The in-situ NMR evidence of gas hydrate forming in micro-pores in the Shenhu area, South China Sea

Nuclear magnetic resonance (NMR) measurement could provide information during the formation and dissociation of gas hydrate on the pore structure properties which are of great important to understand the gas production behavior. In this study, the in–situ NMR and other well logging data achieved dur...

Full description

Bibliographic Details
Main Authors: Yingfeng Xie, Jing’an Lu, Huimin Cai, Wei Deng, Zenggui Kuang, Tong Wang, Dongju Kang, Chaoqi Zhu
Format: Article
Language:English
Published: Elsevier 2022-11-01
Series:Energy Reports
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2352484722000981
_version_ 1828011168723107840
author Yingfeng Xie
Jing’an Lu
Huimin Cai
Wei Deng
Zenggui Kuang
Tong Wang
Dongju Kang
Chaoqi Zhu
author_facet Yingfeng Xie
Jing’an Lu
Huimin Cai
Wei Deng
Zenggui Kuang
Tong Wang
Dongju Kang
Chaoqi Zhu
author_sort Yingfeng Xie
collection DOAJ
description Nuclear magnetic resonance (NMR) measurement could provide information during the formation and dissociation of gas hydrate on the pore structure properties which are of great important to understand the gas production behavior. In this study, the in–situ NMR and other well logging data achieved during the natural gas hydrate drilling program were used to study the pore size and hydrate formation properties in the Shenhu area, South China Sea by comparing transverse magnetic relaxation time (T2) distributions between the gas hydrate zone and the upper water–saturated zone whose properties represent the virgin status. Compared with those of the upper water–saturated layer, increasing resistivity, higher–than–baseline shear modulus, less–than–density–porosity NMR porosity, shortening T2 peak time, reducing amplitude and covered area of T2 distributions and decreasing water–filling pore size denote the association of hydrate. Based on eight bin porosities distribution derived from user-defined time intervals of the T2 distribution for researching the hydrate formation characteristic in different pore size, macro–pores (T2 ≥ 10 ms, rc≥ 0.9 μm), meso–pores (3 ms ≤ T2 < 10 ms, 0.27 μm ≤rc<0.9μm) and micro–pores (T2 < 3 ms, rc< 0.27 μm) were divided. It was found that the meso–pores are the dominant pore size in the Shenhu area, but hydrate form more easily in the macro–pores. Just as the previous experience, gas hydrate forms primarily in macro–pores and meso–pores resulting in an increase of micro–pores. In addition, another mode was achieved that gas hydrate forms in the three types of pore spaces leading to a decrease of micro–pores. Both forming modes can develop reservoirs with high hydrate saturation that can exceed 30%.
first_indexed 2024-04-10T09:12:16Z
format Article
id doaj.art-89c6aad6082d4b57a2f468369a0160f9
institution Directory Open Access Journal
issn 2352-4847
language English
last_indexed 2024-04-10T09:12:16Z
publishDate 2022-11-01
publisher Elsevier
record_format Article
series Energy Reports
spelling doaj.art-89c6aad6082d4b57a2f468369a0160f92023-02-21T05:10:12ZengElsevierEnergy Reports2352-48472022-11-01829362946The in-situ NMR evidence of gas hydrate forming in micro-pores in the Shenhu area, South China SeaYingfeng Xie0Jing’an Lu1Huimin Cai2Wei Deng3Zenggui Kuang4Tong Wang5Dongju Kang6Chaoqi Zhu7Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou), Guangzhou, 511458, China; Guangzhou Marine Geological Survey, China Geological Survey, Guangzhou, 510075, ChinaSouthern Marine Science and Engineering Guangdong Laboratory (Guangzhou), Guangzhou, 511458, China; Guangzhou Marine Geological Survey, China Geological Survey, Guangzhou, 510075, China; Corresponding authors.Schlumberger China Petroleum Institute, Beijing, 100015, ChinaSouthern Marine Science and Engineering Guangdong Laboratory (Guangzhou), Guangzhou, 511458, China; Guangzhou Marine Geological Survey, China Geological Survey, Guangzhou, 510075, ChinaSouthern Marine Science and Engineering Guangdong Laboratory (Guangzhou), Guangzhou, 511458, China; Guangzhou Marine Geological Survey, China Geological Survey, Guangzhou, 510075, ChinaGuangzhou Marine Geological Survey, China Geological Survey, Guangzhou, 510075, ChinaGuangzhou Marine Geological Survey, China Geological Survey, Guangzhou, 510075, ChinaShandong Provincial Key Laboratory of Marine Environment and Geological Engineering (Ocean University of China), Qingdao, 266100, China; Laboratory for Marine Geology, Qingdao National Laboratory for Marine Science and Technology, Qingdao, 266061, China; Hainan Key Laboratory of Marine Geological Resources and Environment, Hainan, 570206, China; Key Laboratory of Submarine Geosciences and Prospecting Techniques, Ministry of Education, Ocean University of China, Qingdao, 266100, China; Corresponding authors.Nuclear magnetic resonance (NMR) measurement could provide information during the formation and dissociation of gas hydrate on the pore structure properties which are of great important to understand the gas production behavior. In this study, the in–situ NMR and other well logging data achieved during the natural gas hydrate drilling program were used to study the pore size and hydrate formation properties in the Shenhu area, South China Sea by comparing transverse magnetic relaxation time (T2) distributions between the gas hydrate zone and the upper water–saturated zone whose properties represent the virgin status. Compared with those of the upper water–saturated layer, increasing resistivity, higher–than–baseline shear modulus, less–than–density–porosity NMR porosity, shortening T2 peak time, reducing amplitude and covered area of T2 distributions and decreasing water–filling pore size denote the association of hydrate. Based on eight bin porosities distribution derived from user-defined time intervals of the T2 distribution for researching the hydrate formation characteristic in different pore size, macro–pores (T2 ≥ 10 ms, rc≥ 0.9 μm), meso–pores (3 ms ≤ T2 < 10 ms, 0.27 μm ≤rc<0.9μm) and micro–pores (T2 < 3 ms, rc< 0.27 μm) were divided. It was found that the meso–pores are the dominant pore size in the Shenhu area, but hydrate form more easily in the macro–pores. Just as the previous experience, gas hydrate forms primarily in macro–pores and meso–pores resulting in an increase of micro–pores. In addition, another mode was achieved that gas hydrate forms in the three types of pore spaces leading to a decrease of micro–pores. Both forming modes can develop reservoirs with high hydrate saturation that can exceed 30%.http://www.sciencedirect.com/science/article/pii/S2352484722000981Nuclear magnetic resonance (NMR) loggingTransverse magnetic relaxation time (T2) distributionPore sizeBin porosityGas hydrate formation mode
spellingShingle Yingfeng Xie
Jing’an Lu
Huimin Cai
Wei Deng
Zenggui Kuang
Tong Wang
Dongju Kang
Chaoqi Zhu
The in-situ NMR evidence of gas hydrate forming in micro-pores in the Shenhu area, South China Sea
Energy Reports
Nuclear magnetic resonance (NMR) logging
Transverse magnetic relaxation time (T2) distribution
Pore size
Bin porosity
Gas hydrate formation mode
title The in-situ NMR evidence of gas hydrate forming in micro-pores in the Shenhu area, South China Sea
title_full The in-situ NMR evidence of gas hydrate forming in micro-pores in the Shenhu area, South China Sea
title_fullStr The in-situ NMR evidence of gas hydrate forming in micro-pores in the Shenhu area, South China Sea
title_full_unstemmed The in-situ NMR evidence of gas hydrate forming in micro-pores in the Shenhu area, South China Sea
title_short The in-situ NMR evidence of gas hydrate forming in micro-pores in the Shenhu area, South China Sea
title_sort in situ nmr evidence of gas hydrate forming in micro pores in the shenhu area south china sea
topic Nuclear magnetic resonance (NMR) logging
Transverse magnetic relaxation time (T2) distribution
Pore size
Bin porosity
Gas hydrate formation mode
url http://www.sciencedirect.com/science/article/pii/S2352484722000981
work_keys_str_mv AT yingfengxie theinsitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT jinganlu theinsitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT huimincai theinsitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT weideng theinsitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT zengguikuang theinsitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT tongwang theinsitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT dongjukang theinsitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT chaoqizhu theinsitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT yingfengxie insitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT jinganlu insitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT huimincai insitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT weideng insitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT zengguikuang insitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT tongwang insitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT dongjukang insitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea
AT chaoqizhu insitunmrevidenceofgashydrateforminginmicroporesintheshenhuareasouthchinasea