Preparation of a strong, high prepressing intensity, and multifunction soybean protein adhesive by using hyperbranched functional polymer
The preparation of a soybean protein adhesive with good prepressing intensity, mildew proof, flame retardant, and high bond strength are conducive to the wide application of a soybean protein adhesive, which is important but challenging for the wood-based panel industry. In this study, two hyperbran...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-02-01
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| Series: | Polymer Testing |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S0142941823000119 |
| _version_ | 1811169496498438144 |
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| author | Zheng Liu Tao Liu Jieyu Zhang Yue Li Jing Luo Jianzhang Li Sheldon Q. Shi Qiang Gao An Mao |
| author_facet | Zheng Liu Tao Liu Jieyu Zhang Yue Li Jing Luo Jianzhang Li Sheldon Q. Shi Qiang Gao An Mao |
| author_sort | Zheng Liu |
| collection | DOAJ |
| description | The preparation of a soybean protein adhesive with good prepressing intensity, mildew proof, flame retardant, and high bond strength are conducive to the wide application of a soybean protein adhesive, which is important but challenging for the wood-based panel industry. In this study, two hyperbranched functional polymers were designed. Hyperbranched polyamide (HP) was grafted by 3-hydroxyphenylphosphinyl-propanoic acid (PPA) to obtain PPA@HP and then combined with self-synthesized epoxidized tannin (ETA) to modify the soybean protein adhesive. The hyperbranched functional polymer PPA@HP and ETA reacted with soybean protein to form a hyperbranched cross-linking structure and a hydrogen bond network, which noticeably improved the toughness and bond strength of the adhesive. The wet shear strength of the resultant plywood was improved by 110.9% to 1.35 MPa. The formed hyperbranched hydrogen bond network also significantly improved the prepressing intensity (by 129.0% to 0.71 MPa). In addition, the anti-mildew time increased from 24 h to 120 h. The time to block combustibles increased from 5 s to 80 s, and the limiting oxygen index improved from 23.5% to 38.5%. The use of hyperbranched functional polymers created covalent and non-covalent hybrid networks provides an effective and convenient strategy for developing high-strength and multifunctional composites, such as bio-adhesives, hydrogels, and films. |
| first_indexed | 2024-04-10T16:43:24Z |
| format | Article |
| id | doaj.art-89f465fdcc1349ee803623f4fadc1a56 |
| institution | Directory Open Access Journal |
| issn | 0142-9418 |
| language | English |
| last_indexed | 2024-04-10T16:43:24Z |
| publishDate | 2023-02-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Polymer Testing |
| spelling | doaj.art-89f465fdcc1349ee803623f4fadc1a562023-02-08T04:16:16ZengElsevierPolymer Testing0142-94182023-02-01119107931Preparation of a strong, high prepressing intensity, and multifunction soybean protein adhesive by using hyperbranched functional polymerZheng Liu0Tao Liu1Jieyu Zhang2Yue Li3Jing Luo4Jianzhang Li5Sheldon Q. Shi6Qiang Gao7An Mao8MOE Key Laboratory of Wooden Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing, 100083, ChinaMOE Key Laboratory of Wooden Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing, 100083, ChinaMOE Key Laboratory of Wooden Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing, 100083, ChinaMOE Key Laboratory of Wooden Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing, 100083, ChinaCollege of Materials Science and Engineering, Nanjing Forestry University, Longpan Road 159, Xuanwu District, Nanjing, 210037, ChinaMOE Key Laboratory of Wooden Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing, 100083, ChinaMechanical Engineering, University of North Texas, Denton, TX, 76203, USAMOE Key Laboratory of Wooden Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing, 100083, China; Corresponding author.State Forestry and Grassland Administration Key Laboratory of Silviculture in Downstream Areas of the Yellow River, College of Forestry, Shandong Agricultural University, Tai'an, 271000, China; Corresponding author.The preparation of a soybean protein adhesive with good prepressing intensity, mildew proof, flame retardant, and high bond strength are conducive to the wide application of a soybean protein adhesive, which is important but challenging for the wood-based panel industry. In this study, two hyperbranched functional polymers were designed. Hyperbranched polyamide (HP) was grafted by 3-hydroxyphenylphosphinyl-propanoic acid (PPA) to obtain PPA@HP and then combined with self-synthesized epoxidized tannin (ETA) to modify the soybean protein adhesive. The hyperbranched functional polymer PPA@HP and ETA reacted with soybean protein to form a hyperbranched cross-linking structure and a hydrogen bond network, which noticeably improved the toughness and bond strength of the adhesive. The wet shear strength of the resultant plywood was improved by 110.9% to 1.35 MPa. The formed hyperbranched hydrogen bond network also significantly improved the prepressing intensity (by 129.0% to 0.71 MPa). In addition, the anti-mildew time increased from 24 h to 120 h. The time to block combustibles increased from 5 s to 80 s, and the limiting oxygen index improved from 23.5% to 38.5%. The use of hyperbranched functional polymers created covalent and non-covalent hybrid networks provides an effective and convenient strategy for developing high-strength and multifunctional composites, such as bio-adhesives, hydrogels, and films.http://www.sciencedirect.com/science/article/pii/S0142941823000119Soybean protein adhesiveHyperbranched functional polymerMultifunctionality |
| spellingShingle | Zheng Liu Tao Liu Jieyu Zhang Yue Li Jing Luo Jianzhang Li Sheldon Q. Shi Qiang Gao An Mao Preparation of a strong, high prepressing intensity, and multifunction soybean protein adhesive by using hyperbranched functional polymer Polymer Testing Soybean protein adhesive Hyperbranched functional polymer Multifunctionality |
| title | Preparation of a strong, high prepressing intensity, and multifunction soybean protein adhesive by using hyperbranched functional polymer |
| title_full | Preparation of a strong, high prepressing intensity, and multifunction soybean protein adhesive by using hyperbranched functional polymer |
| title_fullStr | Preparation of a strong, high prepressing intensity, and multifunction soybean protein adhesive by using hyperbranched functional polymer |
| title_full_unstemmed | Preparation of a strong, high prepressing intensity, and multifunction soybean protein adhesive by using hyperbranched functional polymer |
| title_short | Preparation of a strong, high prepressing intensity, and multifunction soybean protein adhesive by using hyperbranched functional polymer |
| title_sort | preparation of a strong high prepressing intensity and multifunction soybean protein adhesive by using hyperbranched functional polymer |
| topic | Soybean protein adhesive Hyperbranched functional polymer Multifunctionality |
| url | http://www.sciencedirect.com/science/article/pii/S0142941823000119 |
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