{(S)-[2-(diphenylphosphanyl)phenyl]hydroxymethyl}ferrocene |
| title_short | (Sp)-1-Diphenylphosphanyl-2-{(S)-[2-(diphenylphosphanyl)phenyl]hydroxymethyl}ferrocene |
| title_sort | sp 1 diphenylphosphanyl 2 s 2 diphenylphosphanyl phenyl hydroxymethyl ferrocene |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808038294 |
| work_keys_str_mv | AT astephenkhashmi sp1diphenylphosphanyl2s2diphenylphosphanylphenylhydroxymethylferrocene AT andreasrivasnass sp1diphenylphosphanyl2s2diphenylphosphanylphenylhydroxymethylferrocene AT angelinodoppiu sp1diphenylphosphanyl2s2diphenylphosphanylphenylhydroxymethylferrocene AT janwbats sp1diphenylphosphanyl2s2diphenylphosphanylphenylhydroxymethylferrocene |