Spark plasma sintering of low modulus titanium-niobium-tantalum-zirconium (TNTZ) alloy for biomedical applications
In metallurgy, titanium has been a staple for biomedical purposes. Its slow toxicity and alloying versatility make it an attractive choice for medical applications. However, studies have shown the difference in elastic modulus between titanium alloys (116 GPa) and human bone (10–40 GPa), which contr...
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Format: | Article |
Language: | English |
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Elsevier
2019-12-01
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Series: | Materials & Design |
Online Access: | http://www.sciencedirect.com/science/article/pii/S026412751930601X |
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author | Nicholas Mavros Taban Larimian Javier Esqivel Rajeev Kumar Gupta Rodrigo Contieri Tushar Borkar |
author_facet | Nicholas Mavros Taban Larimian Javier Esqivel Rajeev Kumar Gupta Rodrigo Contieri Tushar Borkar |
author_sort | Nicholas Mavros |
collection | DOAJ |
description | In metallurgy, titanium has been a staple for biomedical purposes. Its slow toxicity and alloying versatility make it an attractive choice for medical applications. However, studies have shown the difference in elastic modulus between titanium alloys (116 GPa) and human bone (10–40 GPa), which contributes to long term issues with loose hardware fixation. Additionally, long term studies have shown elements such as vanadium and aluminum, which are commonly used in Ti-6Al-4V biomedical alloys, have been linked to neurodegenerative diseases like Alzheimer and Parkinson. Alternative metals known to be less toxic are being explored as replacements for alloying elements in titanium alloys. This study will focus on advanced processing and characterization of β-phase titanium alloys for biomedical applications. The microstructure, mechanical, and electrochemical properties of these alloys have been analyzed and compared with C.P. titanium. Bond order B¯O and energy level M¯D approach has been used to design these alloys in order to achieve low elastic modulus. The main objective is to study the effect of different alloying elements on microstructure, phase transformation and mechanical properties of these newly developed low modulus β-phase titanium alloys and establish new avenues for the future development of biocompatible titanium alloys with optimum microstructure and properties. Keywords: Low modulus beta titanium alloys, Mechanical alloying, Spark plasma sintering, Corrosion, Biomedical applications |
first_indexed | 2024-12-21T19:14:38Z |
format | Article |
id | doaj.art-8a3911ee2c404c7ca3c54914807cc64e |
institution | Directory Open Access Journal |
issn | 0264-1275 |
language | English |
last_indexed | 2024-12-21T19:14:38Z |
publishDate | 2019-12-01 |
publisher | Elsevier |
record_format | Article |
series | Materials & Design |
spelling | doaj.art-8a3911ee2c404c7ca3c54914807cc64e2022-12-21T18:53:06ZengElsevierMaterials & Design0264-12752019-12-01183Spark plasma sintering of low modulus titanium-niobium-tantalum-zirconium (TNTZ) alloy for biomedical applicationsNicholas Mavros0Taban Larimian1Javier Esqivel2Rajeev Kumar Gupta3Rodrigo Contieri4Tushar Borkar5Department of Mechanical Engineering, Cleveland State University, OH 44115, United States of AmericaDepartment of Mechanical Engineering, Cleveland State University, OH 44115, United States of AmericaDepartment of Chemical and Biomolecular Engineering, Corrosion Engineering Program, The University of Akron, OH 44325, United States of AmericaDepartment of Chemical and Biomolecular Engineering, Corrosion Engineering Program, The University of Akron, OH 44325, United States of AmericaSchool of Applied Science, University of Campinas, Limeira, BrazilDepartment of Mechanical Engineering, Cleveland State University, OH 44115, United States of America; Corresponding author.In metallurgy, titanium has been a staple for biomedical purposes. Its slow toxicity and alloying versatility make it an attractive choice for medical applications. However, studies have shown the difference in elastic modulus between titanium alloys (116 GPa) and human bone (10–40 GPa), which contributes to long term issues with loose hardware fixation. Additionally, long term studies have shown elements such as vanadium and aluminum, which are commonly used in Ti-6Al-4V biomedical alloys, have been linked to neurodegenerative diseases like Alzheimer and Parkinson. Alternative metals known to be less toxic are being explored as replacements for alloying elements in titanium alloys. This study will focus on advanced processing and characterization of β-phase titanium alloys for biomedical applications. The microstructure, mechanical, and electrochemical properties of these alloys have been analyzed and compared with C.P. titanium. Bond order B¯O and energy level M¯D approach has been used to design these alloys in order to achieve low elastic modulus. The main objective is to study the effect of different alloying elements on microstructure, phase transformation and mechanical properties of these newly developed low modulus β-phase titanium alloys and establish new avenues for the future development of biocompatible titanium alloys with optimum microstructure and properties. Keywords: Low modulus beta titanium alloys, Mechanical alloying, Spark plasma sintering, Corrosion, Biomedical applicationshttp://www.sciencedirect.com/science/article/pii/S026412751930601X |
spellingShingle | Nicholas Mavros Taban Larimian Javier Esqivel Rajeev Kumar Gupta Rodrigo Contieri Tushar Borkar Spark plasma sintering of low modulus titanium-niobium-tantalum-zirconium (TNTZ) alloy for biomedical applications Materials & Design |
title | Spark plasma sintering of low modulus titanium-niobium-tantalum-zirconium (TNTZ) alloy for biomedical applications |
title_full | Spark plasma sintering of low modulus titanium-niobium-tantalum-zirconium (TNTZ) alloy for biomedical applications |
title_fullStr | Spark plasma sintering of low modulus titanium-niobium-tantalum-zirconium (TNTZ) alloy for biomedical applications |
title_full_unstemmed | Spark plasma sintering of low modulus titanium-niobium-tantalum-zirconium (TNTZ) alloy for biomedical applications |
title_short | Spark plasma sintering of low modulus titanium-niobium-tantalum-zirconium (TNTZ) alloy for biomedical applications |
title_sort | spark plasma sintering of low modulus titanium niobium tantalum zirconium tntz alloy for biomedical applications |
url | http://www.sciencedirect.com/science/article/pii/S026412751930601X |
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