Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic Fields

Nuclear magnetic resonance (NMR) is a branch of spectroscopy commonly used for identifying the chemical structure of various materials. One of the areas in which NMR provides accurate data is the determination of nuclear magnetic moments. This work reviews NMR experiments with the nuclei of light el...

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Main Authors: Włodzimierz Makulski, Mateusz A. Słowiński, Piotr Garbacz
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Magnetochemistry
Subjects:
Online Access:https://www.mdpi.com/2312-7481/9/6/148
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author Włodzimierz Makulski
Mateusz A. Słowiński
Piotr Garbacz
author_facet Włodzimierz Makulski
Mateusz A. Słowiński
Piotr Garbacz
author_sort Włodzimierz Makulski
collection DOAJ
description Nuclear magnetic resonance (NMR) is a branch of spectroscopy commonly used for identifying the chemical structure of various materials. One of the areas in which NMR provides accurate data is the determination of nuclear magnetic moments. This work reviews NMR experiments with the nuclei of light elements in simple molecules. Since nuclear shielding constants from up-to-date quantum calculations are now available, very accurate dipole moments of many nuclei can be determined. Recent experimental measurements of <sup>1</sup>H, <sup>2</sup>H, <sup>3</sup>H, <sup>3</sup>He, <sup>6</sup>Li, <sup>7</sup>Li, <sup>9</sup>Be, <sup>10</sup>B, and <sup>11</sup>B nuclear magnetic moments and the appropriate theoretical predictions are presented and commented upon. Several achievements in this field using different methodologies, such as NMR spectroscopy, molecular beam experiments, and the Penning trap method are reported.
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spelling doaj.art-8a76b9fe6c0b45809417c0fa727a72202023-11-18T11:21:51ZengMDPI AGMagnetochemistry2312-74812023-06-019614810.3390/magnetochemistry9060148Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic FieldsWłodzimierz Makulski0Mateusz A. Słowiński1Piotr Garbacz2Laboratory of NMR Spectroscopy, Faculty of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, PolandLaboratory of NMR Spectroscopy, Faculty of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, PolandLaboratory of NMR Spectroscopy, Faculty of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, PolandNuclear magnetic resonance (NMR) is a branch of spectroscopy commonly used for identifying the chemical structure of various materials. One of the areas in which NMR provides accurate data is the determination of nuclear magnetic moments. This work reviews NMR experiments with the nuclei of light elements in simple molecules. Since nuclear shielding constants from up-to-date quantum calculations are now available, very accurate dipole moments of many nuclei can be determined. Recent experimental measurements of <sup>1</sup>H, <sup>2</sup>H, <sup>3</sup>H, <sup>3</sup>He, <sup>6</sup>Li, <sup>7</sup>Li, <sup>9</sup>Be, <sup>10</sup>B, and <sup>11</sup>B nuclear magnetic moments and the appropriate theoretical predictions are presented and commented upon. Several achievements in this field using different methodologies, such as NMR spectroscopy, molecular beam experiments, and the Penning trap method are reported.https://www.mdpi.com/2312-7481/9/6/148nuclear dipole momentsnuclear shielding constantslight nucleiNMR spectroscopy
spellingShingle Włodzimierz Makulski
Mateusz A. Słowiński
Piotr Garbacz
Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic Fields
Magnetochemistry
nuclear dipole moments
nuclear shielding constants
light nuclei
NMR spectroscopy
title Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic Fields
title_full Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic Fields
title_fullStr Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic Fields
title_full_unstemmed Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic Fields
title_short Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic Fields
title_sort nuclear dipole moments and shielding constants of light nuclei measured in magnetic fields
topic nuclear dipole moments
nuclear shielding constants
light nuclei
NMR spectroscopy
url https://www.mdpi.com/2312-7481/9/6/148
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AT mateuszasłowinski nucleardipolemomentsandshieldingconstantsoflightnucleimeasuredinmagneticfields
AT piotrgarbacz nucleardipolemomentsandshieldingconstantsoflightnucleimeasuredinmagneticfields