p-Type Polymers for Templated Crystallization of Perovskite Films and Interface Optimization for High Performance Solar Cells

The purity of the perovskite material is of paramount importance as it determines the optoelectronic properties and, hence, the device performance. However, the error during the experiment and incomplete crystallization is inevitable, leading to a low quality. Here, two p-type polymers were designed...

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Main Authors: Wei-Wei Zuo, Weifei Fu, Wan-Sheng Zong, Shen-Gang Xu, Ying-Liang Liu, Shao-Kui Cao
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/11/6/654
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author Wei-Wei Zuo
Weifei Fu
Wan-Sheng Zong
Shen-Gang Xu
Ying-Liang Liu
Shao-Kui Cao
author_facet Wei-Wei Zuo
Weifei Fu
Wan-Sheng Zong
Shen-Gang Xu
Ying-Liang Liu
Shao-Kui Cao
author_sort Wei-Wei Zuo
collection DOAJ
description The purity of the perovskite material is of paramount importance as it determines the optoelectronic properties and, hence, the device performance. However, the error during the experiment and incomplete crystallization is inevitable, leading to a low quality. Here, two p-type polymers were designed to template the crystallization of perovskite to obtain perovskite films with higher crystallinity and higher phase purity. The polymers at the perovskite/transport interface could also improve the charge transfer and, thus, the device performance. In this study, the highest efficiency device achieved an efficiency value of ~19% with improved open-circuit voltage and fill factor.
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spelling doaj.art-89828b077f7b4bdbba294b22b85381442023-11-21T23:23:01ZengMDPI AGCrystals2073-43522021-06-0111665410.3390/cryst11060654p-Type Polymers for Templated Crystallization of Perovskite Films and Interface Optimization for High Performance Solar CellsWei-Wei Zuo0Weifei Fu1Wan-Sheng Zong2Shen-Gang Xu3Ying-Liang Liu4Shao-Kui Cao5Henan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, ChinaState Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, ChinaHenan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, ChinaHenan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, ChinaHenan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, ChinaHenan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, ChinaThe purity of the perovskite material is of paramount importance as it determines the optoelectronic properties and, hence, the device performance. However, the error during the experiment and incomplete crystallization is inevitable, leading to a low quality. Here, two p-type polymers were designed to template the crystallization of perovskite to obtain perovskite films with higher crystallinity and higher phase purity. The polymers at the perovskite/transport interface could also improve the charge transfer and, thus, the device performance. In this study, the highest efficiency device achieved an efficiency value of ~19% with improved open-circuit voltage and fill factor.https://www.mdpi.com/2073-4352/11/6/654templated crystallizationinterfaceperovskitesolar cells
spellingShingle Wei-Wei Zuo
Weifei Fu
Wan-Sheng Zong
Shen-Gang Xu
Ying-Liang Liu
Shao-Kui Cao
p-Type Polymers for Templated Crystallization of Perovskite Films and Interface Optimization for High Performance Solar Cells
Crystals
templated crystallization
interface
perovskite
solar cells
title p-Type Polymers for Templated Crystallization of Perovskite Films and Interface Optimization for High Performance Solar Cells
title_full p-Type Polymers for Templated Crystallization of Perovskite Films and Interface Optimization for High Performance Solar Cells
title_fullStr p-Type Polymers for Templated Crystallization of Perovskite Films and Interface Optimization for High Performance Solar Cells
title_full_unstemmed p-Type Polymers for Templated Crystallization of Perovskite Films and Interface Optimization for High Performance Solar Cells
title_short p-Type Polymers for Templated Crystallization of Perovskite Films and Interface Optimization for High Performance Solar Cells
title_sort p type polymers for templated crystallization of perovskite films and interface optimization for high performance solar cells
topic templated crystallization
interface
perovskite
solar cells
url https://www.mdpi.com/2073-4352/11/6/654
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AT weifeifu ptypepolymersfortemplatedcrystallizationofperovskitefilmsandinterfaceoptimizationforhighperformancesolarcells
AT wanshengzong ptypepolymersfortemplatedcrystallizationofperovskitefilmsandinterfaceoptimizationforhighperformancesolarcells
AT shengangxu ptypepolymersfortemplatedcrystallizationofperovskitefilmsandinterfaceoptimizationforhighperformancesolarcells
AT yingliangliu ptypepolymersfortemplatedcrystallizationofperovskitefilmsandinterfaceoptimizationforhighperformancesolarcells
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