Swelling properties of acrylamide-N,N’-methylene bis(acrylamide) hydrogels synthesized by using meso-2,3-dimercaptosuccinic acid-cerium(IV) redox couple
In this paper, meso-2,3-dimercaptosuccinic acid-Ce(IV) redox couple is used for crosslinking polymerization of acrylamide (AAm) with N,N′-methylene bis(acrylamide) (MBAA) in acid aqueous medium. We have investigated the effects of crosslinker ratio, acid concentration and the molar ratio o...
| Format: | Article |
|---|---|
| Language: | English |
| Published: |
Budapest University of Technology
2009-03-01
|
| Series: | eXPRESS Polymer Letters |
| Subjects: | |
| Online Access: | http://www.expresspolymlett.com/letolt.php?file=EPL-0000878&mi=cd |
| _version_ | 1818563071895928832 |
|---|---|
| collection | DOAJ |
| description | In this paper, meso-2,3-dimercaptosuccinic acid-Ce(IV) redox couple is used for crosslinking polymerization of acrylamide (AAm) with N,N′-methylene bis(acrylamide) (MBAA) in acid aqueous medium. We have investigated the effects of crosslinker ratio, acid concentration and the molar ratio of AAm/Ce(IV) on the swelling behaviors of the synthesized P(AAm-MBAA) hydrogels. The experimental results show that the increase in the nAAm/nMBAA and nAAm/nCe(IV) result in an increase in the swelling ratio and rate of resulting hydrogels. However, the swelling equilibrium ratio and rate have been decreased with increasing of acid concentration. The k and n values in the equation of swelling rate have been determined. The n exponent decreases with increasing crosslinker, initiator and acid concentrations whereas k values increase. Kinetics and equilibrium swelling values have been discussed in terms of reaction parameters. |
| first_indexed | 2024-12-14T01:12:04Z |
| format | Article |
| id | doaj.art-898d3e6d22584033b2f47a67ad320021 |
| institution | Directory Open Access Journal |
| issn | 1788-618X |
| language | English |
| last_indexed | 2024-12-14T01:12:04Z |
| publishDate | 2009-03-01 |
| publisher | Budapest University of Technology |
| record_format | Article |
| series | eXPRESS Polymer Letters |
| spelling | doaj.art-898d3e6d22584033b2f47a67ad3200212022-12-21T23:22:43ZengBudapest University of TechnologyeXPRESS Polymer Letters1788-618X2009-03-013316817610.3144/expresspolymlett.2009.22Swelling properties of acrylamide-N,N’-methylene bis(acrylamide) hydrogels synthesized by using meso-2,3-dimercaptosuccinic acid-cerium(IV) redox coupleIn this paper, meso-2,3-dimercaptosuccinic acid-Ce(IV) redox couple is used for crosslinking polymerization of acrylamide (AAm) with N,N′-methylene bis(acrylamide) (MBAA) in acid aqueous medium. We have investigated the effects of crosslinker ratio, acid concentration and the molar ratio of AAm/Ce(IV) on the swelling behaviors of the synthesized P(AAm-MBAA) hydrogels. The experimental results show that the increase in the nAAm/nMBAA and nAAm/nCe(IV) result in an increase in the swelling ratio and rate of resulting hydrogels. However, the swelling equilibrium ratio and rate have been decreased with increasing of acid concentration. The k and n values in the equation of swelling rate have been determined. The n exponent decreases with increasing crosslinker, initiator and acid concentrations whereas k values increase. Kinetics and equilibrium swelling values have been discussed in terms of reaction parameters.http://www.expresspolymlett.com/letolt.php?file=EPL-0000878&mi=cdPolymer gelsdimercaptosuccinic acidredox initiatoracrylamideswelling |
| spellingShingle | Swelling properties of acrylamide-N,N’-methylene bis(acrylamide) hydrogels synthesized by using meso-2,3-dimercaptosuccinic acid-cerium(IV) redox couple eXPRESS Polymer Letters Polymer gels dimercaptosuccinic acid redox initiator acrylamide swelling |
| title | Swelling properties of acrylamide-N,N’-methylene bis(acrylamide) hydrogels synthesized by using meso-2,3-dimercaptosuccinic acid-cerium(IV) redox couple |
| title_full | Swelling properties of acrylamide-N,N’-methylene bis(acrylamide) hydrogels synthesized by using meso-2,3-dimercaptosuccinic acid-cerium(IV) redox couple |
| title_fullStr | Swelling properties of acrylamide-N,N’-methylene bis(acrylamide) hydrogels synthesized by using meso-2,3-dimercaptosuccinic acid-cerium(IV) redox couple |
| title_full_unstemmed | Swelling properties of acrylamide-N,N’-methylene bis(acrylamide) hydrogels synthesized by using meso-2,3-dimercaptosuccinic acid-cerium(IV) redox couple |
| title_short | Swelling properties of acrylamide-N,N’-methylene bis(acrylamide) hydrogels synthesized by using meso-2,3-dimercaptosuccinic acid-cerium(IV) redox couple |
| title_sort | swelling properties of acrylamide n n methylene bis acrylamide hydrogels synthesized by using meso 2 3 dimercaptosuccinic acid cerium iv redox couple |
| topic | Polymer gels dimercaptosuccinic acid redox initiator acrylamide swelling |
| url | http://www.expresspolymlett.com/letolt.php?file=EPL-0000878&mi=cd |