Fabrication of dual atomic copper‑indium (CuIn) catalysts for electrochemical CO2 reduction to methanol
Dual atomic copper‑indium (CuIn) catalysts (CuIn-DACs) have been fabricated by metal-organic framework (MOF) derivation strategy for electrochemical reduction of CO2 to methanol with high selectivity, in which Cu and In atoms are simultaneously introduced in MOF. The introduction of indium modulates...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-04-01
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| Series: | Catalysis Communications |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1566736723000420 |
| _version_ | 1797842854231408640 |
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| author | Jiongliang Yuan Yaru Chen Feng Liu Yuning Su |
| author_facet | Jiongliang Yuan Yaru Chen Feng Liu Yuning Su |
| author_sort | Jiongliang Yuan |
| collection | DOAJ |
| description | Dual atomic copper‑indium (CuIn) catalysts (CuIn-DACs) have been fabricated by metal-organic framework (MOF) derivation strategy for electrochemical reduction of CO2 to methanol with high selectivity, in which Cu and In atoms are simultaneously introduced in MOF. The introduction of indium modulates the electronic structure of Cu atoms. The neighbouring CuIn dual atomic sites inhibit the hydrogen evolution reaction and promote the conversion of CO2 to methanol because of the synergistic effect between Cu and In. CuIn-DACs exhibit higher selectivity to methanol than single atomic Cu catalysts. |
| first_indexed | 2024-04-09T16:54:54Z |
| format | Article |
| id | doaj.art-8a363776c74d4c92bcd38aaefee7cbd7 |
| institution | Directory Open Access Journal |
| issn | 1873-3905 |
| language | English |
| last_indexed | 2024-04-09T16:54:54Z |
| publishDate | 2023-04-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Catalysis Communications |
| spelling | doaj.art-8a363776c74d4c92bcd38aaefee7cbd72023-04-21T06:40:54ZengElsevierCatalysis Communications1873-39052023-04-01177106640Fabrication of dual atomic copper‑indium (CuIn) catalysts for electrochemical CO2 reduction to methanolJiongliang Yuan0Yaru Chen1Feng Liu2Yuning Su3Corresponding author.; Department of Environmental Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, PR ChinaDepartment of Environmental Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, PR ChinaDepartment of Environmental Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, PR ChinaDepartment of Environmental Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, PR ChinaDual atomic copper‑indium (CuIn) catalysts (CuIn-DACs) have been fabricated by metal-organic framework (MOF) derivation strategy for electrochemical reduction of CO2 to methanol with high selectivity, in which Cu and In atoms are simultaneously introduced in MOF. The introduction of indium modulates the electronic structure of Cu atoms. The neighbouring CuIn dual atomic sites inhibit the hydrogen evolution reaction and promote the conversion of CO2 to methanol because of the synergistic effect between Cu and In. CuIn-DACs exhibit higher selectivity to methanol than single atomic Cu catalysts.http://www.sciencedirect.com/science/article/pii/S1566736723000420Dual atomic catalystsElectrochemical CO2 reductionSelectivityMethanol |
| spellingShingle | Jiongliang Yuan Yaru Chen Feng Liu Yuning Su Fabrication of dual atomic copper‑indium (CuIn) catalysts for electrochemical CO2 reduction to methanol Catalysis Communications Dual atomic catalysts Electrochemical CO2 reduction Selectivity Methanol |
| title | Fabrication of dual atomic copper‑indium (CuIn) catalysts for electrochemical CO2 reduction to methanol |
| title_full | Fabrication of dual atomic copper‑indium (CuIn) catalysts for electrochemical CO2 reduction to methanol |
| title_fullStr | Fabrication of dual atomic copper‑indium (CuIn) catalysts for electrochemical CO2 reduction to methanol |
| title_full_unstemmed | Fabrication of dual atomic copper‑indium (CuIn) catalysts for electrochemical CO2 reduction to methanol |
| title_short | Fabrication of dual atomic copper‑indium (CuIn) catalysts for electrochemical CO2 reduction to methanol |
| title_sort | fabrication of dual atomic copper indium cuin catalysts for electrochemical co2 reduction to methanol |
| topic | Dual atomic catalysts Electrochemical CO2 reduction Selectivity Methanol |
| url | http://www.sciencedirect.com/science/article/pii/S1566736723000420 |
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