Hypervalent Iodine–Mediated Ring Contraction Reactions
Hypervalent iodine reagents constitute a powerful tool in modern synthetic organic chemistry, promoting several important reactions. One such reaction is the ring contraction of cycloalkenes and cycloalkanones promoted by iodine(III) compounds, such as iodobenzene diacetate, iodosylbenzene, iodotolu...
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| Format: | Article |
| Language: | English |
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MDPI AG
2006-06-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/11/6/421/ |
| _version_ | 1818300099572269056 |
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| author | Luiz F. Silva |
| author_facet | Luiz F. Silva |
| author_sort | Luiz F. Silva |
| collection | DOAJ |
| description | Hypervalent iodine reagents constitute a powerful tool in modern synthetic organic chemistry, promoting several important reactions. One such reaction is the ring contraction of cycloalkenes and cycloalkanones promoted by iodine(III) compounds, such as iodobenzene diacetate, iodosylbenzene, iodotoluene difluoride, and [hydroxy(tosyloxy)- iodo]benzene (Koser ÃŒÂs reagent). This review covers all the literature related to the ring contraction of cyclic ketones and olefins promoted by iodine(III) species. |
| first_indexed | 2024-12-13T05:01:44Z |
| format | Article |
| id | doaj.art-8a7f3dd89e8a4dba8a3a2d667f1abae7 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-13T05:01:44Z |
| publishDate | 2006-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-8a7f3dd89e8a4dba8a3a2d667f1abae72022-12-21T23:58:46ZengMDPI AGMolecules1420-30492006-06-0111642143410.3390/11060421Hypervalent Iodine–Mediated Ring Contraction ReactionsLuiz F. SilvaHypervalent iodine reagents constitute a powerful tool in modern synthetic organic chemistry, promoting several important reactions. One such reaction is the ring contraction of cycloalkenes and cycloalkanones promoted by iodine(III) compounds, such as iodobenzene diacetate, iodosylbenzene, iodotoluene difluoride, and [hydroxy(tosyloxy)- iodo]benzene (Koser ÃŒÂs reagent). This review covers all the literature related to the ring contraction of cyclic ketones and olefins promoted by iodine(III) species.http://www.mdpi.com/1420-3049/11/6/421/Iodine(III)hypervalent iodinering contractionoxidationcycloalkenescycloalkanones. |
| spellingShingle | Luiz F. Silva Hypervalent Iodine–Mediated Ring Contraction Reactions Molecules Iodine(III) hypervalent iodine ring contraction oxidation cycloalkenes cycloalkanones. |
| title | Hypervalent Iodine–Mediated Ring Contraction Reactions |
| title_full | Hypervalent Iodine–Mediated Ring Contraction Reactions |
| title_fullStr | Hypervalent Iodine–Mediated Ring Contraction Reactions |
| title_full_unstemmed | Hypervalent Iodine–Mediated Ring Contraction Reactions |
| title_short | Hypervalent Iodine–Mediated Ring Contraction Reactions |
| title_sort | hypervalent iodinea¢a€a mediated ring contraction reactions |
| topic | Iodine(III) hypervalent iodine ring contraction oxidation cycloalkenes cycloalkanones. |
| url | http://www.mdpi.com/1420-3049/11/6/421/ |
| work_keys_str_mv | AT luizfsilva hypervalentiodineaaamediatedringcontractionreactions |