Synthesis and Structure of a New Iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> with a Complex Framework Based on the Condensation of [Sc(IO<sub>3</sub>)<sub>6</sub>] Building Blocks
Transparent single crystals of a new iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> were synthesized under mild hydrothermal conditions. X-ray diffraction of single crystal was used...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-09-01
|
| Series: | Symmetry |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-8994/15/9/1777 |
| _version_ | 1797576551718453248 |
|---|---|
| author | Olga V. Reutova Elena L. Belokoneva Anatoly S. Volkov Olga V. Dimitrova |
| author_facet | Olga V. Reutova Elena L. Belokoneva Anatoly S. Volkov Olga V. Dimitrova |
| author_sort | Olga V. Reutova |
| collection | DOAJ |
| description | Transparent single crystals of a new iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> were synthesized under mild hydrothermal conditions. X-ray diffraction of single crystal was used to determine the large crystal structure with 52 independent atoms, sp. gr. <i>P</i>2<sub>1</sub>/<i>c</i>. The building blocks [Sc(IO<sub>3</sub>)<sub>6</sub>]<sup>3−</sup> of Sc octahedra and six (IO<sub>3</sub>) groups are condensed into a framework; the structure contains additional isolated (IO<sub>3</sub>) groups. Large Cs cations occupy holes and form an intercrossing framework. Similar building blocks [M(IO<sub>3</sub>)<sub>6</sub>] are known for many iodates; however, most are isolated. Their topology and symmetry differ and determine the properties of the compounds. |
| first_indexed | 2024-03-10T21:54:39Z |
| format | Article |
| id | doaj.art-89d23351b4fc46a188efedc2bbba4acd |
| institution | Directory Open Access Journal |
| issn | 2073-8994 |
| language | English |
| last_indexed | 2024-03-10T21:54:39Z |
| publishDate | 2023-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Symmetry |
| spelling | doaj.art-89d23351b4fc46a188efedc2bbba4acd2023-11-19T13:12:31ZengMDPI AGSymmetry2073-89942023-09-01159177710.3390/sym15091777Synthesis and Structure of a New Iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> with a Complex Framework Based on the Condensation of [Sc(IO<sub>3</sub>)<sub>6</sub>] Building BlocksOlga V. Reutova0Elena L. Belokoneva1Anatoly S. Volkov2Olga V. Dimitrova3Department of Crystallography and Crystal Chemistry, Geological Faculty, Lomonosov Moscow State University, Moscow 119991, RussiaDepartment of Crystallography and Crystal Chemistry, Geological Faculty, Lomonosov Moscow State University, Moscow 119991, RussiaSkolkovo Institute of Science and Technology, Moscow 121205, RussiaDepartment of Crystallography and Crystal Chemistry, Geological Faculty, Lomonosov Moscow State University, Moscow 119991, RussiaTransparent single crystals of a new iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> were synthesized under mild hydrothermal conditions. X-ray diffraction of single crystal was used to determine the large crystal structure with 52 independent atoms, sp. gr. <i>P</i>2<sub>1</sub>/<i>c</i>. The building blocks [Sc(IO<sub>3</sub>)<sub>6</sub>]<sup>3−</sup> of Sc octahedra and six (IO<sub>3</sub>) groups are condensed into a framework; the structure contains additional isolated (IO<sub>3</sub>) groups. Large Cs cations occupy holes and form an intercrossing framework. Similar building blocks [M(IO<sub>3</sub>)<sub>6</sub>] are known for many iodates; however, most are isolated. Their topology and symmetry differ and determine the properties of the compounds.https://www.mdpi.com/2073-8994/15/9/1777iodatehydrothermal synthesissingle crystal structurebuilding blockcomplex framework |
| spellingShingle | Olga V. Reutova Elena L. Belokoneva Anatoly S. Volkov Olga V. Dimitrova Synthesis and Structure of a New Iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> with a Complex Framework Based on the Condensation of [Sc(IO<sub>3</sub>)<sub>6</sub>] Building Blocks Symmetry iodate hydrothermal synthesis single crystal structure building block complex framework |
| title | Synthesis and Structure of a New Iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> with a Complex Framework Based on the Condensation of [Sc(IO<sub>3</sub>)<sub>6</sub>] Building Blocks |
| title_full | Synthesis and Structure of a New Iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> with a Complex Framework Based on the Condensation of [Sc(IO<sub>3</sub>)<sub>6</sub>] Building Blocks |
| title_fullStr | Synthesis and Structure of a New Iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> with a Complex Framework Based on the Condensation of [Sc(IO<sub>3</sub>)<sub>6</sub>] Building Blocks |
| title_full_unstemmed | Synthesis and Structure of a New Iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> with a Complex Framework Based on the Condensation of [Sc(IO<sub>3</sub>)<sub>6</sub>] Building Blocks |
| title_short | Synthesis and Structure of a New Iodate Cs<sub>5</sub>[Sc<sub>2</sub>(IO<sub>3</sub>)<sub>9</sub>](IO<sub>3</sub>)<sub>2</sub> with a Complex Framework Based on the Condensation of [Sc(IO<sub>3</sub>)<sub>6</sub>] Building Blocks |
| title_sort | synthesis and structure of a new iodate cs sub 5 sub sc sub 2 sub io sub 3 sub sub 9 sub io sub 3 sub sub 2 sub with a complex framework based on the condensation of sc io sub 3 sub sub 6 sub building blocks |
| topic | iodate hydrothermal synthesis single crystal structure building block complex framework |
| url | https://www.mdpi.com/2073-8994/15/9/1777 |
| work_keys_str_mv | AT olgavreutova synthesisandstructureofanewiodatecssub5subscsub2subiosub3subsub9subiosub3subsub2subwithacomplexframeworkbasedonthecondensationofsciosub3subsub6subbuildingblocks AT elenalbelokoneva synthesisandstructureofanewiodatecssub5subscsub2subiosub3subsub9subiosub3subsub2subwithacomplexframeworkbasedonthecondensationofsciosub3subsub6subbuildingblocks AT anatolysvolkov synthesisandstructureofanewiodatecssub5subscsub2subiosub3subsub9subiosub3subsub2subwithacomplexframeworkbasedonthecondensationofsciosub3subsub6subbuildingblocks AT olgavdimitrova synthesisandstructureofanewiodatecssub5subscsub2subiosub3subsub9subiosub3subsub2subwithacomplexframeworkbasedonthecondensationofsciosub3subsub6subbuildingblocks |