Removal of Pb2+ ions from aqueous medium by using chitosan-diatomite composite: equilibrium, kinetic and thermodynamic studies

In this study, a novel, low-cost, natural, and highly effective adsorbent, chitosan (Ch) -diatomite (D) composite was synthesized. Ch-D composite was tested as an effective and alternative adsorbent for the removal of Pb2+ ions. The Ch-D composite was characterized by FT-IR, SEM-EDX and PZC analyses...

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Bibliographic Details
Main Authors: Zeynep Mine ŞENOL, Selçuk ŞİMŞEK
Format: Article
Language:English
Published: Turkish Chemical Society 2020-02-01
Series:Journal of the Turkish Chemical Society, Section A: Chemistry
Subjects:
Online Access:https://dergipark.org.tr/en/pub/jotcsa/issue/49279/634590
Description
Summary:In this study, a novel, low-cost, natural, and highly effective adsorbent, chitosan (Ch) -diatomite (D) composite was synthesized. Ch-D composite was tested as an effective and alternative adsorbent for the removal of Pb2+ ions. The Ch-D composite was characterized by FT-IR, SEM-EDX and PZC analyses. The adsorption process of Pb2+ ions onto Ch-D as initial lead concentration, solution pH, temperature, contact time and recovery was investigated. From the adsorption process results, it has been observed that the highest removal efficiency is approximately 95% at a contact time of 4-hour, initial Pb2+ concentration of 500 mg L-1 and agitation speed of 150 rpm at natural pH 4.0. The maximum Pb2+ adsorption capacity from the Langmuir model was found as 0.154 mol kg-1 at 25 oC. Besides, adsorption kinetics was also explained with pseudo-first-order models. Adsorption thermodynamics have shown that Pb2+ adsorption onto Ch-D is possible, spontaneous and exothermic. Ch-D composite can become an alternative adsorbent for the treatment of lead ions in the wastewater.
ISSN:2149-0120