Effect of Pore Size and Film Thickness on Gold-Coated Nanoporous Anodic Aluminum Oxide Substrates for Surface-Enhanced Raman Scattering Sensor

A sensitive surface enhanced Raman scattering chemical sensor is demonstrated by using inexpensive gold-coated nanoporous anodic aluminum oxide substrates. To optimize the performance of the substrates for sensing by the Surface-enhanced Raman scattering (SERS) technique, the size of the nanopores i...

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Main Authors: Aschalew Kassu, Carlton Farley, Anup Sharma, Wonkyu Kim, Junpeng Guo
Format: Article
Language:English
Published: MDPI AG 2015-11-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/15/12/29778
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author Aschalew Kassu
Carlton Farley
Anup Sharma
Wonkyu Kim
Junpeng Guo
author_facet Aschalew Kassu
Carlton Farley
Anup Sharma
Wonkyu Kim
Junpeng Guo
author_sort Aschalew Kassu
collection DOAJ
description A sensitive surface enhanced Raman scattering chemical sensor is demonstrated by using inexpensive gold-coated nanoporous anodic aluminum oxide substrates. To optimize the performance of the substrates for sensing by the Surface-enhanced Raman scattering (SERS) technique, the size of the nanopores is varied from 18 nm to 150 nm and the gold film thickness is varied from 30 nm to 120 nm. The sensitivity of gold-coated nanoporous surface enhanced Raman scattering sensor is characterized by detecting low concentrations of Rhodamine 6G laser dye molecules. The morphology of the SERS substrates is characterized by atomic force microscopy. Optical properties of the nanoporous SERS substrates including transmittance, reflectance, and absorbance are also investigated. Relative signal enhancement is plotted for a range of substrate parameters and a detection limit of 10−6 M is established.
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spelling doaj.art-8a330e83d1c941d68f24c8f42746620b2022-12-22T04:04:00ZengMDPI AGSensors1424-82202015-11-011512299242993710.3390/s151229778s151229778Effect of Pore Size and Film Thickness on Gold-Coated Nanoporous Anodic Aluminum Oxide Substrates for Surface-Enhanced Raman Scattering SensorAschalew Kassu0Carlton Farley1Anup Sharma2Wonkyu Kim3Junpeng Guo4Department of Engineering, Construction Management & Ind. Tech., Alabama A & M University, 4900 Meridian Street, Normal, AL 35762, USADepartment of Physics, Chemistry and Mathematics, Alabama A & M University, 4900 Meridian Street, Normal, AL 35762, USADepartment of Physics, Chemistry and Mathematics, Alabama A & M University, 4900 Meridian Street, Normal, AL 35762, USADepartment of Electrical and Computer Engineering, University of Alabama in Huntsville, 301 Sparkman Dr., Huntsville, AL 35899, USADepartment of Electrical and Computer Engineering, University of Alabama in Huntsville, 301 Sparkman Dr., Huntsville, AL 35899, USAA sensitive surface enhanced Raman scattering chemical sensor is demonstrated by using inexpensive gold-coated nanoporous anodic aluminum oxide substrates. To optimize the performance of the substrates for sensing by the Surface-enhanced Raman scattering (SERS) technique, the size of the nanopores is varied from 18 nm to 150 nm and the gold film thickness is varied from 30 nm to 120 nm. The sensitivity of gold-coated nanoporous surface enhanced Raman scattering sensor is characterized by detecting low concentrations of Rhodamine 6G laser dye molecules. The morphology of the SERS substrates is characterized by atomic force microscopy. Optical properties of the nanoporous SERS substrates including transmittance, reflectance, and absorbance are also investigated. Relative signal enhancement is plotted for a range of substrate parameters and a detection limit of 10−6 M is established.http://www.mdpi.com/1424-8220/15/12/29778surface enhanced Raman scatteringsensingnanoporous substratesanodic aluminum oxidechemical sensoroptical sensorceramic membranes
spellingShingle Aschalew Kassu
Carlton Farley
Anup Sharma
Wonkyu Kim
Junpeng Guo
Effect of Pore Size and Film Thickness on Gold-Coated Nanoporous Anodic Aluminum Oxide Substrates for Surface-Enhanced Raman Scattering Sensor
Sensors
surface enhanced Raman scattering
sensing
nanoporous substrates
anodic aluminum oxide
chemical sensor
optical sensor
ceramic membranes
title Effect of Pore Size and Film Thickness on Gold-Coated Nanoporous Anodic Aluminum Oxide Substrates for Surface-Enhanced Raman Scattering Sensor
title_full Effect of Pore Size and Film Thickness on Gold-Coated Nanoporous Anodic Aluminum Oxide Substrates for Surface-Enhanced Raman Scattering Sensor
title_fullStr Effect of Pore Size and Film Thickness on Gold-Coated Nanoporous Anodic Aluminum Oxide Substrates for Surface-Enhanced Raman Scattering Sensor
title_full_unstemmed Effect of Pore Size and Film Thickness on Gold-Coated Nanoporous Anodic Aluminum Oxide Substrates for Surface-Enhanced Raman Scattering Sensor
title_short Effect of Pore Size and Film Thickness on Gold-Coated Nanoporous Anodic Aluminum Oxide Substrates for Surface-Enhanced Raman Scattering Sensor
title_sort effect of pore size and film thickness on gold coated nanoporous anodic aluminum oxide substrates for surface enhanced raman scattering sensor
topic surface enhanced Raman scattering
sensing
nanoporous substrates
anodic aluminum oxide
chemical sensor
optical sensor
ceramic membranes
url http://www.mdpi.com/1424-8220/15/12/29778
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