Sedimentary Environment and Organic Accumulation of the Ordovician–Silurian Black Shale in Weiyuan, Sichuan Basin, China

The sedimentary environment and organic matter enrichment relationship of the Upper Ordovician Wufeng Formation black shale, Guanyinqiao mudstone, and Lower Silurian Longmaxi Formation black shale in the Sichuan Basin of Weiyuan are analyzed using geochemical methods such as organic carbon, sulfur,...

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Main Authors: Wei Fu, Wangshui Hu, Quansheng Cai, Sile Wei, Jiachao She, Xiaochen Wang, Xiaodong Liu
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/13/9/1161
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author Wei Fu
Wangshui Hu
Quansheng Cai
Sile Wei
Jiachao She
Xiaochen Wang
Xiaodong Liu
author_facet Wei Fu
Wangshui Hu
Quansheng Cai
Sile Wei
Jiachao She
Xiaochen Wang
Xiaodong Liu
author_sort Wei Fu
collection DOAJ
description The sedimentary environment and organic matter enrichment relationship of the Upper Ordovician Wufeng Formation black shale, Guanyinqiao mudstone, and Lower Silurian Longmaxi Formation black shale in the Sichuan Basin of Weiyuan are analyzed using geochemical methods such as organic carbon, sulfur, major elements, and trace elements. The experimental results illustrate that the upper section of the Wufeng Formation and the lower section of the Longmaxi Formation are organic matter enrichment layers. The presence of P indicates a high productivity level in the Sichuan Basin from the Late Ordovician to the Early Silurian. In addition, indicators such as V/Cr, Ni/Co, and S/C suggest that the Wufeng Formation was deposited under anoxic reductive conditions, that the ice age Guanyinqiao segment was in an oxygen-rich to oxygen-poor environment, and that the Longmaxi Formation was in a sulfidic environment. Mo/TOC indicates that the Wufeng Formation shale was controlled by a restricted basin and that the Guanyinqiao segment and the Longmaxi Formation were in a medium-to-weak retention environment. The weak correlation of TOC with P/Al and Al indicates that the level of primary productivity and terrigenous detritus had a minor effect on the organic matter enrichment of the Wufeng and Longmaxi Formation black shale. Conversely, the positive correlation of TOC with V/Cr and Ni/Co illustrates that the anoxic reductive sedimentary environment is the main factor affecting the organic matter enrichment of the Wufeng and Longmaxi Formation black shale. Based on these studies, the development model of organic-rich shales of the Ordovician–Silurian in Weiyuan, Sichuan Basin is proposed. This paper may provide a reference for shale gas exploration in the Wufeng–Longmaxi Formation and a sedimentary response to the major geological events of Ordovician–Silurian.
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spelling doaj.art-8a088bfb27184f7d99387d0eb16ae41d2023-11-19T12:05:11ZengMDPI AGMinerals2075-163X2023-08-01139116110.3390/min13091161Sedimentary Environment and Organic Accumulation of the Ordovician–Silurian Black Shale in Weiyuan, Sichuan Basin, ChinaWei Fu0Wangshui Hu1Quansheng Cai2Sile Wei3Jiachao She4Xiaochen Wang5Xiaodong Liu6School of Geosciences, Yangtze University, Wuhan 430100, ChinaSchool of Geosciences, Yangtze University, Wuhan 430100, ChinaSchool of Geosciences, Yangtze University, Wuhan 430100, ChinaSchool of Geosciences, Yangtze University, Wuhan 430100, ChinaPetroChina, Tuha Oilfield Company, Hami 839099, ChinaQHSE Supervision Center of PetroChina Huabei Oilfield Company, Renqiu 062522, ChinaDownhole Services Company BHDC, Renqiu 062522, ChinaThe sedimentary environment and organic matter enrichment relationship of the Upper Ordovician Wufeng Formation black shale, Guanyinqiao mudstone, and Lower Silurian Longmaxi Formation black shale in the Sichuan Basin of Weiyuan are analyzed using geochemical methods such as organic carbon, sulfur, major elements, and trace elements. The experimental results illustrate that the upper section of the Wufeng Formation and the lower section of the Longmaxi Formation are organic matter enrichment layers. The presence of P indicates a high productivity level in the Sichuan Basin from the Late Ordovician to the Early Silurian. In addition, indicators such as V/Cr, Ni/Co, and S/C suggest that the Wufeng Formation was deposited under anoxic reductive conditions, that the ice age Guanyinqiao segment was in an oxygen-rich to oxygen-poor environment, and that the Longmaxi Formation was in a sulfidic environment. Mo/TOC indicates that the Wufeng Formation shale was controlled by a restricted basin and that the Guanyinqiao segment and the Longmaxi Formation were in a medium-to-weak retention environment. The weak correlation of TOC with P/Al and Al indicates that the level of primary productivity and terrigenous detritus had a minor effect on the organic matter enrichment of the Wufeng and Longmaxi Formation black shale. Conversely, the positive correlation of TOC with V/Cr and Ni/Co illustrates that the anoxic reductive sedimentary environment is the main factor affecting the organic matter enrichment of the Wufeng and Longmaxi Formation black shale. Based on these studies, the development model of organic-rich shales of the Ordovician–Silurian in Weiyuan, Sichuan Basin is proposed. This paper may provide a reference for shale gas exploration in the Wufeng–Longmaxi Formation and a sedimentary response to the major geological events of Ordovician–Silurian.https://www.mdpi.com/2075-163X/13/9/1161south SichuanWeiyuan areablack shalesedimentary environmentWufeng formationLongmaxi formation
spellingShingle Wei Fu
Wangshui Hu
Quansheng Cai
Sile Wei
Jiachao She
Xiaochen Wang
Xiaodong Liu
Sedimentary Environment and Organic Accumulation of the Ordovician–Silurian Black Shale in Weiyuan, Sichuan Basin, China
Minerals
south Sichuan
Weiyuan area
black shale
sedimentary environment
Wufeng formation
Longmaxi formation
title Sedimentary Environment and Organic Accumulation of the Ordovician–Silurian Black Shale in Weiyuan, Sichuan Basin, China
title_full Sedimentary Environment and Organic Accumulation of the Ordovician–Silurian Black Shale in Weiyuan, Sichuan Basin, China
title_fullStr Sedimentary Environment and Organic Accumulation of the Ordovician–Silurian Black Shale in Weiyuan, Sichuan Basin, China
title_full_unstemmed Sedimentary Environment and Organic Accumulation of the Ordovician–Silurian Black Shale in Weiyuan, Sichuan Basin, China
title_short Sedimentary Environment and Organic Accumulation of the Ordovician–Silurian Black Shale in Weiyuan, Sichuan Basin, China
title_sort sedimentary environment and organic accumulation of the ordovician silurian black shale in weiyuan sichuan basin china
topic south Sichuan
Weiyuan area
black shale
sedimentary environment
Wufeng formation
Longmaxi formation
url https://www.mdpi.com/2075-163X/13/9/1161
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