Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ2N,N′)copper(II) dihydrate
In the title compound, [Cu(C3H10N2)2(C6H6NO3S)2]·2H2O, the CuII atom lies on an inversion center and is hexacoordinated by four N atoms from two 1,3-diaminopropane ligands and two O atoms from two 4-aminobenzenesulfonate ligands in a trans arrangement, displaying a distorted and axially...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809049769 |
| _version_ | 1818776182790815744 |
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| author | Xiu-Ling Li Xiang-Gao Meng Ke-Juan Zhang |
| author_facet | Xiu-Ling Li Xiang-Gao Meng Ke-Juan Zhang |
| author_sort | Xiu-Ling Li |
| collection | DOAJ |
| description | In the title compound, [Cu(C3H10N2)2(C6H6NO3S)2]·2H2O, the CuII atom lies on an inversion center and is hexacoordinated by four N atoms from two 1,3-diaminopropane ligands and two O atoms from two 4-aminobenzenesulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octahedral coordination geometry, with the O atoms at the axial positions. A three-dimensional network is formed in the crystal structure through O—H...O, N—H...O and N—H...N hydrogen bonds. |
| first_indexed | 2024-12-18T11:08:52Z |
| format | Article |
| id | doaj.art-8a360e353ff14d96a1164713c5b9606e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T11:08:52Z |
| publishDate | 2009-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8a360e353ff14d96a1164713c5b9606e2022-12-21T21:10:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1678m167910.1107/S1600536809049769Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ2N,N′)copper(II) dihydrateXiu-Ling LiXiang-Gao MengKe-Juan ZhangIn the title compound, [Cu(C3H10N2)2(C6H6NO3S)2]·2H2O, the CuII atom lies on an inversion center and is hexacoordinated by four N atoms from two 1,3-diaminopropane ligands and two O atoms from two 4-aminobenzenesulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octahedral coordination geometry, with the O atoms at the axial positions. A three-dimensional network is formed in the crystal structure through O—H...O, N—H...O and N—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536809049769 |
| spellingShingle | Xiu-Ling Li Xiang-Gao Meng Ke-Juan Zhang Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ2N,N′)copper(II) dihydrate Acta Crystallographica Section E |
| title | Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ2N,N′)copper(II) dihydrate |
| title_full | Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ2N,N′)copper(II) dihydrate |
| title_fullStr | Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ2N,N′)copper(II) dihydrate |
| title_full_unstemmed | Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ2N,N′)copper(II) dihydrate |
| title_short | Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ2N,N′)copper(II) dihydrate |
| title_sort | bis 4 aminobenzenesulfonato amp 954 o bis propane 1 3 diamine amp 954 2n n amp 8242 copper ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809049769 |
| work_keys_str_mv | AT xiulingli bis4aminobenzenesulfonatoamp954obispropane13diamineamp9542nnamp8242copperiidihydrate AT xianggaomeng bis4aminobenzenesulfonatoamp954obispropane13diamineamp9542nnamp8242copperiidihydrate AT kejuanzhang bis4aminobenzenesulfonatoamp954obispropane13diamineamp9542nnamp8242copperiidihydrate |