Composite Film Based on Pulping Industry Waste and Chitosan for Food Packaging

Wood auto-hydrolysates (WAH) are obtained in the pulping process by the hydrothermal extraction, which contains lots of hemicelluloses and slight lignin. WAH and chitosan (CS) were introduced into this study to construct WAH-based films by the casting method. The FT-IR results revealed the crosslink...

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Main Authors: Ji-Dong Xu, Ya-Shuai Niu, Pan-Pan Yue, Ya-Jie Hu, Jing Bian, Ming-Fei Li, Feng Peng, Run-Cang Sun
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/11/11/2264
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author Ji-Dong Xu
Ya-Shuai Niu
Pan-Pan Yue
Ya-Jie Hu
Jing Bian
Ming-Fei Li
Feng Peng
Run-Cang Sun
author_facet Ji-Dong Xu
Ya-Shuai Niu
Pan-Pan Yue
Ya-Jie Hu
Jing Bian
Ming-Fei Li
Feng Peng
Run-Cang Sun
author_sort Ji-Dong Xu
collection DOAJ
description Wood auto-hydrolysates (WAH) are obtained in the pulping process by the hydrothermal extraction, which contains lots of hemicelluloses and slight lignin. WAH and chitosan (CS) were introduced into this study to construct WAH-based films by the casting method. The FT-IR results revealed the crosslinking interaction between WAH and CS due to the Millard reaction. The morphology, transmittance, thermal properties and mechanical properties of composite WAH/CS films were investigated. As the results showed, the tensile strength, light transmittances and thermal stability of the WAH-based composite films increased with the increment of WAH/CS content ratio. In addition, the results of oxygen transfer rate (OTR) and water vapor permeability (WVP) suggested that the OTR and WVP values of the films decreased due to the addition of CS. The maximum value of tensile strengths of the composite films achieved 71.2 MPa and the OTR of the films was low as 0.16 cm<sup>3</sup>&#183;&#956;m&#183;m<sup>&#8722;2</sup>&#183;24 h<sup>&#8722;1</sup>&#183;kPa<sup>&#8722;1</sup>, these properties are better than those of other hemicelluloses composite films. These results suggested that the barrier composite films based on WAH and CS will become attractive in the food packaging application for great mechanical properties, good transmittance and low oxygen transfer rate.
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spelling doaj.art-8a5c702062c243b2922085d75e14222c2022-12-22T03:36:08ZengMDPI AGMaterials1996-19442018-11-011111226410.3390/ma11112264ma11112264Composite Film Based on Pulping Industry Waste and Chitosan for Food PackagingJi-Dong Xu0Ya-Shuai Niu1Pan-Pan Yue2Ya-Jie Hu3Jing Bian4Ming-Fei Li5Feng Peng6Run-Cang Sun7Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, ChinaBeijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, ChinaBeijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, ChinaBeijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, ChinaBeijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, ChinaBeijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, ChinaBeijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, ChinaBeijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, ChinaWood auto-hydrolysates (WAH) are obtained in the pulping process by the hydrothermal extraction, which contains lots of hemicelluloses and slight lignin. WAH and chitosan (CS) were introduced into this study to construct WAH-based films by the casting method. The FT-IR results revealed the crosslinking interaction between WAH and CS due to the Millard reaction. The morphology, transmittance, thermal properties and mechanical properties of composite WAH/CS films were investigated. As the results showed, the tensile strength, light transmittances and thermal stability of the WAH-based composite films increased with the increment of WAH/CS content ratio. In addition, the results of oxygen transfer rate (OTR) and water vapor permeability (WVP) suggested that the OTR and WVP values of the films decreased due to the addition of CS. The maximum value of tensile strengths of the composite films achieved 71.2 MPa and the OTR of the films was low as 0.16 cm<sup>3</sup>&#183;&#956;m&#183;m<sup>&#8722;2</sup>&#183;24 h<sup>&#8722;1</sup>&#183;kPa<sup>&#8722;1</sup>, these properties are better than those of other hemicelluloses composite films. These results suggested that the barrier composite films based on WAH and CS will become attractive in the food packaging application for great mechanical properties, good transmittance and low oxygen transfer rate.https://www.mdpi.com/1996-1944/11/11/2264hemicelluloseschitosancomposite filmsoxygen barrier propertyfood packaging
spellingShingle Ji-Dong Xu
Ya-Shuai Niu
Pan-Pan Yue
Ya-Jie Hu
Jing Bian
Ming-Fei Li
Feng Peng
Run-Cang Sun
Composite Film Based on Pulping Industry Waste and Chitosan for Food Packaging
Materials
hemicelluloses
chitosan
composite films
oxygen barrier property
food packaging
title Composite Film Based on Pulping Industry Waste and Chitosan for Food Packaging
title_full Composite Film Based on Pulping Industry Waste and Chitosan for Food Packaging
title_fullStr Composite Film Based on Pulping Industry Waste and Chitosan for Food Packaging
title_full_unstemmed Composite Film Based on Pulping Industry Waste and Chitosan for Food Packaging
title_short Composite Film Based on Pulping Industry Waste and Chitosan for Food Packaging
title_sort composite film based on pulping industry waste and chitosan for food packaging
topic hemicelluloses
chitosan
composite films
oxygen barrier property
food packaging
url https://www.mdpi.com/1996-1944/11/11/2264
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