Geochemical Features of Potentially Ore-Bearing Mafic Intrusions at the Eastern Norilsk Region and Their Relationships with Lavas (NW Siberian Traps Province)

The problem of the world-class PGE-Cu-Ni Norilsk deposits’ origin has attracted geologists for several decades. The main goal of this study is to determine the specific features of ore-bearing intrusions in comparison with thousands of similar barren intrusions widespread within the Siberian igneous...

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Main Authors: Yuri Kostitsyn, Nadezhda Krivolutskaya, Alina V. Somsikova, Maria Anosova, Svetlana Demidova, Artem Konyshev
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Minerals
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Online Access:https://www.mdpi.com/2075-163X/13/2/213
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author Yuri Kostitsyn
Nadezhda Krivolutskaya
Alina V. Somsikova
Maria Anosova
Svetlana Demidova
Artem Konyshev
author_facet Yuri Kostitsyn
Nadezhda Krivolutskaya
Alina V. Somsikova
Maria Anosova
Svetlana Demidova
Artem Konyshev
author_sort Yuri Kostitsyn
collection DOAJ
description The problem of the world-class PGE-Cu-Ni Norilsk deposits’ origin has attracted geologists for several decades. The main goal of this study is to determine the specific features of ore-bearing intrusions in comparison with thousands of similar barren intrusions widespread within the Siberian igneous province, and to establish their genesis. As a result of statistical processing of previously published isotope-geochemical data and obtained by the authors, systematic differences were found in the distribution of the isotopic ratio of Nd in ore-bearing and barren intrusions, as well as in volcanic rocks at the Norilsk region. Thus, ore-bearing rocks in ten deposits (Talnakh, Kharayelakh, Norilsk 1, South-Maslovsky, North-Maslovsky, Norilsk 2, Chernogorsky, Zub-Mrksheydersky, Pyasino-Vologochansky, Imangdinsky), different in Ni and PGE reserves, show a very narrow range of Nd isotopic ratio, Ԑ<sub>Nd</sub>(T) = 1.0 ± 1.0 (2σ, N = 139), whereas barren and volcanic rocks are characterized by a rather wide Ԑ<sub>Nd</sub>(T) range, from −10 to +7 units (N = 256). Furthermore, ore-bearing intrusions are characterized by reduced and compact variations of the La/Lu ratio due to lower concentrations of light lanthanides. For the first time the authors studied two new intrusions penetrated by MD-48 and MD-60 boreholes drilled by Norislkgeologia LLT at the eastern part of the Mikchangda area. Their economic values are still unclear and should be estimated using geochemical methods. Both intrusions lie in the Devonian rocks, have similar thickness and mineral composition, but differ in textural and structural features, which indicate a rapid crystallization of the MD-48 intrusion. According to the contents of the major oxides, the rocks in MD-48 and MD-60 are identical, but they differ in U/Nb, La/Sm, and Gd/Yb ratios. It is important that the rocks in the MD-60 borehole are characterized by Ԑ<sub>Nd</sub>(T) = 1.0 ± 0.6 (2σ) and fall into the range of ore-bearing intrusions, whereas the rocks in MD-48 have Ԑ<sub>Nd</sub>(T) 2.4 ± 0.9, and, thus, are outside of ore-bearing intrusions. Therefore, Ԑ<sub>Nd</sub>(T) values can be used as a local criterion for the estimation of economic potential of mafic intrusions, which is demonstrated for the Mikachangda area.
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spelling doaj.art-8a7783891c9b4bfb9f9e6e41f91538802023-11-16T22:18:26ZengMDPI AGMinerals2075-163X2023-02-0113221310.3390/min13020213Geochemical Features of Potentially Ore-Bearing Mafic Intrusions at the Eastern Norilsk Region and Their Relationships with Lavas (NW Siberian Traps Province)Yuri Kostitsyn0Nadezhda Krivolutskaya1Alina V. Somsikova2Maria Anosova3Svetlana Demidova4Artem Konyshev5Vernadsky Institute of Geochemistry and Analytical Chemistry of the Russian Academy of Sciences, 119991 Moscow, RussiaVernadsky Institute of Geochemistry and Analytical Chemistry of the Russian Academy of Sciences, 119991 Moscow, RussiaVernadsky Institute of Geochemistry and Analytical Chemistry of the Russian Academy of Sciences, 119991 Moscow, RussiaVernadsky Institute of Geochemistry and Analytical Chemistry of the Russian Academy of Sciences, 119991 Moscow, RussiaVernadsky Institute of Geochemistry and Analytical Chemistry of the Russian Academy of Sciences, 119991 Moscow, RussiaInstitute of Geology of Karelian Research Centre, The Russian Academy of Sciences, 185910 Petrozavodsk, RussiaThe problem of the world-class PGE-Cu-Ni Norilsk deposits’ origin has attracted geologists for several decades. The main goal of this study is to determine the specific features of ore-bearing intrusions in comparison with thousands of similar barren intrusions widespread within the Siberian igneous province, and to establish their genesis. As a result of statistical processing of previously published isotope-geochemical data and obtained by the authors, systematic differences were found in the distribution of the isotopic ratio of Nd in ore-bearing and barren intrusions, as well as in volcanic rocks at the Norilsk region. Thus, ore-bearing rocks in ten deposits (Talnakh, Kharayelakh, Norilsk 1, South-Maslovsky, North-Maslovsky, Norilsk 2, Chernogorsky, Zub-Mrksheydersky, Pyasino-Vologochansky, Imangdinsky), different in Ni and PGE reserves, show a very narrow range of Nd isotopic ratio, Ԑ<sub>Nd</sub>(T) = 1.0 ± 1.0 (2σ, N = 139), whereas barren and volcanic rocks are characterized by a rather wide Ԑ<sub>Nd</sub>(T) range, from −10 to +7 units (N = 256). Furthermore, ore-bearing intrusions are characterized by reduced and compact variations of the La/Lu ratio due to lower concentrations of light lanthanides. For the first time the authors studied two new intrusions penetrated by MD-48 and MD-60 boreholes drilled by Norislkgeologia LLT at the eastern part of the Mikchangda area. Their economic values are still unclear and should be estimated using geochemical methods. Both intrusions lie in the Devonian rocks, have similar thickness and mineral composition, but differ in textural and structural features, which indicate a rapid crystallization of the MD-48 intrusion. According to the contents of the major oxides, the rocks in MD-48 and MD-60 are identical, but they differ in U/Nb, La/Sm, and Gd/Yb ratios. It is important that the rocks in the MD-60 borehole are characterized by Ԑ<sub>Nd</sub>(T) = 1.0 ± 0.6 (2σ) and fall into the range of ore-bearing intrusions, whereas the rocks in MD-48 have Ԑ<sub>Nd</sub>(T) 2.4 ± 0.9, and, thus, are outside of ore-bearing intrusions. Therefore, Ԑ<sub>Nd</sub>(T) values can be used as a local criterion for the estimation of economic potential of mafic intrusions, which is demonstrated for the Mikachangda area.https://www.mdpi.com/2075-163X/13/2/213PGE-Cu-Ni depositsNorilsk districtSiberian trapsgeochemistry of basic intrusionsSr and Nd isotopescriteria
spellingShingle Yuri Kostitsyn
Nadezhda Krivolutskaya
Alina V. Somsikova
Maria Anosova
Svetlana Demidova
Artem Konyshev
Geochemical Features of Potentially Ore-Bearing Mafic Intrusions at the Eastern Norilsk Region and Their Relationships with Lavas (NW Siberian Traps Province)
Minerals
PGE-Cu-Ni deposits
Norilsk district
Siberian traps
geochemistry of basic intrusions
Sr and Nd isotopes
criteria
title Geochemical Features of Potentially Ore-Bearing Mafic Intrusions at the Eastern Norilsk Region and Their Relationships with Lavas (NW Siberian Traps Province)
title_full Geochemical Features of Potentially Ore-Bearing Mafic Intrusions at the Eastern Norilsk Region and Their Relationships with Lavas (NW Siberian Traps Province)
title_fullStr Geochemical Features of Potentially Ore-Bearing Mafic Intrusions at the Eastern Norilsk Region and Their Relationships with Lavas (NW Siberian Traps Province)
title_full_unstemmed Geochemical Features of Potentially Ore-Bearing Mafic Intrusions at the Eastern Norilsk Region and Their Relationships with Lavas (NW Siberian Traps Province)
title_short Geochemical Features of Potentially Ore-Bearing Mafic Intrusions at the Eastern Norilsk Region and Their Relationships with Lavas (NW Siberian Traps Province)
title_sort geochemical features of potentially ore bearing mafic intrusions at the eastern norilsk region and their relationships with lavas nw siberian traps province
topic PGE-Cu-Ni deposits
Norilsk district
Siberian traps
geochemistry of basic intrusions
Sr and Nd isotopes
criteria
url https://www.mdpi.com/2075-163X/13/2/213
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