Design of SiO2/4H–SiC MOS interfaces by sputter deposition of SiO2 followed by high-temperature CO2-post deposition annealing

Oxidation of silicon carbide (SiC) is known to induce defects at the interface of the SiO2/SiC system. NO-annealing is a standard industrial method of nitridation, but oxidation may progress during NO-nitridation, which may generate interface defects. Here, we propose a new method of fabricating SiO...

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Main Authors: Tae-Hyeon Kil, Takuma Kobayashi, Takayoshi Shimura, Heiji Watanabe
Format: Article
Language:English
Published: AIP Publishing LLC 2023-11-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/5.0169573
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author Tae-Hyeon Kil
Takuma Kobayashi
Takayoshi Shimura
Heiji Watanabe
author_facet Tae-Hyeon Kil
Takuma Kobayashi
Takayoshi Shimura
Heiji Watanabe
author_sort Tae-Hyeon Kil
collection DOAJ
description Oxidation of silicon carbide (SiC) is known to induce defects at the interface of the SiO2/SiC system. NO-annealing is a standard industrial method of nitridation, but oxidation may progress during NO-nitridation, which may generate interface defects. Here, we propose a new method of fabricating SiO2/SiC metal-oxide-semiconductor (MOS) devices: sputter deposition of SiO2 in an Ar/N2 gas mixture followed by high-temperature CO2-post deposition annealing to form SiO2 and incorporate nitrogen at the interface while suppressing oxidation of the SiC. We obtained the nitrogen depth profile by performing x-ray photoelectron spectroscopy and confirmed that most of the nitrogen atoms exist at the abrupt interface. While maintaining a low interface state density and good insulating property, we demonstrated much improved reliability of MOS devices compared to conventional NO-annealed samples, thanks to the well-designed SiO2/SiC interface by the proposed method.
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spelling doaj.art-8a3bd10246da4f56b9f2bbfb4aad03c92023-12-04T17:18:29ZengAIP Publishing LLCAIP Advances2158-32262023-11-011311115304115304-510.1063/5.0169573Design of SiO2/4H–SiC MOS interfaces by sputter deposition of SiO2 followed by high-temperature CO2-post deposition annealingTae-Hyeon Kil0Takuma Kobayashi1Takayoshi Shimura2Heiji Watanabe3Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, JapanGraduate School of Engineering, Osaka University, Suita, Osaka 565-0871, JapanGraduate School of Engineering, Osaka University, Suita, Osaka 565-0871, JapanGraduate School of Engineering, Osaka University, Suita, Osaka 565-0871, JapanOxidation of silicon carbide (SiC) is known to induce defects at the interface of the SiO2/SiC system. NO-annealing is a standard industrial method of nitridation, but oxidation may progress during NO-nitridation, which may generate interface defects. Here, we propose a new method of fabricating SiO2/SiC metal-oxide-semiconductor (MOS) devices: sputter deposition of SiO2 in an Ar/N2 gas mixture followed by high-temperature CO2-post deposition annealing to form SiO2 and incorporate nitrogen at the interface while suppressing oxidation of the SiC. We obtained the nitrogen depth profile by performing x-ray photoelectron spectroscopy and confirmed that most of the nitrogen atoms exist at the abrupt interface. While maintaining a low interface state density and good insulating property, we demonstrated much improved reliability of MOS devices compared to conventional NO-annealed samples, thanks to the well-designed SiO2/SiC interface by the proposed method.http://dx.doi.org/10.1063/5.0169573
spellingShingle Tae-Hyeon Kil
Takuma Kobayashi
Takayoshi Shimura
Heiji Watanabe
Design of SiO2/4H–SiC MOS interfaces by sputter deposition of SiO2 followed by high-temperature CO2-post deposition annealing
AIP Advances
title Design of SiO2/4H–SiC MOS interfaces by sputter deposition of SiO2 followed by high-temperature CO2-post deposition annealing
title_full Design of SiO2/4H–SiC MOS interfaces by sputter deposition of SiO2 followed by high-temperature CO2-post deposition annealing
title_fullStr Design of SiO2/4H–SiC MOS interfaces by sputter deposition of SiO2 followed by high-temperature CO2-post deposition annealing
title_full_unstemmed Design of SiO2/4H–SiC MOS interfaces by sputter deposition of SiO2 followed by high-temperature CO2-post deposition annealing
title_short Design of SiO2/4H–SiC MOS interfaces by sputter deposition of SiO2 followed by high-temperature CO2-post deposition annealing
title_sort design of sio2 4h sic mos interfaces by sputter deposition of sio2 followed by high temperature co2 post deposition annealing
url http://dx.doi.org/10.1063/5.0169573
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