First Example of Fluorinated Phenanthroline Diamides: Synthesis, Structural Study, and Complexation with Lanthanoids

First Example of Fluorinated Phenanthroline Diamides: Synthesis, Structural Study, and Complexation with Lanthanoids

An efficient approach to the synthesis of diamides of 4,7-difluoro-1,10-phenanthroline-2,9-dicarboxylic acid was elaborated. Direct nucleophilic substitution with 4,7-dichloro-1,10-phenanthroline precursors opened access to difluoro derivatives in high yield. As a result, four new fluorinated ligand...

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Bibliographic Details
Main Authors: Nane A. Avagyan, Pavel S. Lemport, Konstantin A. Lysenko, Alexey O. Gudovannyy, Vitaly A. Roznyatovsky, Valentine S. Petrov, Mikhail F. Vokuev, Yuri A. Ustynyuk, Valentine G. Nenajdenko
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Molecules
Subjects:
fluorine
phenanthroline
nucleophilic substitution
complex
lanthanoid
structure
Online Access:https://www.mdpi.com/1420-3049/27/15/4705

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