In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst
A fourth-generation Ziegler-Natta catalyst was prepared to synthesize polypropylene (PP), which was stabilized by in situpolymerization employing lignin as antioxidant. The antioxidant properties of lignin were compared with those of the commercial antioxidant Irganox 1010. The presence of lignin in...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Iran Polymer and Petrochemical Institute
2014-01-01
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| Series: | Polyolefins Journal |
| Subjects: | |
| Online Access: | http://poj.ippi.ac.ir/article_889_d231796666c0dcdb0c4b8576190f7a4b.pdf |
| _version_ | 1819040785283153920 |
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| author | Maria Marques Renato Oliveira Rafael Araujo Bruno Amantes |
| author_facet | Maria Marques Renato Oliveira Rafael Araujo Bruno Amantes |
| author_sort | Maria Marques |
| collection | DOAJ |
| description | A fourth-generation Ziegler-Natta catalyst was prepared to synthesize polypropylene (PP), which was stabilized by in situpolymerization employing lignin as antioxidant. The antioxidant properties of lignin were compared with those of the commercial antioxidant Irganox 1010. The presence of lignin in the reaction medium slightly decreased the catalytic activity of the reaction. The isotacticity index (I.I.) of PP synthesized with lignin (PP-lig) was not affected by the presence of the additive in the reaction medium. The thermal properties, characterized by differential scanning calorimetry, showed slightly decreased degree of crystallinity (Xc), but the melting temperature (Tm) and crystallization temperature (Tc) were not affected when compared with the neat polymer. Lignin showed good activity as a stabilizer by thermogravimetry. The initial temperature of degradation (Tonset) increased when compared to the pure PP and PP stabilized with the commercial antioxidant. The lower carbonyl index of the PP, evaluated by infrared spectroscopy (FTIR) after thermo-oxidative treatment, also revealed the stabilizing action of lignin. |
| first_indexed | 2024-12-21T09:14:37Z |
| format | Article |
| id | doaj.art-89af1eba15ad487e8456f2aa2a3580c6 |
| institution | Directory Open Access Journal |
| issn | 2322-2212 2345-6868 |
| language | English |
| last_indexed | 2024-12-21T09:14:37Z |
| publishDate | 2014-01-01 |
| publisher | Iran Polymer and Petrochemical Institute |
| record_format | Article |
| series | Polyolefins Journal |
| spelling | doaj.art-89af1eba15ad487e8456f2aa2a3580c62022-12-21T19:09:10ZengIran Polymer and Petrochemical InstitutePolyolefins Journal2322-22122345-68682014-01-0111172410.22063/poj.2014.889889In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalystMaria Marques0Renato Oliveira1Rafael Araujo2Bruno Amantes3Instituto de Macromoléculas (IMA) - Universidade Federal do Rio de Janeiro - UFRJ, CP 68525, CEP 21941- 590, Rio de Janeiro-RJ, BrazilInstituto de Macromoléculas (IMA) - Universidade Federal do Rio de Janeiro - UFRJ, CP 68525, CEP 21941- 590, Rio de Janeiro-RJ, BrazilInstituto de Macromoléculas (IMA) - Universidade Federal do Rio de Janeiro - UFRJ, CP 68525, CEP 21941- 590, Rio de Janeiro-RJ, BrazilInstituto de Macromoléculas (IMA) - Universidade Federal do Rio de Janeiro - UFRJ, CP 68525, CEP 21941- 590, Rio de Janeiro-RJ, BrazilA fourth-generation Ziegler-Natta catalyst was prepared to synthesize polypropylene (PP), which was stabilized by in situpolymerization employing lignin as antioxidant. The antioxidant properties of lignin were compared with those of the commercial antioxidant Irganox 1010. The presence of lignin in the reaction medium slightly decreased the catalytic activity of the reaction. The isotacticity index (I.I.) of PP synthesized with lignin (PP-lig) was not affected by the presence of the additive in the reaction medium. The thermal properties, characterized by differential scanning calorimetry, showed slightly decreased degree of crystallinity (Xc), but the melting temperature (Tm) and crystallization temperature (Tc) were not affected when compared with the neat polymer. Lignin showed good activity as a stabilizer by thermogravimetry. The initial temperature of degradation (Tonset) increased when compared to the pure PP and PP stabilized with the commercial antioxidant. The lower carbonyl index of the PP, evaluated by infrared spectroscopy (FTIR) after thermo-oxidative treatment, also revealed the stabilizing action of lignin.http://poj.ippi.ac.ir/article_889_d231796666c0dcdb0c4b8576190f7a4b.pdfAntioxidantpolypropyleneZiegler-Natta catalyst |
| spellingShingle | Maria Marques Renato Oliveira Rafael Araujo Bruno Amantes In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst Polyolefins Journal Antioxidant polypropylene Ziegler-Natta catalyst |
| title | In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst |
| title_full | In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst |
| title_fullStr | In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst |
| title_full_unstemmed | In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst |
| title_short | In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst |
| title_sort | in situ stabilization of polypropylene by lignin using a ziegler natta catalyst |
| topic | Antioxidant polypropylene Ziegler-Natta catalyst |
| url | http://poj.ippi.ac.ir/article_889_d231796666c0dcdb0c4b8576190f7a4b.pdf |
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