[(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)
In the title complex, [Pt(SCN)2(C8H12)], the PtII ion lies in a square-planar coordination geometry defined by the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene and two S-bound SCN− anions. The complex is disposed about a mirror plane passing through the Pt atom and the SCN...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2019-01-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314619001627 |
| _version_ | 1818366182574522368 |
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| author | Kwang Ha |
| author_facet | Kwang Ha |
| author_sort | Kwang Ha |
| collection | DOAJ |
| description | In the title complex, [Pt(SCN)2(C8H12)], the PtII ion lies in a square-planar coordination geometry defined by the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene and two S-bound SCN− anions. The complex is disposed about a mirror plane passing through the Pt atom and the SCN− ligands, and bisecting the cycloocta-1,5-diene molecule. The room-temperature crystal structure of the title complex was previously reported in the orthorhombic space group Pna21 [Musitu & Garcia-Blanco (1984). Acta Cryst. A40, C101]. The low-temperature structure presented herein represents a different (higher symmetry) orthorhombic space group Pnma whereby the PtII atom lies on a mirror plane, lacking in the earlier study. |
| first_indexed | 2024-12-13T22:32:06Z |
| format | Article |
| id | doaj.art-89778c2883564983a9e55aacea2cdd7d |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-13T22:32:06Z |
| publishDate | 2019-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-89778c2883564983a9e55aacea2cdd7d2022-12-21T23:29:03ZengInternational Union of CrystallographyIUCrData2414-31462019-01-0141x19016210.1107/S2414314619001627tk4054[(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)Kwang Ha0Chonnam National University, School of Chemical Engineering, Research Institute of Catalysis, Gwangju, Republic of KoreaIn the title complex, [Pt(SCN)2(C8H12)], the PtII ion lies in a square-planar coordination geometry defined by the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene and two S-bound SCN− anions. The complex is disposed about a mirror plane passing through the Pt atom and the SCN− ligands, and bisecting the cycloocta-1,5-diene molecule. The room-temperature crystal structure of the title complex was previously reported in the orthorhombic space group Pna21 [Musitu & Garcia-Blanco (1984). Acta Cryst. A40, C101]. The low-temperature structure presented herein represents a different (higher symmetry) orthorhombic space group Pnma whereby the PtII atom lies on a mirror plane, lacking in the earlier study.http://scripts.iucr.org/cgi-bin/paper?S2414314619001627crystal structureplatinum(II) complexcycloocta-1,5-dienethiocyanate |
| spellingShingle | Kwang Ha [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II) IUCrData crystal structure platinum(II) complex cycloocta-1,5-diene thiocyanate |
| title | [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II) |
| title_full | [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II) |
| title_fullStr | [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II) |
| title_full_unstemmed | [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II) |
| title_short | [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II) |
| title_sort | 1 2 5 6 η cycloocta 1 5 diene bis thiocyanato κs platinum ii |
| topic | crystal structure platinum(II) complex cycloocta-1,5-diene thiocyanate |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314619001627 |
| work_keys_str_mv | AT kwangha 1256ēcycloocta15dienebisthiocyanatoksplatinumii |